Rapid Processing of Carbon-Carbon Composites by Forced Flow-Thermal Gradient Chemical Vapor Infiltration (FCVI)

1994 ◽  
Vol 365 ◽  
Author(s):  
S. Vaidyaraman ◽  
W. J. Lackey ◽  
P. K. Agrawal ◽  
G. B. Freeman ◽  
M. D. Langman

ABSTRACTCarbon fiber-carbon matrix composites were fabricated using the forced flow-thermal gradient chemical vapor infiltration (FCVI) process. Preforms were prepared by stacking 40 layers of plain weave carbon cloth in a graphite holder. The preforms were infiltrated using propylene, propane, and methane. The present work showed that the FCVI process is well suited for fabricating carboncarbon composites; without optimization of the process, we have achieved uniform and thorough densification. Composites with porosities as low as 7% were fabricated in 8–12 h. The highest deposition rate obtained in the present study was ∼3 μm/h which is more than an order of magnitude faster than the typical value of 0.1–0.25 μm/h for the isothermal process. It was also found that the use of propylene and propane as reagents resulted in faster infiltration compared to methane.

1995 ◽  
Vol 10 (6) ◽  
pp. 1469-1477 ◽  
Author(s):  
Sundar Vaidyaraman ◽  
W. Jack Lackey ◽  
Garth B. Freeman ◽  
Pradeep K. Agrawal ◽  
Matthew D. Langman

Carbon fiber-carbon matrix composites were fabricated using the forced flow-thermal gradient chemical vapor infiltration (FCVI) process. The preforms for the infiltration were prepared by stacking 40 layers of carbon cloth in a graphite holder. The preforms were infiltrated with carbon using propylene or methane as a reactant, with hydrogen as a diluent. Composites with porosities as low as 7% have been processed within 8-12 h. The highest deposition rate obtained in the present study was ∼3 μm/h, which is more than an order of magnitude faster than the typical value of 0.1-0.25 μm/h for the isothermal infiltration process.


1991 ◽  
Vol 250 ◽  
Author(s):  
D. P. Stinton ◽  
R. A. Lowden ◽  
T. M. Besmann

AbstractA forced-flow thermal-gradient chemical vapor infiltration process has been developed to fabricate composites of thick-walled tubular geometry common to many components. Fibrous preforms of different fiber architectures (3-dimensionally braided and filament wound) have been investigated to accommodate components with different mechanical property requirements. This paper will discuss the fabrication of tubular, fiber-reinforced SiC matrix composites and their mechanical properties.


Carbon ◽  
1995 ◽  
Vol 33 (9) ◽  
pp. 1211-1215 ◽  
Author(s):  
Sundar Vaidyaraman ◽  
W.Jack Lackey ◽  
Pradeep K. Agrawal ◽  
Garth B. Freeman

1999 ◽  
Vol 5 (S2) ◽  
pp. 798-799
Author(s):  
K.A. Appiah ◽  
Z.L. Wang ◽  
W.J. Lackey

Silicon carbide is a versatile material possessing properties such as a wide energy bandgap, high thermal conductivity, high elastic modulus and high-temperature creep resistance, which enable it to be used in a variety of electronic, optical and structural applications. Chemical vapor infiltration/deposition (CVI/CVD) coupled with the application of a temperature gradient and forced flow of reagents is particularly suited to the production of SiC structural composites due to the benefits of reduced infiltration time and uniform composite density. In this work, the growth and orientation of polycrystalline SiC on graphite during CVI is investigated using TEM and HRTEM.The composites studied possess a laminated matrix of alternating layers of carbon and SiC which were deposited by alternating the reagent streams from one layer to the next. Specimens for TEM examination were obtained by cutting ∽1 mm thickness slices from the bulk sample with a low speed diamond saw.


Carbon ◽  
1996 ◽  
Vol 34 (9) ◽  
pp. 1123-1133 ◽  
Author(s):  
S. Vaidyaraman ◽  
W.J. Lackey ◽  
P.K. Agrawal ◽  
T.L. Starr

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