This research adopts the important iron electrolysis, removal of the wastewater of high COD, SS, phosphorus pretreatment experiment. Discusses the different iron dosing quantity, iron carbon ratio, and pH value, reaction time on the COD and turbidity, the influence of the phosphorus removal effect. Studies show that iron important electrochemical test in brewery wastewater treatment static optimal processing conditions for: water pH value is 4, 5% dosage of iron filings, 60 min temperature response, COD removal rate was 52.31%. When the iron carbon ratio of 2:1, removing effect is good, can reach 54.53%.