Infrared and Raman Spectroscopic Study of Isocytosine

Abstract Isocytosine and isocytosine-d3 crystals have been investigated at 300 K, 90 K, and 10 K by infrared spectroscopy; the Raman spectra of crystals and solutions in H2O , D2O have also been studied. Using these data and the frequency group approximation we propose assignments of the fundamental molecular frequencies. Eleven lattice vibration frequencies have been observed in absorption and nine in diffusion.

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Hydrogen Bonds: Raman Spectroscopic Study

International Journal of Molecular Sciences ◽

10.3390/ijms22105380 ◽

2021 ◽

Vol 22 (10) ◽

pp. 5380

Author(s):

Boris A. Kolesov

Keyword(s):

Hydrogen Bonding ◽

Hydrogen Bonds ◽

Spectroscopic Study ◽

Raman Spectra ◽

Temperature Region ◽

Vibrational Frequency ◽

Chemical Compounds ◽

Raman Spectroscopic ◽

Raman Spectroscopic Study ◽

Proton Dynamics

The work outlines general ideas on how the frequency and the intensity of proton vibrations of X–H×××Y hydrogen bonding are formed as the bond evolves from weak to maximally strong bonding. For this purpose, the Raman spectra of different chemical compounds with moderate, strong, and extremely strong hydrogen bonds were obtained in the temperature region of 5 K–300 K. The dependence of the proton vibrational frequency is schematically presented as a function of the rigidity of O-H×××O bonding. The problems of proton dynamics on tautomeric O–H···O bonds are considered. A brief description of the N–H···O and C–H···Y hydrogen bonds is given.

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A Raman spectroscopic study of the natural carbonophosphates Na3MCO3PO4 (M is Mn, Fe, and Mg)

European Journal of Mineralogy ◽

10.5194/ejm-33-283-2021 ◽

2021 ◽

Vol 33 (3) ◽

pp. 283-297

Author(s):

Evgeniy Nikolaevich Kozlov ◽

Ekaterina Nikolaevna Fomina ◽

Vladimir Nikolaevich Bocharov ◽

Mikhail Yurievich Sidorov ◽

Natalia Sergeevna Vlasenko ◽

...

Keyword(s):

Spectroscopic Study ◽

General Formula ◽

Raman Spectra ◽

Crystallographic Orientation ◽

Energy Dispersive ◽

X Ray ◽

Raman Spectroscopic ◽

Raman Spectroscopic Study ◽

Vibrational Bands

Abstract. Raman spectra of three natural carbonophosphates (sidorenkite, bonshtedtite, and bradleyite) with the general formula Na3MCO3PO4 (M is Mn, Fe, and Mg) were studied and compared. These spectra showed from 21 to 24 vibrational bands, of which the two most intense (964±5 and 1074±3 cm−1) correspond to the υ1(P–O) and υ1(C–O) modes. These two bands split into doublet peaks due to the occurrence of isomorphic impurities. It was found that the crystallographic orientation of the sample influences the intensity of most bands. Most bands assigned to the same vibrations showed a regular shift (the smallest in sidorenkite spectra, an intermediate in bonshtedtite, and the largest in bradleyite). We propose an algorithm that allows for diagnostics of carbonophosphates in inclusions by their Raman spectra, providing a reliable result even in the absence of energy-dispersive X-ray spectroscopy (EDX) data.

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RAMAN SPECTROSCOPIC STUDY OF THE DIFFERENT CRYSTALLOGRAPHIC FACES OF YBa2Cu3O6+δ SINGLE CRYSTALS IN THE TETRAGONAL AND ORTHORHOMBIC PHASES

Modern Physics Letters B ◽

10.1142/s0217984991001556 ◽

1991 ◽

Vol 05 (19) ◽

pp. 1275-1279

Author(s):

S. M. RAO ◽

B. H. LOO ◽

R. E. BREWSTER ◽

J. M. CHANG

Keyword(s):

Spectroscopic Study ◽

Single Crystals ◽

Raman Spectra ◽

Raman Spectroscopic ◽

Raman Spectroscopic Study ◽

Two Phases

Raman spectra recorded on different crystallographic faces of the YBa 2 Cu 3 O 6+δ crystals in both the tetragonal and orthorhombic phases are presented which show that the spectra differ for the (001) face in the two phases.

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A Raman spectroscopic study of uranyl minerals from Cornwall, UK

RSC Advances ◽

10.1039/c4ra09361e ◽

2014 ◽

Vol 4 (103) ◽

pp. 59137-59149 ◽

Cited By ~ 19

Author(s):

R. J. P. Driscoll ◽

D. Wolverson ◽

J. M. Mitchels ◽

J. M. Skelton ◽

S. C. Parker ◽

...

Keyword(s):

Spectroscopic Study ◽

Raman Spectra ◽

Raman Spectroscopic ◽

Raman Spectroscopic Study

Raman spectra have been collected using three excitation wavelengths for thirteen uranyl mineral samples, including novác̆ekite, and analysed.

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Raman spectroscopic study on the equilibrium of carbon dioxide in aqueous monoethanolamine

RSC Advances ◽

10.1039/c5ra22926j ◽

2016 ◽

Vol 6 (13) ◽

pp. 10816-10823 ◽

Cited By ~ 8

Author(s):

M. K. Wong ◽

A. M. Shariff ◽

M. A. Bustam

Keyword(s):

Carbon Dioxide ◽

Spectroscopic Study ◽

Raman Spectra ◽

Chemical Species ◽

Raman Spectroscopic ◽

Raman Spectroscopic Study ◽

Major Chemical

Raman spectra of aqueous monoethanolamine of various loadings showing peak evolvement for six major chemical species.

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A RAMAN SPECTROSCOPIC STUDY OF RE2BaCuO5 WHERE RE = Y, Sm, Eu, Gd, Dy, Ho, Er, Tm, and Lu

Modern Physics Letters B ◽

10.1142/s0217984989002107 ◽

1989 ◽

Vol 03 (18) ◽

pp. 1401-1407 ◽

Cited By ~ 7

Author(s):

B. H. LOO ◽

D. H. BURNS ◽

A. L. XIDIS

Keyword(s):

Rare Earth ◽

Rare Earth Elements ◽

Spectroscopic Study ◽

Raman Spectra ◽

Raman Spectroscopic ◽

Raman Spectroscopic Study

We have prepared and determined the Raman spectra of a class of compounds of formula RE2 BaCuO 5, where RE = Y , Sm, Eu, Gd, Dy, Ho, Er, Tm, and Lu. Other rare-earth elements, Nd, Ce, Tb and Pr, are found not to form this class of compounds.

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