The New Vanadoborate-supported Hexanuclear Zinc Complex [Zn(teta)]6[(VO)12O6B18O36(OH)6](H2O) · 8H2O
Keyword(s):
The new vanadoborate-supported zinc complex [Zn(teta)]6[(VO)12O6B18O36(OH)6](H2O) ・8H2O (1, teta = triethylenetetramine) was synthesized hydrothermally and characterized by elemental and thermogravimetric analysis, and IR and UV/Vis spectroscopy. Complex 1 crystallizes in the trigonal system in space group R3̄ and consists of the neutral [Zn(teta)]6[(VO)12O6B18O36(OH)6](H2O) cage aggregate that is built up from a [(VO)12O6B18O36(OH)6]12− cluster decorated with six [Zn(teta)]2+ complex groups, and a water molecule occupying the center of the cluster cage.
1994 ◽
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2017 ◽
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pp. 1191-1204
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pp. C656-C656
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