Mechanical Response of High Performance Polymers: Abpbo, Abpbi and Abpbt

1992 ◽  
Vol 291 ◽  
Author(s):  
Tahir Çağin
Keyword(s):  
High Performance ◽  
Mechanical Response ◽  
High Strength ◽  
Elastic Stiffness ◽  
Theory Of Elasticity ◽  
High Performance Polymers ◽  
Atomistic Modelling ◽  
Tension And Compression ◽  
Finite Theory ◽  
Stiff Chain

ABSTRACTLight weight, high strength fibers and films produced from stiff chain polymers are good candidates for use as structural materials. Over the last decade, considerable success has been achieved in synthesizing high strength fibers and films. Due to their thermal and oxidative stability aromatic heterocyclic stiff chain polymers such as ABPBO, ABPBT, and ABPBI are especially good candidates. We first describe the finite theory of elasticity as applied in atomistic modelling and simulations of anisotropic solids and then use this description to investigate the mechanical response of these crystalline polymers as a function of applied hydrostatic pressure and uniaxial tension and compression along the chain direction in molecular mechanics simulations. In addition to these finite stress-strain experiments, I will also present the results of the first elastic stiffness matrix calculations performed on these high performance polymers.

scholarly journals The Ductile Behavior of High Performance Concrete in Compression

2010 ◽  
Vol 56 (1) ◽  
pp. 3-18 ◽  
Author(s):  
A. P. Fantilli ◽  
H. Mihashi ◽  
P. Vallini ◽  
B. Chiaia
Keyword(s):  
High Performance ◽  
Mechanical Response ◽  
High Performance Concrete ◽  
Triaxial Compression ◽  
Confining Pressure ◽  
Inelastic Displacement ◽  
Confinement Stress ◽  
Relative Stress ◽  
Tension And Compression ◽  
Ductile Behavior

Abstract The ductility of High Performance Concrete (HPC) can develop both in tension and compression. This aspect is evidenced in the present paper by measuring the mechanical response of normal vibrated concrete (NC), self-compacting concrete (SC) and some HPCs cylindrical specimens under uniaxial and triaxial compression. The post-peak behaviour of these specimens is defined by a non-dimensional function that relates the inelastic displacement and the relative stress during softening. Both for NC and SC, the increase of the fracture toughness with the confinement stress is observed. Conversely, all the tested HPCs, even in absence of confinement, show practically the same ductility measured in normal and self-compacting concretes with a confining pressure. Thus, the presence of HPC in compressed columns is itself sufficient to create a sort of active distributed confinement.

Ultimate Properties of Polymer Chains

1993 ◽  
Vol 305 ◽  
Author(s):  
W. Wade Adams ◽  
Ruth Pachter ◽  
Peter D. Haaland ◽  
Thomas R. Horn ◽  
Scott G. Wierschke ◽  
...  
Keyword(s):  
Smart Materials ◽  
High Performance ◽  
Mechanical Response ◽  
Alpha Helix ◽  
Polymer Chains ◽  
Single Chain ◽  
Tension And Compression ◽  
Rigid Rod ◽  
Different Response ◽  
Semi Empirical

AbstractNew polymers with exceptional properties are needed for applications in high-performance structures, novel electrical, optical and electro-optical devices, and for multi-functional smart materials. Concurrently, new computational capabilities and methods for properties prediction and analysis have enabled the study of a variety of polymer chain architectures to examine the principles that govern their high-performance properties. By semi-empirical and ab initio computational methods, flexible, stiff-chain, rigid-rod, and biological structures could be analyzed. Single chain molecular stress-strain curves for axial tension and compression were calculated, and the strain dependence of the molecular modulus and vibrational frequencies were compared to measurements of molecular deformation, such as IR and Raman spectroscopy. However, of special interest is the distinctly different response of alpha-helical biopolymer chains to strain. Indeed, in this study we compare on a theoretical basis the ‘spring-like’ microscopic mechanical response of alpha-helical biopolymers having a reinforcing intra-molecular hydrogen bonding network to analogous synthetic extended chain polymers, especially poly(para-phenylene terephthalamide) (PPTA) [KEVLARTM]. The theoretical verification of the absence of compressive buckling in alpha-helical biopolymer chains rationalizes the molecular elasticity and resistance to ‘kinking’ of those strands, manifested by the prevalence in Nature for coiled coils. The understanding of the structure-tofunction relationship in biopolymers explaining the role of the alpha-helix in these systems as a requirement for superior compressive mechanical properties, may enable new guidance for the synthesis of motifs consistent with molecular frameworks optimized by Nature.

Two-stage self-seeding method for preparation of single crystals of poly(phenylene sulfide)

1989 ◽  
Vol 47 ◽  
pp. 368-369
Author(s):  
Sengshiu Chung ◽  
Peggy Cebe
Keyword(s):  
Single Crystals ◽  
High Performance ◽  
Dilute Solution ◽  
Two Stage ◽  
Annealing Behavior ◽  
High Performance Polymers ◽  
Seeding Method ◽  
Phenylene Sulfide

We are studying the crystallization and annealing behavior of high performance polymers, like poly(p-pheny1ene sulfide) PPS, and poly-(etheretherketone), PEEK. Our purpose is to determine whether PPS, which is similar in many ways to PEEK, undergoes reorganization during annealing. In an effort to address the issue of reorganization, we are studying solution grown single crystals of PPS as model materials.Observation of solution grown PPS crystals has been reported. Even from dilute solution, embrionic spherulites and aggregates were formed. We observe that these morphologies result when solutions containing uncrystallized polymer are cooled. To obtain samples of uniform single crystals, we have used two-stage self seeding and solution replacement techniques.

CHEMICAL CONVERSION OF 2.4.6-TRINITROTOLUENE (TNT) TO NEW HIGH PERFORMANCE POLYMERS

2002 ◽  
Vol 5 (1-6) ◽  
pp. 1031-1047
Author(s):  
A. L. Rusanov ◽  
L. G. Komarova ◽  
M. P. Prigozhina ◽  
V. A. Tartakovsky ◽  
S. A. Shevelev ◽  
...  
Keyword(s):  
High Performance ◽  
Chemical Conversion ◽  
High Performance Polymers

BERYLCO 25

Alloy Digest ◽  
1973 ◽  
Vol 22 (9) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Physical Properties ◽  
Tensile Properties ◽  
Copper Alloy ◽  
High Performance ◽  
High Strength ◽  
Heat Treating ◽  
Beryllium Copper

Abstract BERYLCO 25 is the standard high-performance beryllium copper alloy most widely used because of its high strength, hardness and excellent spring characteristics. BERYLCO 25 is the updated version of BERYLCO 25S (Alloy Digest Cu-3, November 1952). This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Cu-271. Producer or source: Kawecki Berylco Industries Inc..

ARMCO PH 13-8Mo

Alloy Digest ◽  
1990 ◽  
Vol 39 (2) ◽  
Keyword(s):  
Fracture Toughness ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Physical Properties ◽  
Stress Corrosion ◽  
Tensile Properties ◽  
High Performance ◽  
High Strength ◽  
Heat Treating ◽  
Temperature Performance

Abstract ARMCO PH 13-8Mo is designed for high-performance applications requiring high strength coupled with excellent resistance to corrosion and stress corrosion. It has excellent toughness, good transverse properties and excellent forgeability. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on low and high temperature performance, and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SS-224. Producer or source: Baltimore Specialty Steels Corporation. Originally published May 1969, revised February 1990.

STRENX 100

Alloy Digest ◽  
2019 ◽  
Vol 68 (2) ◽  
Keyword(s):  
Yield Strength ◽  
Physical Properties ◽  
Structural Steel ◽  
Tensile Properties ◽  
High Performance ◽  
High Strength ◽  
Minimum Yield

Abstract Strenx 100 is a high-strength, high-performance structural steel with a minimum yield strength of 690 MPa (100 ksi). It meets the requirements of ASTM A514 Grade S. Strenx 100 is a US Customary steel similar to Strenx 700 (Alloy Digest SA-779, February 2017). This datasheet provides information on composition, physical properties, and tensile properties. Filing Code: SA-838. Producer or source: SSAB Swedish Steel Inc..

OUTOKUMPU TYPE 630

Alloy Digest ◽  
2016 ◽  
Vol 65 (2) ◽  
Keyword(s):  
Fracture Toughness ◽  
Stainless Steel ◽  
Corrosion Resistance ◽  
Physical Properties ◽  
High Performance ◽  
High Strength ◽  
Heat Treating ◽  
304 Stainless Steel ◽  
Type 304 ◽  
Type 304 Stainless Steel

Abstract Outokumpu Type 630 is a martensitic age hardenable alloy of composition 17Cr-4Ni. The alloy has high strength and corrosion resistance similar to that of Type 304 stainless steel. This datasheet provides information on composition, physical properties, hardness, and tensile properties as well as fracture toughness. It also includes information on corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-1238. Producer or source: Outokumpu High Performance Stainless.

Bestimmung der Dauerhaftigkeit von Hochleistungsbeton mit Hilfe des CDF-Tests / Determination of the durability of high performance concrete by means of CDF-test

1999 ◽  
Vol 5 (1) ◽  
pp. 29-40
Author(s):  
R. Krumbach ◽  
U. Schmelter ◽  
K. Seyfarth
Keyword(s):  
Frost Resistance ◽  
High Strength Concrete ◽  
High Performance ◽  
High Performance Concrete ◽  
High Strength ◽  
Strength Concrete ◽  
Factors Influencing

Abstract Variable obsen>ations concerning frost resistance of high performance concrete have been made. The question arises which are the decisive factors influencing durability under the action of frost and de-icing salt. The proposed experiments are to be carried out in cooperation with F.A.- Finger - Institute of Bauhaus University Weimar. The aim of this study is to determine possible change of durability of high strength concrete, and to investigate the origin thereof. Measures to reduce the risk of reduced durability have to be found.

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