Structural and IR-spectroscopic characterization of magnesium acesulfamate

2016 ◽  
Vol 71 (1) ◽  
pp. 51-55 ◽  
Author(s):  
Oscar E. Piro ◽  
Gustavo A. Echeverría ◽  
Beatriz S. Parajón-Costa ◽  
Enrique J. Baran
Keyword(s):  
Crystal Structure ◽  
Aqueous Solution ◽  
Elemental Analysis ◽  
Spectroscopic Characterization ◽  
Magnesium Carbonate ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
X Ray ◽  
Ir Spectroscopic

AbstractMagnesium acesulfamate, Mg(C4H4NO4S)2·6H2O, was prepared by the reaction of acesulfamic acid and magnesium carbonate in aqueous solution, and characterized by elemental analysis. Its crystal structure was determined by single crystal X-ray diffraction methods. The substance crystallizes in the triclinic space group P1̅ with one molecule per unit cell. The FTIR spectrum of the compound was also recorded and is briefly discussed. Some comparisons with other simple acesulfamate and saccharinate salts are also made.

Structural and IR-spectroscopic characterization of pyridinium acesulfamate, a monoclinic twin

2018 ◽  
Vol 73 (11) ◽  
pp. 753-758
Author(s):  
Enrique J. Baran ◽  
Oscar E. Piro ◽  
Gustavo A. Echeverría ◽  
Beatriz S. Parajón-Costa
Keyword(s):  
Crystal Structure ◽  
Spectroscopic Characterization ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
X Ray ◽  
Pyridinium Cation ◽  
Ft Ir ◽  
The Fourier Transform ◽  
Ir Spectroscopic

AbstractThe crystal structure of pyridinium 6-methyl-1,2,3,-oxathiazine-4(3H)-one-2,2-dioxide [(C5NH6)(C4H4NO4S)], for short, pyH(ace), was determined by X-ray diffraction methods. It crystallizes as a twin in the monoclinic space group P21/c with a=6.9878(9), b=7.2211(7), c=21.740(2) Å, β=91.67(1)° and Z=4 molecules per unit cell. The structure was determined employing 1599 reflections with I>2σ(I) from one of the twin domains and refined employing 2092 reflections from both crystal domains to an agreement R1 factor of 0.0466. Besides electrostatic attractions, intermolecular pyH···O=C(ace) hydrogen bonds stabilize the acesulfamate anion and the pyridinium cation into planar discrete units parallel to the (100) crystal plane. The units form stacks of alternating ace− and pyH+ ions along the a axis that favors inter-ring π–π interactions. The Fourier transform-infrared (FT-IR) spectrum of the compound was recorded and is briefly discussed. Some comparisons with related pyridinium saccharinate salts are also made.

Synthese und Kristallstruktur von l,13-Bis(8-chinolyl)- 1,4,7,10,13-pentaoxatridecan-diquecksilber(I)-diperchlorat

1991 ◽  
Vol 46 (1) ◽  
pp. 1-4 ◽  
Author(s):  
Klaus Brodersen ◽  
Jörg Zimmerhackl
Keyword(s):  
Crystal Structure ◽  
Aqueous Solution ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
Space Group ◽  
X Ray ◽  
R Value ◽  
Torsional Angles ◽  
L 13 ◽  
Oxygen Atoms

1,13-Bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane-dimercury(I)-diperchlorate is formed by the reaction of 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane in ethanol with an aqueous solution of dimercury(I)-diperchlorate.It crystallizes in the triclinic space group P Ī with a = 1020.6(2), b = 1200.6(8), c = 1441.1(6) pm , α = 69.60(5)°, β = 83.04(13)°, y = 66.53(4)° and Z = 2. The crystal structure was determined by X -ray diffraction and refined to an R-value o f 0.079. The Hg22+ -ion is coordinated to both nitrogen atoms and four oxygen atoms of one molecule of the ligand. By changing four C - O torsional angles from trans to gauche, the ligand adopts a helical, chiral configuration around the Hg22+-ion. The CIO4--ions are not coordinated to the Hg22+-ion.

Synthese und Kristallstruktur von Triphenyltelluroniumsulfid / Synthesis and Crystal Structure of Triphenyltelluroniumsulfide

1994 ◽  
Vol 49 (12) ◽  
pp. 1654-1658 ◽  
Author(s):  
Markus Wieber ◽  
Stefan Lang ◽  
Stefan Rohse ◽  
Ralph Habersack ◽  
Christian Burschka
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Title Compound ◽  
Spectroscopic Characterization ◽  
Unit Cell ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Cell Parameters

The synthesis of triphenyltelluroniumsulfide (Ph3TeS)4 is described together with a NMR-spectroscopic characterization. The structure of the title compound was determined by single crystal X-ray diffraction. Crystals of triphenyltelluroniumsulfide are triclinic (space group P1) with the cell parameters a = 1178.0(3) pm. b = 1295.8(6) pm. c = 1298.7(4) pm, α = 77.67(3)°, β = 82.18(2)°, γ = 66.00(2)° (V = 1766(1) × 106 pm3) and Z = 2. The compound appears to form a step-like structure of two [Ph3TeS]2 units and crystallizes with two molecules of CH2Cl2 per unit cell.

Synthesis and Characterization of a Three-dimensional Porous Compound: [Cu(H2O)6][{Cu(H2O)2}2{Cu(H2O)4H4W12O42}] · 12H2O

2008 ◽  
Vol 63 (2) ◽  
pp. 187-192 ◽  
Author(s):  
Chun-jing Zhang ◽  
Ya-guang Chen ◽  
Dong-mei Shi ◽  
Hai-jun Pang
Keyword(s):  
Aqueous Solution ◽  
Magnetic Susceptibility ◽  
Elemental Analysis ◽  
3D Structure ◽  
Three Dimensional ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Vis Spectroscopy

A novel transition metal polyoxotungstate, [Cu(H2O)6][{Cu(H2O)2}2{Cu(H2O)4H4W12O42}] · 12H2O (1), has been synthesized in aqueous solution and characterized by single-crystal X-ray diffraction, elemental analysis, IR and UV/vis spectroscopy, and TG analysis. The paradodecatungstate anions [H2W12O42]10− are linked by CuO6 octahedra, forming a three-dimensional (3D) structure. The magnetic susceptibility of compound 1 in the temperature range 2 - 300 K shows the presence of antiferromagnetic interactions within the uniform Cu2・ ・ ・Cu3 chains

scholarly journals Synthesis and spectroscopic characterization of some lanthanide(III) nitrate complexes of 3-[3-carboxyethyl-4,5- dimethylthiophene-2-yl)azo]pent-2,4-dione

2011 ◽  
Vol 76 (2) ◽  
pp. 249-261 ◽  
Author(s):  
Janardhanan Athira ◽  
Yesodharan Sindhu ◽  
Susamma Sujamol ◽  
Kochukittan Mohanan
Keyword(s):  
Elemental Analysis ◽  
Metal Ion ◽  
Spectroscopic Characterization ◽  
Molar Conductance ◽  
Spectral Studies ◽  
Structural Form ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nitrate Complexes

3-[3-Carboxyethyl-4,5-dimethylthiophene-2-yl)azo]pent-2,4-dione was synthesized by coupling diazotized 2-amino-3-carboxyethyl- 4,5-dimethylthiophene with acetylacetone. Based on various spectral studies and elemental analysis, an intramolecularly hydrogen bonded azoenol structural form was assigned for the ligand. This ligand is versatile in forming a series of lanthanide(III) complexes viz, lanthanum(III), cerium(III), praseodymium(III), neodymium(III), samarium(III) and gadolinium(III), which were characterized through various spectral studies, elemental analysis, magnetic susceptibility measurements, molar conductance and thermal analysis. The spectral data revealed that the ligand acted as a neutral tridentate, coordinating to the metal ion through one of the azo nitrogen atoms, the ester carbonyl and the enolic oxygen of the acetylacetone moiety, without deprotonation. Molar conductance values adequately supported their non-electrolytic nature. The ligand and lanthanum(III) complexes were subjected to X-ray diffraction studies. In addition, the lanthanum(III) complex underwent a facile transesterification reaction on refluxing with methanol for a long period. The thermal behavior of the lanthanum(III) complex was also examined.

Darstellung und spektroskopische Charakterisierung von (η3-Hexahydro-closo-hexaborato)phenylquecksilber(1-) [Hg(η3-B6H6)Ph] sowie Kristallstruktur von [PPh4][Hg(η3-B6H6)Ph] / Preparation and Spectroscopic Characterization of (η3-Hexahydro-closo-hexaborato)phenylmercury(1 -) [Hg(η3-B6H6)Ph]- and Crystal Structure of [PPh4][Hg(η3-B6H6)Ph]

1997 ◽  
Vol 52 (1) ◽  
pp. 57-60 ◽  
Author(s):  
T. Schaper ◽  
W. Preetz
Keyword(s):  
Crystal Structure ◽  
Diffraction Analysis ◽  
Spectroscopic Characterization ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Lower Field ◽  
Nmr Spectrum ◽  
X Ray ◽  
Ir And Raman

By reaction of [B6H7]- with PhHg(CH3COO) in dichloromethane [Hg(η3-B6H6)Ph]- is formed. The crystal structure of [PPh4][Hg(η3-B6H6)Ph] has been determined by single crystal X-ray diffraction analysis; monoclinic space group P 21/c with a = 9.567(5) Å, b = 22.213(5) Å, c = 14.296(5) Å, β = 94.484(5)°. The 11B NMR spectrum exhibits a doublet at -9.9 ppm shifted to lower field as compared with [B6H7]- and the 199Hg NMR spectrum a singlet at -74.5 ppm. In the IR and Raman spectra characteristic B-H vibrations are observed

Darstellung und spektroskopische Charakterisierung von Methylnitro-closo-hexaboraten sowie Kristallstrukturen von cis-(Ph4As)2[B6H4(CH3)(NO2)],fac-(Ph4As)2[B6H3(CH3)(NO2)2] · CH3CN und mer-(Ph4P)2[B6H3(CH3)(NO2)C2] / Synthesis and Spectroscopic Characterization of Methylnitro-closo-hexaborates and Crystal Structures of cis -(Ph4As)2[B6H4(CH3)(NO2)],fac-(Ph4As)2[B6H3(CH3)(NO2)2] · CH3CN and mer-(Ph4P)2[B6H3(CH3)(NO2)C2]

1999 ◽  
Vol 54 (3) ◽  
pp. 349-356 ◽  
Author(s):  
C. Drewes ◽  
W. Preetz
Keyword(s):  
Nmr Spectra ◽  
Spectroscopic Characterization ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Dichloromethane Solution ◽  
Triclinic Space Group ◽  
Space Group ◽  
X Ray ◽  
Cis And Trans

By electrochemical oxidation of (n-Bu4N)[B6H6(CH3)] in the presence of nitrite ions and of the base DBU in dichloromethane solution cis- and trans-[B6H4(CH3)(NO2)]2- , fac- [B6H3(CH3)(NO2)2]2- and mer-[B6H3(CH3)(NO2)c2]2- are formed. X-ray diffraction analyses have been performed on single crystals of cis-(Ph4As)2[B6H4(CH3O)(NO2)] (1) (monoclinic, space group P21/a, a = 20.063(2), b = 10.858(1), c =21.384(2) Å, β = 105.818(9)°, Z = 4), fac-(Ph4As)2[B6H3(CH3)(NO2)2] ·CH3CN (2) (triclinic, space group P1̄, a = 10.333(3), b = 10.695(3), c = 22.833(6) Å, α = 93.91(3), β = 96.79(3), γ = 104.56(2)°, Z = 2), and mer-(Ph4P)2[B6H3(CH3)(NO2)c2] (3) (triclinic, space group P1̄, a - 10.100(1), b = 10.402(3), c = 22.923(3) Å, α = 96.328(18), β = 89.928(12), γ = 107.963(16)°, Z = 2). The 11B NMR spectra and the vibrational spectra of the methylnitro compounds are discussed and compared with those of the monomethyl- and mononitro-closo-hexaborates.

Synthesis and Crystal Structure of a Novel Polymeric Lead(II) Complex with Thiosemicarbazonato and Thiocyanate Ligands

2001 ◽  
Vol 56 (6) ◽  
pp. 517-520 ◽  
Author(s):  
Alfonso Castiñeiras ◽  
Ricardo Domínguez ◽  
Leandro Bresolin ◽  
Jairo Bordinhão ◽  
Adaílton João Bortoluzzi ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Single Crystal ◽  
Elemental Analysis ◽  
Lead Atom ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Polymeric Chains

AbstractA novel heptacoordinated thiosemicarbazonato lead(II) complex [Pb(4ML)(SCN)] (4ML = 2-Acetylpyridine-4N-methylthiosemicarbazonato) was synthesized and characterized by conventional methods (IR and elemental analysis) and single-crystal X-ray diffraction. [Pb(4ML)(SCN)] shows an unusual polymeric structure in which the lead atom is hexa-coordinate, the deprotonated thiosemicarbazone both chelates and bridges, and the thiocyanate group acts as bridge between lead(II)-thiosemicarbazonate fragments. There is hydrogen-bonding between the polymeric chains. The complex crystallizes in the triclinic space group P 1̅̅ with a = 7.461(2), b = 9.572(2), c = 11.235(2) Å, α = 66.51(3), β = 84.01(3), γ = 68.75(3)°, V = 685.1(2) Å3, Z = 2.

scholarly journals The Reduction of Pyridine by K12Si17 to the 4,4′-Bipyridine Radical Anion [C10H8N2]-•: Crystal Structure and Spectroscopic Characterization of [K([2.2.2]crypt)][C10H8N2]

2014 ◽  
Vol 69 (11-12) ◽  
pp. 1119-1123 ◽  
Author(s):  
Christian B. Benda ◽  
Thomas F. Fässler
Keyword(s):  
Crystal Structure ◽  
Radical Anion ◽  
Spectroscopic Characterization ◽  
X Ray Diffraction ◽  
Compound K ◽  
Zintl Phase ◽  
X Ray ◽  
Vis Spectroscopy ◽  
C Nmr

Abstract From an anhydrous pyridine extract of the binary Zintl phase K12Si17 in the presence of the cation sequestering agent [2.2.2]crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) crystals of the compound [K([2.2.2]crypt)][C10H8N2] have been isolated which contains the 4,4′- bipyridine radical monoanion. This compound was fully characterized by X-ray diffraction, 1H, 13C NMR, EPR, IR and UV=Vis spectroscopy

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