The Effect of Capillary Forces in a Porous Electrode on Output Current Voltage Characteristics of Fuel Cell with Polymer Proton Exchange Membrane

2007 ◽  
Vol 10 (8) ◽  
pp. 739-750 ◽  
Author(s):  
V. E. Nakoryakov ◽  
Vladimir G. Gasenko
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Porous Electrode ◽  
Capillary Forces ◽  
Proton Exchange ◽  
Output Current ◽  
Current Voltage ◽  
Current Voltage Characteristics ◽  
Exchange Membrane

Modeling and Simulation Study on the Complex Seepage Mechanism of Porous Electrode for a Proton Exchange Membrane Fuel Cell

2011 ◽  
Vol 295-297 ◽  
pp. 1972-1977
Author(s):  
Hui He ◽  
Peng Tao Sun ◽  
You Sheng Xu
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Porous Electrode ◽  
Flow Characteristics ◽  
Equation System ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Chemical Components ◽  
Physical Parameters ◽  
Exchange Membrane

In this paper, a three-dimensional, complex seepage model of a proton exchange membrane fuel cell (PEMFC) is studied, the corresponding finite element method and numerical simulation are given as well, where species transport, fluid flow, charge transport, heat transfer and electrochemical reaction in the PEMFC are simultaneously addressed. The domain to be studied includes porous gas diffusion layers, catalyst layers, gas channels, bipolar plates, and membrane. The fluid transportation phenomena arising in the whole fuel cell are described by the referred model, different physical parameters and source terms are reflected in different areas. The chemical components, flow characteristics and distributions of temperature in the 3-D space are obtained by resolving the seepage control equation system coupled with electrochemical equations. The induced methods and results can guide the optimal design of PEMFC.

Static and Dynamic Current–Voltage Modeling of a Proton Exchange Membrane Fuel Cell Using an Input–Output Diffusive Approach

2016 ◽  
Vol 63 (2) ◽  
pp. 1003-1015 ◽  
Author(s):  
Carlos Restrepo ◽  
Germain Garcia ◽  
Javier Calvente ◽  
Roberto Giral ◽  
Luis Martinez-Salamero
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Input Output ◽  
Current Voltage ◽  
Exchange Membrane

scholarly journals Dynamic Modeling of a Proton-Exchange Membrane Fuel Cell Using a Gaussian Approach

Membranes ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 953
Author(s):  
Catalina González-Castaño ◽  
Leandro L. Lorente-Leyva ◽  
Janeth Alpala ◽  
Javier Revelo-Fuelagán ◽  
Diego H. Peluffo-Ordóñez ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Gaussian Model ◽  
Proton Exchange ◽  
Current Voltage ◽  
Optimization Formulation ◽  
Operating Current ◽  
Long Time ◽  
Current Value ◽  
Exchange Membrane

This paper proposes a Gaussian approach for the proton-exchange membrane fuel cell (PEMFC) model that estimates its voltage behavior from the operating current value. A multi-parametric Gaussian model and an unconstrained optimization formulation based on a conventional non-linear least squares optimizer is mainly considered. The model is tested using experimental data from the Ballard Nexa 1.2 kW fuel cell (FC). This methodology offers a promising approach for static and current-voltage, characteristic of the three regions of operation. A statistical study is developed to evaluate the effectiveness and superiority of the proposed FC Gaussian model compared with the Diffusive Global model and the Evolution Strategy. In addition, an approximation to the exponential function for a Gaussian model simplification can be used in systems that require real-time emulators or complex long-time simulations.

Highly proton conductive membranes based on carboxylated cellulose nanofibres and their performance in proton exchange membrane fuel cells

2019 ◽  
Author(s):  
Valentina Guccini ◽  
Annika Carlson ◽  
Shun Yu ◽  
Göran Lindbergh ◽  
Rakel Wreland Lindström ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Surface Charge ◽  
Proton Exchange Membrane ◽  
Membrane Surface ◽  
Proton Exchange ◽  
Membrane Thickness ◽  
Fuel Cell Performance ◽  
Cellulose Nanofibres ◽  
Exchange Membrane

The performance of thin carboxylated cellulose nanofiber-based (CNF) membranes as proton exchange membranes in fuel cells has been measured in-situ as a function of CNF surface charge density (600 and 1550 µmol g<sup>-1</sup>), counterion (H<sup>+</sup>or Na<sup>+</sup>), membrane thickness and fuel cell relative humidity (RH 55 to 95 %). The structural evolution of the membranes as a function of RH as measured by Small Angle X-ray scattering shows that water channels are formed only above 75 % RH. The amount of absorbed water was shown to depend on the membrane surface charge and counter ions (Na<sup>+</sup>or H<sup>+</sup>). The high affinity of CNF for water and the high aspect ratio of the nanofibers, together with a well-defined and homogenous membrane structure, ensures a proton conductivity exceeding 1 mS cm<sup>-1</sup>at 30 °C between 65 and 95 % RH. This is two orders of magnitude larger than previously reported values for cellulose materials and only one order of magnitude lower than Nafion 212. Moreover, the CNF membranes are characterized by a lower hydrogen crossover than Nafion, despite being ≈ 30 % thinner. Thanks to their environmental compatibility and promising fuel cell performance the CNF membranes should be considered for new generation proton exchange membrane fuel cells.<br>

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