scholarly journals Improvement of phosphorus removal by calcium addition in the iron electrocoagulation process

2017 ◽  
Vol 76 (4) ◽  
pp. 920-927 ◽  
Author(s):  
I. Mishima ◽  
M. Hama ◽  
Y. Tabata ◽  
J. Nakajima

Small-scale wastewater treatment plants (SWTPs) are widely used as decentralized wastewater treatment systems in sparsely populated areas of Japan. Iron electrolysis, an electrocoagulation technology, is installed in these SWTPs for phosphorus removal. Phosphorus can be removed via the formation of an insoluble compound containing phosphate and iron, such as FePO4; however, it was necessary to determine the conditions under which phosphorus can be effectively and stably removed in actual SWTPs. According to previous studies using iron compounds, improved phosphorus removal was obtained by Ca addition. It is therefore thought that calcium addition may also be effective in improving the phosphorus removal during iron electrolysis in SWTPs. It is also important to determine the chemical state of iron to understand the phosphorus removal mechanism during iron electrolysis. In this study, laboratory-scale batch experiments with the iron electrolysis method were conducted to investigate the effect of phosphorus removal using treated wastewater from actual SWTPs without or with Ca addition. The results indicated that the addition of Ca improved the phosphorus removal performance. Furthermore, phosphorus removal was inhibited in the presence of high dissolved organic carbon (DOC). The X-ray absorption fine structure measurements of the produced particulates in the experiments showed no substantial change in the chemical state of iron without or with Ca addition. The statistical analyses revealed the range of improving or inhibiting effects on phosphorus removal due to the Ca and DOC. Thus, the results of this study provided useful information pertaining to the influence of coexisting substances on phosphorus removal and the chemical state of iron in the produced particulates.

2018 ◽  
Vol 78 (6) ◽  
pp. 1304-1311 ◽  
Author(s):  
I. Mishima ◽  
M. Hama ◽  
Y. Tabata ◽  
J. Nakajima

Abstract Small-scale wastewater treatment plants (SWTPs), called Johkasou, are widely used as decentralized and individual wastewater treatment systems in sparsely populated areas in Japan. Even in SWTPs, nutrients should be removed to control eutrophication. An iron electrolysis method is effective to remove phosphorus chemically in SWTPs. However, it is necessary to determine the precise conditions under which phosphorus can be effectively and stably removed in full scale SWTPs for a long period. Therefore, long-term phosphorus removal from SWTPs was investigated and optimum operational conditions for phosphorus removal by iron electrolysis were analyzed in this study. Efficient phosphorus removal can be achieved for a long time by adjusting the amount of iron against the actual population equivalent. The change of the recirculation ratio had no negative effect on overall phosphorus removal. Phosphorus release to the bulk phase was prevented by the accumulated iron, which was supplied by iron electrolysis, resulting in stable phosphorus removal. The effect of environmental load reduction due to phosphorus removal by iron electrolysis was greater than the cost of power consumption for iron electrolysis.


2012 ◽  
Vol 7 (2) ◽  
Author(s):  
T. Kuyama ◽  
M. Mizuochi ◽  
H. Koyanagi ◽  
T. Wako

This study examines the feasibility of the contact aeration method for utilisation in small-scale domestic wastewater treatment facilities in various rural areas of China, where the national government starts to address the water pollution issue. Three pilot facilities using the contact aeration method with different capacities were constructed, operated and monitored in Chongqing city and Jiangsu province. In order to evaluate the feasibility of the constructed facilities, the quality of treated wastewater and the operational cost were monitored. Results obtained from the monitoring showed that BOD and COD effluent concentrations achieved quality targets in all facilities. As for the other pollutants, quality targets were met for most of the period. Operational costs of facilities bettered those set for the facility in the town of Baiyang and new village of Zhaojia, but exceeded them for the facility in the village of Dongbei. The main reasons for the differences were the electricity billing system and operational system for each facility. In order to promote small-scale aeration-based domestic wastewater treatment plants in rural China in the future, the issue of what constitutes efficient facility maintenance first needs to be addressed.


Author(s):  
Julita Šarko ◽  
Aušra Mažeikienė

Nowadays, the problem of water pollution with phosphorus compounds is especially important. Wastewater treatment plants do not always meet the strict requirements for the residual total phosphorus concentration – 1 mg/l in the treated wastewater. Usually individual wastewater treatment plants have a poorer removal of phosphorus from the wastewater because they are more sensitive to fluctuations in wastewater flow and environmental conditions. Research results in the scientific literature shows that only 30–50% of the phosphorus is removed from the wastewater by conventional methods. Additional wastewater treatment is recommended for higher phosphorus removal efficiency achievement. One of the ways to remove phosphorus from wastewater is filtration through sorbents filter media. The efficiency of three sorbents – Filtralite P, foam-glass and crushed shells to remove phosphorus from biologically treated wastewater is investigated in this article. A phosphate phosphorus concentration was reduced by filtering wastewater through sorbents filter media during the experiment. Concentrations of treated wastewater pollutants, filtration rate, efficiency of sorbents to remove phosphorus from the wastewater were measured and evaluated. Experiment results showed that phosphate phosphorus was effectively removed by Filtralite P sorbent (removal efficiency 97–98%), less effective were foam-glass (removal efficiency 66–95%) and crushed shells sorbents (removal efficiency 39–50%).


1990 ◽  
Vol 22 (3-4) ◽  
pp. 211-216
Author(s):  
Niels Skov Olesen

In some areas of Denmark nutrient removal is required even for very small wastewater plants, that is down to 500 pe (pe = person equivalents). The goal for the removal is 80% removal of nitrogen and 90% removal of phosphorus, or in terms of concentrations: 8 mg nitrogen/l and 1.2 mg phosphorus/l. The inlet concentrations are typically 40 mg N/l and 10 mg P/l. The paper presents the results from two such plants with a capacity of 800 pe. Phosphorus removal is made by simultaneous precipitation with ferrous sulphate. Nitrogen removal is carried out using the recirculation method. Both plants were originally rotor aerated oxidation ditches. They have been extended with a denitrification reactor and a recirculation pumping station. At present both plants have been in activity for about 3 years and with satisfactory results. Average concentrations of nitrogen (summer) and phosphorus is 7 mg/l and 0.9 mg/l respectively. Nitrogen removal seems to be a practical solution on these small plants. It is,though, sensitive to temperature and highly oxidized rain water. Phosphorus removal seems to be an easily run and relatively non-sensitive technique at least when using simultaneous precipitation.


1993 ◽  
Vol 28 (10) ◽  
pp. 1-8 ◽  
Author(s):  
A. Gaber ◽  
M. Antill ◽  
W. Kimball ◽  
R. Abdel Wahab

The implementation of urban village wastewater treatment plants in developing countries has historically been primarily a function of appropriate technology choice and deciding which of the many needy communities should receive the available funding and priority attention. Usually this process is driven by an outside funding agency who views the planning, design, and construction steps as relatively insignificant milestones in the overall effort required to quickly better a community's sanitary drainage problems. With the exception of very small scale type sanitation projects which have relatively simple replication steps, the development emphasis tends to be on the final treatment plant product with little or no attention specifically focused on community participation and institutionalizing national and local policies and procedures needed for future locally sponsored facilities replication. In contrast to this, the Government of Egypt (GOE) enacted a fresh approach through a Local Development Program with the United States AID program. An overview is presented of the guiding principals of the program which produced the first 24 working wastewater systems including gravity sewers, sewage pumping stations and wastewater treatment plants which were designed and constructed by local entities in Egypt. The wastewater projects cover five different treatment technologies implemented in both delta and desert regions.


Membranes ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 221
Author(s):  
Rafał Tytus Bray ◽  
Katarzyna Jankowska ◽  
Eliza Kulbat ◽  
Aneta Łuczkiewicz ◽  
Aleksandra Sokołowska

The paper presents the results of research on the use of ultrafiltration, using membranes of 200 and 400 kDa separation, for disinfection of municipal treated wastewater. The research was conducted on a fractional technical scale using real municipal treated wastewater from two large wastewater treatment plants treating most of the wastewater over the one-million polycentric Gdańsk agglomeration (1.2 million inhabitants). UF 200 kDa and UF 400 kDa processes enabled further improvement of the physical and chemical parameters of treated wastewater. Total phosphorus (to below 0.2 mg/L–UF 200 kDa, 0.13 mg/L–UF 400 kDa) and turbid substances (to below 0.2 mg/L, both membranes) were removed in the highest degree. COD was reduced efficiently (to below 25.6 mgO2/L–UF 200 kDa, 26.8 mgO2/L–UF 400 kDa), while total nitrogen was removed to a small extent (to 7.12 mg/L–UF 200 kDa and 5.7 mg/L–UF 400 kDa. Based on the reduction of indicator bacteria; fecal coliforms including E. coli (FC) and fecal enterococci (FE) it was found that the ultrafiltration is an effective method of disinfection. Not much indicator bacterial were observed in the permeate after processes (UF 200 kDa; FC—5 CFU/L; FE—1 CFU/L and UF 400 kDa; FC—70 CFU/L; FE—10 CFU/L. However, microscopic analysis of prokaryotic cells and virus particles showed their presence after the application of both membrane types; TCN 3.0 × 102 cells/mL–UF 200 kDa, 5.0 × 103 cells/mL–UF 400 kDa, VP 1.0 × 105/mL. The presence of potentially pathogenic, highly infectious virus particles means that ultrafiltration cannot be considered a sufficient disinfection method for treated wastewater diverted for reuse or discharged from high load wastewater treatment plants to recreational areas. For full microbiological safety it would be advisable to apply an additional disinfection method (e.g., ozonation).


2021 ◽  
Vol 3 (7) ◽  
Author(s):  
T. S. C. Quintão ◽  
F. G. Silva ◽  
A. L. Pereira ◽  
W. N. Araújo ◽  
P. M. Oliveira ◽  
...  

AbstractHuman enteric viruses, such as enteric adenoviruses (HAdV), are known to be involved with gastrointestinal disorders, especially acute gastroenteritis. Several studies have used HAdV as an indicator of water quality, since they are considered highly stable and widely distributed viruses in water matrices. The aim of this study was to detect and genotype HAdVs in water matrices impacted by discharges of treated effluents from wastewater treatment plants (WWTPs). Wastewater treatment plants from the sanitary system of the Brazilian Federal District were assessed in 2018 and 2019. Samples were collected upstream and downstream from discharge points for each WWTP. Viral concentration based on adsorption-elution and conventional PCR was used for molecular detection, and positive samples were sequenced for phylogenetic analysis. Pluviosity data for the period in which the samples were collected were obtained. Our results demonstrated the presence of HAdVs in 27.2% (61/224) of the samples. The positivity was significantly higher in downstream samples compared to upstream. Moreover, the HAdV positivity was higher in downstream samples collected from receiving water bodies impacted by secondary-level WWTPs in comparison with those impacted by tertiary-level WWTPs. Phylogenetic analysis demonstrated the presence of genotypes 40 and 41, with prevalence of HAdV genotype 41. Despite the predominance of HAdV-41, an increasing frequency of the HAdV-40 was associated with higher pluviosity. In conclusion, this study is the first documentation in the Brazilian Federal District dealing with the prevalence and diversity of HAdVs in several WWTP, along with their correlation with rainfall index.


2021 ◽  
Author(s):  
Adamo R. Petosa ◽  
Monica Nowierski ◽  
Viviane Yargeau

Abstract Bioanalytical tools, namely in vitro bioassays, can be employed in tandem with chemical analyses to assess the efficacy of wastewater treatment and the potential for adverse effects from the discharges of wastewater into receiving waters. In the present study, samples of untreated wastewater (i.e. influent) and treated wastewater (i.e. effluent) were collected from two wastewater treatment plants and a wastewater treatment lagoon serving municipalities in southern Ontario, Canada. In addition, grab samples of surface water were collected downstream of the lagoon discharge. After solid phase extraction (SPE) using ion-exchange columns for basic/neutral and acidic compounds, respectively, the extracts were analyzed for a suite of 16 indicator compounds. The two SPE extracts were combined for analysis of biological responses in four in vitro cell-based bioassays. The concentrations of several indicator compounds, including the estrogens, 17β-estradiol and 17α-ethinylestradiol, were below the limits of detection. However, androstenedione and estrone were detected in several influent samples. The concentrations of these steroid hormones and some of the other indicator compounds declined during treatment but acesulfame K, carbamazepine, trimethoprim and DEET persisted in the effluent. The MTS- CellTiter 96® AQueous One Solution Cell Proliferation Assay (MTS) indicated that cell viability was not affected by exposure to the extracts. The Qiagen Nuclear Receptors 10-Pathway Reporter Array indicated that several cellular pathways were upregulated, with the greatest upregulation observed with the estrogen receptor (i.e. induction ratios 12 to 47) and the liver X receptor (i.e. induction ratios 10 to 45). The ERα CALUX assay indicated that estrogenic activity was lower in effluents compared to influents, with the greatest estrogenic activity observed for grab samples of influent from the lagoon (i.e. 56-215 ng L-1 17β-estradiol equivalents). Finally, the results of the Nrf2 Luciferase Luminescence Assay indicated a lower oxidative stress in the effluent samples. Overall, the present study demonstrates that chemical analyses are limited in their ability to predict or explain reductions in the toxicity of treated wastewater. There are thus advantages to using a combination of chemical analyses and in vitro bioassays to monitor the treatment efficiency of wastewater treatment plants and to predict the potential impacts of wastewater discharges into receiving waters.


Water ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 2764
Author(s):  
Argyro Plevri ◽  
Klio Monokrousou ◽  
Christos Makropoulos ◽  
Christos Lioumis ◽  
Nikolaos Tazes ◽  
...  

Water reuse and recycling is gaining momentum as a way to improve the circularity of cities, while recognizing the central role of water within a circular economy (CE) context. However, such interventions often depend on the location of wastewater treatment plants and the treatment technologies installed in their premises, while relying on an expensive piped network to ensure that treated wastewater gets transported from the treatment plant to the point of demand. Thus, the penetration level of treated wastewater as a source of non-potable supply in dense urban environments is limited. This paper focuses on the demonstration of a sewer mining (SM) unit as a source of treated wastewater, as part of a larger and more holistic configuration that examines all three ‘streams’ associated with water in CE: water, energy and materials. The application area is the Athens Plant Nursery, in the (water stressed) city of Athens, Greece. SM technology is in fact a mobile wastewater treatment unit in containers able to extract wastewater from local sewers, treat it directly and reuse at the point of demand even in urban environments with limited space. The unit consists of a membrane bioreactor unit (MBR) and a UV disinfection unit and produces high quality reclaimed water for irrigation and also for aquifer recharge during the winter. Furthermore, a short overview of the integrated nutrient and energy recovery subsystem is presented in order to conceptualise the holistic approach and circularity of the whole configuration. The SM technology demonstrates flexibility, scalability and replicability, which are important characteristics for innovation uptake within the emerging CE context and market.


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