The Synthesis, Characterization and Structural Analysis of a Co(III) Complex of 1,10-Phenanthroline and Perfluorosebacic Acid, [Co(HL)(phen)2(H2O)]L·H2O
2006 ◽
Vol 61
(10)
◽
pp. 1198-1204
◽
Keyword(s):
X Ray
◽
The hexacoordinated mononuclear Co(III) complex 1, [Co(HL)(phen)2(H2O)]L·H2O, with the mixed ligands (H2L = HO2C(CF2)8CO2H and 1,10-phenantroline) has been synthesized and characterized by elemental analysis, IR and UV/vis spectroscopy, magnetic susceptibility, TG analysis and X-ray diffraction techniques. The Co(III) atom is coordinated asymmetrically by two bidentate 1,10 phenanthroline ligands, one hydrogencarboxylate ligand, (O2C(CF2)8CO2H)−, and one water molecule. In the crystal structure, there are also dicarboxylate anions and one water molecule attached through hydrogen bonds. Intermolecular π-π interactions between the adjacent phenanthroline ligands also support the packing of the components.
2020 ◽
Vol 76
(10)
◽
pp. 1675-1678
2021 ◽
Vol 77
(11)
◽
Keyword(s):
2011 ◽
Vol 6
(11)
◽
pp. 1934578X1100601
1979 ◽
Vol 34
(11)
◽
pp. 1487-1490
◽
Keyword(s):
2001 ◽
Vol 56
(10)
◽
pp. 1025-1034
◽