Effective Synthesis of Poly(2,6-Dimethyl-1,4-Phenylene Oxide) Derivatives by Oxidative Coupling Copolymerization of Alkoxyphenols with Copper(II) Catalyst

The oxidative coupling copolymerization between 2,6-dimethylphenol (DMP) and dihydroxynaphthalenes, such as the 2,3- and 2,6-dihydroxynaphthalenes (2,3- and 2,6-DHN), was carried out using a Cu catalyst under an O2 atmosphere. The polymerization was significantly affected by the structure of the comonomer, and the copolymers were efficiently obtained during the copolymerization of DMP and 2,6-DHN. The obtained copolymers containing hydroxyl groups of the DHN unit were further transformed into polymers containing ester and urethane groups. The obtained copolymers containing various functional groups showed a very different solubility from that of the homopolymer of DMP.

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Molecular evolution of a cytochrome P450 for the synthesis of potential antidepressant (2R,6R)-hydroxynorketamine

Chemical Communications ◽

10.1039/d0cc06729f ◽

2021 ◽

Author(s):

Ansgar Bokel ◽

Michael C. Hutter ◽

Vlada B. Urlacher

Keyword(s):

Cytochrome P450 ◽

Molecular Evolution ◽

Cytochrome P450 Monooxygenase ◽

P450 Monooxygenase ◽

Effective Synthesis

Engineered cytochrome P450 monooxygenase CYP154E1 enables the effective synthesis of the potential antidepressant (2R,6R)-hydroxynorketamine via N-demethylation and regio- and stereoselective hydroxylation of (R)-ketamine.

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Cost Effective Synthesis and Fabrication of Phase-Pure Kesterite Cu2-xZn1.3SnS4 P-type Absorber Layer Thin Films by Solvent Based Process Technique for Photovoltaic Solar Energy Applications

International Journal of Emerging Research in Management and Technology ◽

10.23956/ijermt.v7i4.5 ◽

2018 ◽

Vol 7 (4) ◽

pp. 36

Author(s):

B. Khadambari ◽

S. S. Bhattacharya

Keyword(s):

Solar Energy ◽

Renewable Energy Sources ◽

Cost Effective ◽

Absorber Layer ◽

Window Layer ◽

Energy Applications ◽

Process Technique ◽

Absorber Material ◽

Effective Synthesis ◽

P Type

Solar has become one of the fastest growing renewable energy sources. With the push towards sustainability it is an excellent solution to resolve the issue of our diminishing finite resources. Alternative photovoltaic systems are of much importance to utilize solar energy efficiently. The Cu-chalcopyrite compounds CuInS2 and CuInSe2 and their alloys provide absorber material of high absorption coefficients of the order of 105 cm-1. Cu2ZnSnS4 (CZTS) is more promising material for photovoltaic applications as Zn and Sn are abundant materials of earth’s crust. Further, the preparation of CZTS-ink facilitates the production of flexible solar cells. The device can be designed with Al doped ZnO as the front contact, n-type window layer (e.g. intrinsic ZnO); an n-type thin film buffer layer (e.g. CdS) and a p-type CZTS absorber layer with Molybdenum (Mo) substrate as back contact. In this study, CZTS films were synthesized by a non-vaccum solvent based process technique from a molecular-ink using a non toxic eco-friendly solvent dimethyl sulfoxide (DMSO). The deposited CZTS films were optimized and characterized by XRD, UV-visible spectroscopy and SEM.

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Spectrophotometric and Colorimetric Determination of Pharmaceutical by Oxidative Coupling Reaction: A Review

Systematic Reviews in Pharmacy ◽

10.31838/srp.2020.4.91 ◽

2020 ◽

Vol 11 (04) ◽

Keyword(s):

Oxidative Coupling ◽

Coupling Reaction ◽

Colorimetric Determination ◽

Oxidative Coupling Reaction

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An Unprecedented Cyano-Induced Sodium Nitrite-Catalyzed C(sp3)-H and C(sp2)-H Coupling Reaction

Current Organic Synthesis ◽

10.2174/1570179415666180622102458 ◽

2018 ◽

Vol 15 (7) ◽

pp. 989-994 ◽

Cited By ~ 1

Author(s):

Ling Li ◽

Bo Su ◽

Yuxiu Liu ◽

Qingmin Wang

Keyword(s):

Sodium Nitrite ◽

Oxidative Coupling ◽

High Resolution Mass Spectrometry ◽

Coupling Reaction ◽

13C Nmr Spectroscopy ◽

Coupling Reactions ◽

Reaction Conditions ◽

1H And 13C Nmr ◽

Oxidative Coupling Reaction ◽

Oxidative Coupling Reactions

Aim and Objective: During the investigation of sodium nitrite-catalyzed oxidative coupling reaction of aryls, an unprecedented C(sp2)-H and C(sp3)-H coupling of substituted 2-aryl acetonitrile was found. Materials and Methods: The structure of the coupled product was confirmed by 1H and 13C NMR spectroscopy and high-resolution mass spectrometry (HRMS), and comparison of its derivatives with known compounds. The effects of methoxy group in the benzene ring on the reaction were evaluated. Results: The optimized reaction conditions are summarized as follows: CF3SO3H/substrate = 1.5 equiv., NaNO2/substrate = 0.3 equiv., CH3CN as solvent. 2-(4-Methoxyphenyl)acetonitrile and 2-(3,4,5- trimethoxyphenyl)acetonitrile could also generate C(sp2)-H and C(sp3)-H coupling. The coupling reaction occurred as a typical radial mechanism. Conclusion: An unprecedented cyano-induced, NaNO2-catalyzed oxidative C(sp3)-H and C(sp2)-H coupling was reported. The reaction proceeded under very mild conditions, using O2 in the air as terminal oxidant. The unique oxidative manner might provide more inspiration for the development of intriguing oxidative coupling reactions.

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Model of Trust Monitoring and Updating Based on Dynamic Weighted Allocation

Recent Advances in Electrical & Electronic Engineering (Formerly Recent Patents on Electrical & Electronic Engineering) ◽

10.2174/2352096511666180522083726 ◽

2019 ◽

Vol 12 (1) ◽

pp. 79-85

Author(s):

Bin Hu ◽

Yuemin Wu ◽

Min Sun ◽

Zheng Bang Liu ◽

Lin Zhang ◽

...

Keyword(s):

Fuzzy Clustering ◽

Information Entropy ◽

Network Environment ◽

Mathematical Methods ◽

Efficient Operation ◽

Open Network ◽

Dynamic Trust ◽

Effective Synthesis ◽

Effectiveness And Efficiency ◽

And Performance

Backgrounds: In order to guarantee safe and efficient operation interaction in open network environment, a new dynamic trust monitoring and updating model based on behavior context is proposed in this paper. Methods: Setting four behavior attributes such as security, availability, reliability and performance. Then utilizing the fuzzy clustering and information entropy mathematical methods to carry out the effective synthesis on such attributes. Conclusion: The effectiveness and efficiency of the schema are verified by simulation.

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