Spatial variation of metals and phosphorus in sediments of a river influenced by urbanization

ABSTRACT The suspended sediments are a special compartment that characterizes the effects of land use in the watershed. Such compartment is able to trap organic compounds as well as metals in general. Spatial variation of concentrations can be accounted for the land use, soil composition and pollution. In this work, we aimed to assess the spatial variation of metals and phosphorus concentration presented in suspended sediments collected in a river under urban occupation. Using time-integrated suspended sediment samplers, samples were collectec in three sites covering different levels of occupation: Almirante Tamandaré (P1) and two in Curitiba city (Tingui Park -P2 and Barigui Park - P3). The sampler was settled to be 20 cm below the water surface and it was removed after 30 days. Twelve samples were collected to examining the following elements Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, La, Mg, Mn, Na, Nb, Ni, P, Pb, Sc, Sn, Sr, Th, Ti, V, Y, Zn and Zr by ICP-OES. The first site is characterized with only 5.73% of urban area; meanwhile the site P3 has the highest urban area 54.06%. Among the twenty seven elements, nineteen showed a positive variation in concentration between collected sites, giving indication that an enrichment of metals along the river. The following elements showed positive variation: P (151.20%), La (117.98%), Cd (93.33%), Cr (71.43%), Na (68.75%), Ni (68.07%), Y (66.67%), Th (63.64%) and Zn (56.77%). Considering local reference values it is concluded that Cd, Cr, Ni, P, Y and Zn appear associated with urbanization increase in the basin; Co, Sc, Sn, Cu and Mn appear possibly associated with urbanization; Ba, La, Na, Pb and Sr show inconclusive behavior in relation with urban influence ; Al, Fe, Nb, Th, Ti, As, Ca, K, Mg, Zr and Va demonstrate not be associated with urbanization.

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Impact of Land-Use Changes on Spatiotemporal Suspended Sediment Dynamics within a Peri-Urban Catchment

Water ◽

10.3390/w12030665 ◽

2020 ◽

Vol 12 (3) ◽

pp. 665 ◽

Cited By ~ 5

Author(s):

C.S.S. Ferreira ◽

R.P.D. Walsh ◽

Z. Kalantari ◽

A.J.D. Ferreira

Keyword(s):

Land Use ◽

Suspended Sediment ◽

Urban Area ◽

Land Use Changes ◽

Suspended Sediments ◽

Sediment Dynamics ◽

Storm Event ◽

Rainfall Condition ◽

Urban Catchments ◽

The Impact

Understanding sediment dynamics in peri-urban catchments constitutes a research challenge because of the spatiotemporal complexity and variability of land-uses involved. This study investigates differences in the concentration of total sediments (TSC) and suspended sediments (SSC) in the small peri-urban Mediterranean Ribeira dos Covões catchment (40% urban area) in central Portugal. Suspended sediment responses at the catchment outlet (E) and in three upstream sub-catchments, during periods of urbanization (2011–2013) and stabilizing land-use (2017–2018) are compared for storm-event datasets encompassing similar ranges of rainstorm sizes and antecedent rainfall condition. The Quinta sub-catchment, with the lowest urban area (22%) but subject to major construction activities affecting 17% of its area, led to highest TSC and SSC during urbanization (attaining 4320 mg/L and 4184 mg/L, respectively), and a median reduction of 38% and 69%, respectively, during stabilization. Espírito Santo sub-catchment, with highest urban area (49%) and minor construction activities, displayed similar median TSC in both periods (258–240 mg/L) but highest SSC reduction (76%), highlighting the impact of the anthropogenic disturbance mainly on fine-particle sediments and a good connectivity with the stream. Porto Bordalo sub-catchment, with 39% urban area and subject to the construction of a four-line road covering 1.5% of its area, showed the lowest TSC and SSC concentrations and the lowest median reductions in both periods (31% and 64%, correspondingly), mainly because of the impact of an unplanned retention basin established with soil from the construction site. Overall, median TSC and SSC reduced 14% and 59% at E, from urbanization to stabilization. Information about sediment dynamics should guide stakeholders in establishing strategies to reduce sediment loads and mitigate the impacts on urban aquatic ecosystems.

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