Chemical durability of high-level waste glass in repository environment: main conclusions and remaining uncertainties from the GLASTAB and GLAMOR projects

2006 ◽  
Vol 932 ◽  
Author(s):  
P. Van Iseghem ◽  
K. Lemmens ◽  
M. Aertsens ◽  
S. Gin ◽  
I. Ribet ◽  
...  
Keyword(s):  
Near Field ◽  
Chemical Durability ◽  
High Level Waste ◽  
Model Parameters ◽  
Residual Rate ◽  
Geological Disposal ◽  
Glass Dissolution ◽  
Geologic Disposal ◽  
High Level

ABSTRACTThis paper reviews the main conclusions of two European Commission funded projects, GLASTAB and GLAMOR, on the durability of HLW glass in geological disposal, and the remaining uncertainties. The progress in GLASTAB relates to the characterization of the alteration layer, the modeling of glass dissolution, the interaction of glass with near field materials, the behaviour of radionuclides, and the calculation of HLW glass dissolution as part of geological disposal. The GLAMOR programme was focused on the decrease of the glass dissolution rate upon achieving silica saturation in solution. Two conclusions from this programme are the importance of the residual rate measured beyond silica saturation and the need to reduce the uncertainties in model parameters. The overall conclusion from the two projects is that strong progress has been achieved on basic dissolution mechanisms and interaction with disposal environments - HLW glass will act as a good barrier to the release of radionuclides in geologic disposal.

Assessing the durability of nuclear glass with respect to silica controlling processes in a clayey underground disposal

2006 ◽  
Vol 932 ◽  
Author(s):  
Laurent De Windt ◽  
Stéphanie Leclercq ◽  
Jan van der Lee
Keyword(s):  
Host Rock ◽  
Reactive Transport ◽  
Transport Model ◽  
Glass Block ◽  
High Level Waste ◽  
Residual Rate ◽  
Glass Dissolution ◽  
Underground Disposal ◽  
High Level

ABSTRACTThe long-term behaviour of vitrified high-level waste in an underground clay repository was assessed by using the reactive transport model HYTEC with respect to silica diffusion, sorption and precipitation processes. Special attention was given to the chemical interactions between glass, corroded steel and the host-rock considering realistic time scale and repository design. A kinetic and congruent dissolution law of R7T7 nuclear glass was used assuming a first-order dissolution rate, which is chemistry dependent, as well as a long-term residual rate. Without silica sorption and precipitation, glass dissolution is diffusion-driven and the fraction of altered glass after 100,000 years ranges from 5% to 50% depending on the fracturation degree of the glass block. Corrosion products may limit glass dissolution by controlling silica diffusion, whereas silica sorption on such products has almost no effect on glass durability. Within the clayey host-rock, precipitation of silicate minerals such as chalcedony may affect glass durability much more significantly than sorption. In that case, however, a concomitant porosity drop is predicted that could progressively reduce silica diffusion and subsequent glass alteration.

Performance Assessment of a High-Level-Waste Repository in Clay

1988 ◽  
Vol 127 ◽  
Author(s):  
Jan L. Marivoet ◽  
Geert Volckaert ◽  
Arnold A. Bonne
Keyword(s):  
Performance Assessment ◽  
Maximum Dose ◽  
High Level Waste ◽  
Clay Layer ◽  
Geological Disposal ◽  
Dose Rates ◽  
Consequence Analysis ◽  
Calculated Dose ◽  
Order Of Magnitude ◽  
High Level

ABSTRACTPerformance assessment studies have been undertaken on the geological disposal of high-level waste in a clay layer in the framework of the CEC project PAGIS. The methodology applied consists of two consecutive steps : a scenario and a consequence analysis. The scenario analysis has indicated that scenarios of normal evolution, of human intrusion, of climatic change, of secondary glaciation effects and of faulting should be evaluated. For the consequence analysis as well deterministic “best estimate” as stochastic calculations, including uncertainty, risk and sensitivity analyses, have been elaborated.The calculations performed show that most radionuclides decay to negligible levels within the first fewjneters of the clay barrier. Just a few radionuclides, 99Tc, 135Cs and 237Np with its daughter nuclides 233U and 229Th can eventually reach the biosphere. The maximum dose rates arising from the geological disposal of HLW, as evaluated by the “best-estimate” approach are about 10−11 Sv/y for river pathways. If the sinking of a water well into the 150 m deep aquifer layer in the vicinity of the repository is considered together with a climatic change, the maximum calculated dose rate rises to a value of 3×10−7 Sv/y. The maximum dose rates evaluated by stochastic calculations are about one order of magnitude higher due to the considerable uncertainties in the model parameters. In the case of the Boom clay the estimated consequences of a fault scenario are of the same order of magnitude as the results obtained for the normal evolution scenario. The maximum risk is estimated from the results obtained through stochastic calculations to be about 5×10−8 per year. The sensitivity analysis has shown that the effective thickness of the clay layer, the retention factors of Tc, Cs and Np, and the Darcy velocity in the aquifer are parameters which strongly influence the calculated dose rates.

Preparation and characterization of vitrified glass matrix for high level waste from MOX fuel processing

2007 ◽  
Vol 353 (52-54) ◽  
pp. 4647-4653 ◽  
Author(s):  
V.S. Yalmali ◽  
D.S. Deshingkar ◽  
P.K. Wattal ◽  
S.R. Bharadwaj
Keyword(s):  
Glass Matrix ◽  
High Level Waste ◽  
Fuel Processing ◽  
Mox Fuel ◽  
High Level

scholarly journals Reactive transport calculations to evaluate sulphide fluxes in the near-field of a SF/HLW repository

2019 ◽  
Vol 98 ◽  
pp. 10005
Author(s):  
Marek Pękala ◽  
Paul Wersin ◽  
Veerle Cloet ◽  
Nikitas Diomidis
Keyword(s):  
Reactive Transport ◽  
Spent Nuclear Fuel ◽  
Near Field ◽  
Opalinus Clay ◽  
High Level Waste ◽  
Waste Containment ◽  
Geological Repository ◽  
High Level ◽  
Reducing Bacteria ◽  
Hlw Repository

Radioactive waste is planned to be disposed in a deep geological repository in the Opalinus Clay (OPA) rock formation in Switzerland. Cu coating of the steel disposal canister is considered as potential a measure to ensure complete waste containment of spent nuclear fuel (SF) and vitrified high-level waste (HLW) or a period of 100,000 years. Sulphide is a potential corroding agent to Cu under reducing redox conditions. Background dissolved sulphide concentrations in pristine OPA are low, likely controlled by equilibrium with pyrite. At such concentrations, sulphide-assisted corrosion of Cu would be negligible. However, the possibility exists that sulphate reducing bacteria (SRB) might thrive at discrete locations of the repository’s near-field. The activity of SRB might then lead to significantly higher dissolved sulphide concentrations. The objective of this work is to employ reactive transport calculations to evaluate sulphide fluxes in the near-field of the SF/HLW repository in the OPA. Cu canister corrosion due to sulphide fluxes is also simplistically evaluated.

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