Synthesis and Characterization of Poly(2,5-benzimidazole) (ABPBI) Grafted Carbon Nanotubes

2009 ◽  
Vol 1240 ◽  
Author(s):  
Ji-Ye Kang ◽  
Su-Mi Eo ◽  
Loon-Seng Tan ◽  
Jong-Beom Baek

AbstractSingle-walled carbon nanotube (SWCNT) and multi-walled carbon nanotube (MWCNT) were functionalized with 3,4-diaminobenzoic acid via “direct” Friedel-Crafts acylation reaction in PPA/P2O5 to afford ortho-diamino-functionalized SWCNT (DIF-SWCNT) and MWCNT (DIF-MWCNT). The resultant DIF-SWCNT and DIF-MWCNT showed improved solubility and dispersibility. To improve interfacial adhesion between CNT and polymer matrix, the grafting of ABPBI onto the surface of DIF-SWCNT (10 wt%) or DIF-MWCNT (10 wt%) was conducted by simple in-situ polymerization of AB monomer, 3,4-diaminobenzoic acid dihydrochloride, in PPA. The resultant ABPBI-g-MWCNT and ABPBI-g-SWCNT showed improved the mechanical and electrical properties.

2017 ◽  
Vol 8 (45) ◽  
pp. 7025-7032 ◽  
Author(s):  
Jiang Xiao ◽  
Junyan Tan ◽  
Rujian Jiang ◽  
Xiongliang He ◽  
Yanzhi Xu ◽  
...  

We present the synthesis and characterization of a pH and redox dual responsive homopolypeptide which can be used as a dual responsive stabilizer to control the aggregation of carbon nanotubes in water.


2008 ◽  
Vol 29 (4) ◽  
pp. 451-457 ◽  
Author(s):  
Te-Cheng Mo ◽  
Hong-Wen Wang ◽  
San-Yan Chen ◽  
Yun-Chieh Yeh

Polymer ◽  
2005 ◽  
Vol 46 (14) ◽  
pp. 5125-5132 ◽  
Author(s):  
Chungui Zhao ◽  
Guanjun Hu ◽  
Ryan Justice ◽  
Dale W. Schaefer ◽  
Shimin Zhang ◽  
...  

2009 ◽  
Vol 620-622 ◽  
pp. 505-508 ◽  
Author(s):  
Yan Wang ◽  
Lian Gao ◽  
Jing Sun ◽  
Yang Qiao Liu

We report the synthesis and characterization of FePt nanoparticles (NPs)/single walled carbon nanotube (SWNTs) nanocomposites, which might have important potential applications to orient CNTs and the development of new catalysts. The crystallite size of FePt NPs is about 2.5-4 nm and the Fe atom content ranges from 50% to 65%. HiPCO SWNTs have been decorated with FePt nanoparticles under mild conditions without any pretreatment. When the bundle size of HiPCO SWNTs is about 20 nm, FePt NPs mostly attach on the sidewalls of SWNTs. The loading of FePt nanoparticles on the SWNTs bundles can be conveniently controlled by adjusting the initial amount of FePt NPs. The nanocomposite showed magnetic properties in a magnetic field. TEM, HRTEM, and EDS spectra were performed to observe the nanostructure of these nanocomposites.


2000 ◽  
Vol 72 (1-2) ◽  
pp. 209-219 ◽  
Author(s):  
Z. L. Wang ◽  
P. Poncharal ◽  
W. A. de Heer

Property characterization of nanomaterials is challenged by the small size of the structure because of the difficulties in manipulation. Here we demonstrate a novel approach that allows a direct measurement of the mechanical and electrical properties of individual nanotube-like structures by in situ transmission electron microscopy (TEM). The technique is powerful in a way that it can be directly correlated to the atomic-scale microstructure of the carbon nanotube with its physical properties, thus providing a complete characterization of the nanotube. Applications of the technique will be demonstrated in measurements of the mechanical properties, the electron field emission, and the ballistic quantum conductance of individual carbon nanotubes. A nanobalance technique is demonstrated that can be applied to measure the mass of a single tiny particle as light as 22 fg (1 f = 10-15 ).


Polymer ◽  
2011 ◽  
Vol 52 (23) ◽  
pp. 5271-5276 ◽  
Author(s):  
Zhong Xie ◽  
Qixin Zhuang ◽  
Qing Wang ◽  
Xiaoyun Liu ◽  
Yi Chen ◽  
...  

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