scholarly journals Increasing the efficiency Proton exchange membrane (PEMFC) & other fuel cells through multi graphene layers including polymer membrane electrolyte

2020 ◽  
Vol 8 (1) ◽  
pp. 95-107
Author(s):  
Azin Chitsazan ◽  
Majid Monajje
Keyword(s):  
Fuel Cells ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Alkaline Electrolyte ◽  
Membrane Thickness ◽  
Graphene Layers ◽  
Electrolyte Membranes ◽  
Polymer Membrane Electrolyte ◽  
Lower Temperature ◽  
Exchange Membrane

Multi layers Graphene has been simulated theoretically for hydrogen storage and oxygen diffusion at a single unit of fuel cell. Ion transport rate of DFAFC, PAFC, AFC, PEMFC, DMFC and SOFC fuel cells have been studied. AFC which uses an aqueous alkaline electrolyte is suitable for temperature below 90 degree and is appropriate for higher current applications, while PEMFC is suitable for lower temperature compared to others. Thermodynamic equations have been investigated for those fuel cells in viewpoint of voltage output data. Effects of operating data including temperature (T), pressure (P), proton exchange membrane water content (λ) , and proton exchange membrane thickness on the optimal performance of the irreversible fuel cells have been studied.Obviously, the efficiency of PEMFC extremely related to amount of the H2 concentration, water activities in catalyst substrates and polymer of electrolyte membranes, temperature, and such variables dependence in the direction of the fuel and air streams.

scholarly journals Modelling and Controlling of ion transport rate efficiency in Proton exchange membrane (PEMFC), alkaline (AFC), direct methanol (DMFC), phosphoric acid (PAFC), direct forming acid(DFAFC) and direct carbon (DCFC) fuel cells

2019 ◽  
Vol 9 (4) ◽  
pp. 4050-4059 ◽  
Keyword(s):  
Fuel Cells ◽  
Ion Transport ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Transport Rate ◽  
Alkaline Electrolyte ◽  
Membrane Thickness ◽  
Lower Temperature ◽  
Exchange Membrane ◽  
Power Curves

Ion transport rate of DFAFC, PAFC, AFC, PEMFC, DMFC and SOFC fuel cells have been studied. AFC which uses an aqueous alkaline electrolyte is suitable for temperature below 90 degree and is appropriate for higher current applications, while PEMFC is suitable for lower temperature compared to others. Thermodynamic equations have been investigated for those fuel cells in viewpoint of voltage output data. Effects of operating data including temperature (T), pressure (P), proton exchange membrane water content (λ) , and proton exchange membrane thickness ( on the optimal performance of the irreversible fuel cells have been studied. Performance of fuel cells was analyzed by simulating polarization and power curves for a fuel cell operating at various conditions with current densities.

Highly proton conductive membranes based on carboxylated cellulose nanofibres and their performance in proton exchange membrane fuel cells

2019 ◽  
Author(s):  
Valentina Guccini ◽  
Annika Carlson ◽  
Shun Yu ◽  
Göran Lindbergh ◽  
Rakel Wreland Lindström ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Surface Charge ◽  
Proton Exchange Membrane ◽  
Membrane Surface ◽  
Proton Exchange ◽  
Membrane Thickness ◽  
Fuel Cell Performance ◽  
Cellulose Nanofibres ◽  
Exchange Membrane

The performance of thin carboxylated cellulose nanofiber-based (CNF) membranes as proton exchange membranes in fuel cells has been measured in-situ as a function of CNF surface charge density (600 and 1550 µmol g<sup>-1</sup>), counterion (H<sup>+</sup>or Na<sup>+</sup>), membrane thickness and fuel cell relative humidity (RH 55 to 95 %). The structural evolution of the membranes as a function of RH as measured by Small Angle X-ray scattering shows that water channels are formed only above 75 % RH. The amount of absorbed water was shown to depend on the membrane surface charge and counter ions (Na<sup>+</sup>or H<sup>+</sup>). The high affinity of CNF for water and the high aspect ratio of the nanofibers, together with a well-defined and homogenous membrane structure, ensures a proton conductivity exceeding 1 mS cm<sup>-1</sup>at 30 °C between 65 and 95 % RH. This is two orders of magnitude larger than previously reported values for cellulose materials and only one order of magnitude lower than Nafion 212. Moreover, the CNF membranes are characterized by a lower hydrogen crossover than Nafion, despite being ≈ 30 % thinner. Thanks to their environmental compatibility and promising fuel cell performance the CNF membranes should be considered for new generation proton exchange membrane fuel cells.<br>

Optimization of the Operating Parameters of a Proton Exchange Membrane Fuel Cell for Maximum Power Density

2005 ◽  
Vol 2 (2) ◽  
pp. 121-135 ◽  
Author(s):  
A. Mawardi ◽  
F. Yang ◽  
R. Pitchumani
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Power Density ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Optimum Operating ◽  
Design Parameters ◽  
Membrane Thickness ◽  
Exchange Membrane

The performance of fuel cells can be significantly improved by using optimum operating conditions that maximize the power density subject to constraints. Despite its significance, relatively scant work is reported in the open literature on the model-assisted optimization of fuel cells. In this paper, a methodology for model-based optimization is presented by considering a one-dimensional nonisothermal description of a fuel cell operating on reformate feed. The numerical model is coupled with a continuous search simulated annealing optimization scheme to determine the optimum solutions for selected process constraints. Optimization results are presented over a range of fuel cell design parameters to assess the effects of membrane thickness, electrode thickness, constraint values, and CO concentration on the optimum operating conditions.

Highly proton conductive membranes based on carboxylated cellulose nanofibres and their performance in proton exchange membrane fuel cells

2019 ◽  
Author(s):  
Valentina Guccini ◽  
Annika Carlson ◽  
Shun Yu ◽  
Göran Lindbergh ◽  
Rakel Wreland Lindström ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Surface Charge ◽  
Proton Exchange Membrane ◽  
Membrane Surface ◽  
Proton Exchange ◽  
Membrane Thickness ◽  
Fuel Cell Performance ◽  
Cellulose Nanofibres ◽  
Exchange Membrane

<p>The performance of thin carboxylated cellulose nanofiber-based (CNF) membranes as proton exchange membranes in fuel cells has been measured in-situ as a function of CNF surface charge density (600 and 1550 µmol g<sup>-1</sup>), counterion (H<sup>+</sup>or Na<sup>+</sup>), membrane thickness and fuel cell relative humidity (RH 55 to 95 %). The structural evolution of the membranes as a function of RH, as measured by Small Angle X-ray scattering, shows that water channels are formed only above 75 % RH. The amount of absorbed water was shown to depend on the membrane surface charge and counter ions (Na<sup>+</sup>or H<sup>+</sup>). The high affinity of CNF for water and the high aspect ratio of the nanofibers, together with a well-defined and homogenous membrane structure, ensures a proton conductivity exceeding 1 mS cm<sup>-1</sup>at 30 °C between 65 and 95 % RH. This is two orders of magnitude larger than previously reported values for cellulose materials and only one order of magnitude lower than Nafion 212. Moreover, the CNF membranes are characterized by a lower hydrogen crossover than Nafion, despite being ≈ 30 % thinner. Thanks to their environmental compatibility and promising fuel cell performance the CNF membranes should be considered for new generation proton exchange membrane fuel cells.</p>

Highly proton conductive membranes based on carboxylated cellulose nanofibres and their performance in proton exchange membrane fuel cells

2019 ◽  
Author(s):  
Valentina Guccini ◽  
Annika Carlson ◽  
Shun Yu ◽  
Göran Lindbergh ◽  
Rakel Wreland Lindström ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Surface Charge ◽  
Proton Exchange Membrane ◽  
Membrane Surface ◽  
Proton Exchange ◽  
Membrane Thickness ◽  
Fuel Cell Performance ◽  
Cellulose Nanofibres ◽  
Exchange Membrane

<p>The performance of thin carboxylated cellulose nanofiber-based (CNF) membranes as proton exchange membranes in fuel cells has been measured in-situ as a function of CNF surface charge density (600 and 1550 µmol g<sup>-1</sup>), counterion (H<sup>+</sup>or Na<sup>+</sup>), membrane thickness and fuel cell relative humidity (RH 55 to 95 %). The structural evolution of the membranes as a function of RH, as measured by Small Angle X-ray scattering, shows that water channels are formed only above 75 % RH. The amount of absorbed water was shown to depend on the membrane surface charge and counter ions (Na<sup>+</sup>or H<sup>+</sup>). The high affinity of CNF for water and the high aspect ratio of the nanofibers, together with a well-defined and homogenous membrane structure, ensures a proton conductivity exceeding 1 mS cm<sup>-1</sup>at 30 °C between 65 and 95 % RH. This is two orders of magnitude larger than previously reported values for cellulose materials and only one order of magnitude lower than Nafion 212. Moreover, the CNF membranes are characterized by a lower hydrogen crossover than Nafion, despite being ≈ 30 % thinner. Thanks to their environmental compatibility and promising fuel cell performance the CNF membranes should be considered for new generation proton exchange membrane fuel cells.</p>

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