Concrete degradation mechanisms by sulfuric acid attack

2019 ◽  
Vol 71 (7) ◽  
pp. 349-361 ◽  
Author(s):  
Ana Luisa Tavares Torres ◽  
Lourdes Maria Silva de Souza ◽  
Maria Isabel Pais da Silva ◽  
Flávio de Andrade Silva
1970 ◽  
Vol 96 (5) ◽  
pp. 1167-1182
Author(s):  
Alvin H. Meyer ◽  
William B. Ledbetter
Keyword(s):  

2018 ◽  
Vol 10 (10) ◽  
pp. 3769 ◽  
Author(s):  
Victoria García-Vera ◽  
Antonio Tenza-Abril ◽  
Marcos Lanzón ◽  
José Saval

Obtaining durable materials that lengthen the service life of constructions and thereby contribute to sustainability requires research into products that improve the durability of cementitious materials under aggressive conditions. This paper studies the effects of sulfuric acid exposure on four mortar types (control mortar, mortar with nanosilica, mortar with zinc stearate, and mortar with an ethyl silicate coating), and evaluates which of them have better performance against the acid attack. After 28 days of curing, the samples were exposed to a sulfuric acid attack by immersing them in a 3% w/w of H2SO4 solution. Physical changes (mass loss, ultrasonic pulse velocity, open porosity, and water absorption), and mechanical changes (compressive strength) were determined after the sulfuric acid exposure. A scanning electron microscope (SEM) was used to characterize the morphology of the surface mortars after the exposure. The control mortar had the highest compressive strength after the acid attack, although of the four types, the zinc stearate mortar showed the lowest percentage of strength loss. The zinc stearate mortar had the lowest mass loss after the acid exposure; moreover, it had the lowest capillary water absorption coefficient (demonstrating its hydrophobic effect) both in a non-aggressive environment and acid attack.


2019 ◽  
Vol 38 (10) ◽  
pp. 1177-1186 ◽  
Author(s):  
Wei Wang ◽  
Yuan Li ◽  
Kai Yao ◽  
Na Li ◽  
Aizhao Zhou ◽  
...  

2020 ◽  
Vol 1 (2) ◽  
pp. 282-295
Author(s):  
Shima Taheri ◽  
Gerardo Pareja Delgado ◽  
Oluwatoosin B. A. Agbaje ◽  
Paritosh Giri ◽  
Simon Martin Clark

Prolonged exposure to low pH conditions affects the durability of concrete. In this work, the effect of mullite, aluminum silicate, on the strength and the acid corrosion of mortar and concrete under induced accelerated conditions in sulfuric acid solutions at pH of 0.25 and 1 was studied. The characterization of physicochemical changes was performed using techniques including compressive strength, scanning electron microscopy, micro-X-ray fluorescence spectrometry, and the Vickers hardness test. The results indicate that the addition of mullite does not have any significant effect on the overall strength of mortar and concrete samples, while it significantly increases their resistance to corrosion caused by sulfate attack by 90%, therefore, it is expected to increase the life span and decrease the maintenance costs of concrete pipes subjected to acid corrosion in sewer environments. The inhibition efficiency is observed to be sensitive to acid concentration and was improved with increase in the amount of mullite in samples.


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