Synthesis and X -Ray Crystal Structure of the Heterobimetallic Complex [FeRh (μ-CO)(CO)3((μ-PBut2)((μ-Ph2PCH2PPh2)]
1997 ◽
Vol 52
(7)
◽
pp. 810-814
◽
Keyword(s):
X Ray
◽
Abstract The reaction of the phosphido-bridged metal carbonyl [FeRh(CO)6(μ-PBut2)] (1) with dppm [dppm = bis(diphenylphosphino)methane] leads to the heterobimetallic complex [FeRh(μ-CO)(CO)3(μ-PBut2)(μ-dppm)] (2) in good yields. The molecular structure of 2 was determined at room temperature [triclinic, space group P1̄, a = 9.509(6), b = 13.637(5), c = 14.926(8) Å, α = 81.38(4), β = 82.75(4), γ = 71.25(4)°]. The compound acts as a homogeneous catalyst precursor in the hydroformylation reaction of ethylene, but it decomposes during this process.
1990 ◽
Vol 45
(8)
◽
pp. 1210-1212
◽
1994 ◽
Vol 209
(6)
◽
1981 ◽
Vol 36
(10)
◽
pp. 1208-1210
◽
1986 ◽
Vol 51
(11)
◽
pp. 2521-2527
◽
1992 ◽
Vol 47
(12)
◽
pp. 1677-1680
◽
Keyword(s):
2014 ◽
Vol 70
(9)
◽
pp. o924-o925
◽
Keyword(s):