Synthesis and nitrogen stability of ultrafine titanium carbonitride particles
2007 ◽
Vol 22
(1)
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pp. 233-237
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The ultrafine titanium carbonitride particles (TiC0.5N0.5) with 100 nm in mean size was successfully synthesized by nitridation treatment at ordinary temperatures, 1373∼1473 K of the nanostructured half-stoichiometric titanium carbide (TiC0.5) particles, which were produced by the magnesium reduction of gaseous TiCl4+1/4C2Cl4. In addition, the nitrogen stability for the produced titanium carbonitride particles at various temperatures and vacuum conditions was investigated experimentally and compared with values calculated by an ideal solution model.
1989 ◽
Vol 21
(6)
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pp. 653-665
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1998 ◽
Vol 30
(6)
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pp. 709-712
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1968 ◽
Vol 36
(282)
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pp. 839-849
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1997 ◽
Vol 302
(1-2)
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pp. 193-200
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1991 ◽
Vol 74
(9)
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pp. 2295-2298
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