Bildung von Arsensäure aus [As2Cl8]2Ionen und Ozon. Die Kristallstruktur von PPh4Cl · H3AsO4 / Formation of Arsenic Acid from [As2Cl8]2- Ions and Ozone. Crystal Structure of PPh4Cl · H3AsO4
1992 ◽
Vol 47
(12)
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pp. 1677-1680
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Keyword(s):
Reaction of ozone with (PPh4)2[As2Cl8] in CH2C12 at low temperatures yields a red compound, possibly an ozonide. Upon evaporation of the solvent at –78 °C the ozone is released again. At -40 °C or above a subsequent reaction yields PPh4[AsCl6], PPh4Cl · H3AsO4, and other products. The crystal structure of PPh4Cl · H3AsO3 was determined by X-ray diffraction (4253 observed reflexions, R = 0.031). It is triclinic, space group P1̅, and consists of H3AsO4 molecules joined to dimer units via H bridges and associated via O–H · · · Cl- bridges to strands. The packing of the PPh4+ ions is discussed. Products of the reaction of (PPh4)2[Sb2Cl8] with ozone in CH2C12 are PPh4[SbCl6] and (PPh4)2[SbOCl4]2 · 2 CH2Cl2.
1994 ◽
Vol 49
(12)
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pp. 1809-1812
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Keyword(s):
1985 ◽
Vol 40
(11)
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pp. 1457-1462
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Keyword(s):
1992 ◽
Vol 47
(4)
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pp. 460-464
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Keyword(s):
1996 ◽
Vol 51
(9)
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pp. 1245-1247
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