The Production of Green Diesel Rich Pentadecane (C15) from Catalytic Hydrodeoxygenation of Waste Cooking Oil using Ni/Al2O3-ZrO2 and Ni/SiO2-ZrO2

Hydrodeoxygenation (HDO) is applied in fuel processing technology to convert bio-oils to green diesel with metal-based catalysts. The major challenges to this process are feedstock, catalyst preparation, and the production of oxygen-free diesel fuel. In this study, we aimed to synthesize Ni catalysts supported on silica-zirconia and alumina-zirconia binary oxides and evaluated their catalytic activity for waste cooking oil (WCO) hydrodeoxygenation to green diesel. Ni/Al2O3-ZrO2 and Ni/SiO2-ZrO2 were synthesized by wet-impregnation and hydrodeoxygenation of WCO was done using a modified batch reactor. The catalysts were characterized using X-ray diffraction (XRD), X-ray fluorescence (XRF), and scanning electron microscopy - energy dispersive X-ray spectroscopy (SEM-EDS), and N2 isotherm adsorption-desorption analysis. Gas chromatography - mass spectrometry (GC-MS) analysis showed the formation of hydrocarbon framework n-C15 generated from the use of Ni/Al2O3-ZrO2 with the selectivity of 68.97% after a 2 h reaction. Prolonged reaction into 4 h, decreased the selectivity to 58.69%. Ni/SiO2-ZrO2 catalyst at 2 h showed selectivity of 55.39% to n-C15. Conversely, it was observed that the reaction for 4 h increased selectivity to 65.13%. Overall, Ni/Al2O3-ZrO2 and Ni/SiO2-ZrO2 catalysts produced oxygen-free green diesel range (n-C14-C18) enriched with n-C15 hydrocarbon. Reaction time influenced the selectivity to n-C15 hydrocarbon. Both catalysts showed promising hydrodeoxygenation activity via the hydrodecarboxylation pathway. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Study of the dependences of coal-wood composition, identification of combustion features of the obtained composite materials

In the study of the combustion of samples, it was found that, other things being equal, under the experimental conditions and with the fixed technical characteristics of the fuel, different parameters of the flame are observed, namely, the speed of reaching a stationary mode, the completeness of fuel combustion, the size and distribution of temperature zones strongly depend on the methods used to carry out the mechanical fuel processing. Comparison of the results showed that under the same experimental conditions, the temperature distribution along the length of the experimental stand, in a stationary mode of operation, is higher for the composite fuel. In the case of composite fuel, 70 percent of the fuel burned up was observed at a 1 m section, which is indicative of these fuel consumption and kindling processes at industrial thermal power plants.

IMPLEMENTASI TEKNOLOGI PENGOLAHAN SAMPAH PLASTIK, KARET, DAN STYROFOAM SEBAGAI ENERGI ALTERNATIF

Household waste, especially plastic, styrofoam and used tires, is a problem for the community because it reduces the quality of the environment. In addition, another problem faced by the community is the increase in household expenditure from consuming fuel for cooking. The community service team tries to overcome both of these problems by implementing waste-to-fuel processing technology. Community service activities include training, mentoring, and providing facilities for processing waste into environmentally friendly fuel. The activity was carried out at the Surolaras Waste Bank, Yogyakarta City. The benefits that are felt are reduced waste, fuel products that can be used for household needs, reduced household expenses, and a well-preserved natural environment.