Zum Mineral Johillerit verwandte Oxovanadate RbCd4V3O12 und TlCd4V3O12 / Oxovanadates RbCd4V3O12 and TlCd4V3 O12 Related to the Mineral Johillerite
1997 ◽
Vol 52
(5)
◽
pp. 663-668
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Keyword(s):
Abstract Single crystals of I RbCd4V3O12 and TlCd4V3O12 II have been prepared by solid state reactions in closed iron tubes. The compounds crystallize closely related to the Johillerite structure in the space group C62h- C2/c with I: a = 13.058(3); b - 13.528(3), c = 7 .0 6 0 (2 )Å , β = 114.88(2)°; II: a = 12.999(6), b = 13.527(7), c = 7.055(3) Å , β = 114.88(4)°, Z = 4. Special features are the loss of Cu2+ in order to gain an additional Cd2+ position. The crystal structure is discussed with respect to related compounds of the Johillerite type.
1996 ◽
Vol 51
(2)
◽
pp. 229-232
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Keyword(s):
1997 ◽
Vol 52
(4)
◽
pp. 457-461
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Keyword(s):
1997 ◽
Vol 52
(8)
◽
pp. 989-993
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2018 ◽
Vol 74
(2)
◽
pp. 109-112
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1996 ◽
Vol 51
(4)
◽
pp. 489-492
◽
1999 ◽
Vol 54
(6)
◽
pp. 818-820
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Keyword(s):