ANALISIS PENGARUH NILAI KONDUKTIVITAS HIDRAULIK DAN DISPERSIVITAS DINAMIK TERHADAP REMEDIASI AIR TANAH MENGGUNAKAN SIMULASI NUMERIK

Groundwater remediation is one of the solutions to restore the contaminated groundwater. This study was conducted to determine the effect of hydraulic conductivity and dynamic dispersivity on the groundwater remediation effectiveness. As a case study, in 2020, in an area located in Balikpapan, groundwater remediation will be carried out by injecting water containing NaOH through five wells and pumping it back through five wells to form a cycle. The method used is a numerical simulation consisting of groundwater flow simulation, mass transport, and sensitivity analysis. The results show that it takes 124 to 300 days for the injected NaOH to arrive at the pumping wells. The sensitivity analysis results show that when the hydraulic conductivity value is ten times greater, the time required is reduced to 84 to 172 days. Meanwhile, when the dynamic dispersivity is twice larger, the time required is reduced to 75 to 189 days. These results indicate that the groundwater remediation method will be effective for aquifers with high hydraulic conductivity and dynamic dispersivity values. For the study area, the groundwater remediation is suggested to be carried out by increasing the number of injection and pumping wells with a relatively close distance, i.e., around 10 meters, so that NaOH arrives at the pumping wells more quickly.Keywords: groundwater, remediation, hydraulic conductivity, dynamic dispersivity, numerical simulation

Analysis of Hydrogeochemical Characteristics and Origins of Chromium Contamination in Groundwater at a Site in Xinxiang City, Henan Province

Hexavalent chromium contamination in groundwater has become a very serious and challenging problem. Identification of the groundwater chemical characteristics of the sites and their control mechanisms for remediation of pollutants is a significant challenge. In this study, a contaminated site in Xinxiang City, Henan Province, was investigated and 92 groundwater samples were collected from the site. Furthermore, the hydrogeochemical characteristics and the distribution patterns of components in the groundwater were analyzed by a combination of multivariate statistical analysis, Piper diagram, Gibbs diagram, ions ratio and hydrogeochemical simulation. The results showed that the HCO3-Cl-Mg-Ca type, SO4-HCO3-Na type, and HCO3-Mg-Ca-Na type characterize the hydrogeochemical composition of shallow groundwater and HCO3-Cl-Mg-Ca type, HCO3-Na-Mg type, and HCO3-SO4-Mg-Na-Ca type characterize the hydrogeochemical composition of deep groundwater. Ion ratios and saturation index indicated that the groundwater hydrogeochemical characteristics of the study area are mainly controlled by water–rock action and evaporative crystallization. The dissolution of halite, gypsum and anhydrite, the precipitation of aragonite, calcite and dolomite, and the precipitation of trivalent chromium minerals other than CrCl3 and the dissolution of hexavalent chromium minerals occurred in groundwater at the site. The minimum value of pH in groundwater at the site is 7.55 and the maximum value is 9.26. The influence of pH on the fugacity state of minerals was further investigated. It was concluded that the saturation index of dolomite, calcite, aragonite and MgCr2O4 increases with the increase of pH, indicating that these minerals are more prone to precipitation, and the saturation index of Na2Cr2O7, K2Cr2O7 and CrCl3 decreases with the increase of pH, implying that Na2Cr2O7, K2Cr2O7 and CrCl3 are more prone to dissolution. The saturation index of the remaining minerals is less affected by pH changes. The study can provide a scientific basis for groundwater remediation.

Application of Electrochemical Technologies for the Treatment of Industrial Wastewater - An Overview

Environmental engineering, environmental protection and chemical process engineering are today in the avenues of new scientific revelation and deep scientific regeneration. Industrial wastewater treatment and water purification stand in the midst of scientific introspection and scientific comprehension. Both conventional and non-conventional environmental engineering techniques are today the needs of the hour. Non-conventional environmental engineering techniques involve electrochemical treatments and advanced oxidation processes. This review investigates the application of electrochemical technologies for the treatment of industrial wastewater. In the article we have also depicted profoundly the immediate need and the immediate concerns of electrochemical treatments of industrial wastewater. The applications of nanotechnology are also delineated in minute details. The main objective of this article is to elucidate on electrochemical technologies, nanotechnology applications and non- conventional environmental protection methods. The present study deeply deals with various electrochemical technologies in the treatment of industrial wastewater. Various areas of nanomaterials and engineering nanomaterials applications in the treatment of water and wastewater are the other areas of deep scientific research pursuit. Heavy metal groundwater remediation and electrochemical treatments are also dealt with scientific vision and scientific ingenuity in this paper. Arsenic groundwater contamination is a disaster to human life on earth. The authors also stresses on these areas of scientific introspection.

Feasibility of Remediation Lead, Nickel, Zinc, Copper and Cadmium Contaminated Groundwater by Calcium Sulfide

Heavy metals contamination in groundwater often occurs in various industrial processes. Stud-ies have confirmed that polysulfide could reduce hexavalent chromium to trivalent chromium, achieving the effect of in-situ stabilization. For other heavy metals contamination in groundwa-ter, whether polysulfide also had a stabilizing ability to achieve in-situ remediation. This re-search focused on heavy metals except for chromium that often contaminated in groundwater, including lead, nickel, zinc, copper, and cadmium to explore the feasibility of using calcium polysulfide (CaSx) as an in-situ stabilization technology for these heavy metals contamination groundwater. Results showed that CaSx had a great removal efficiency for heavy metals lead, nickel, zinc, copper, and cadmium. However, for nickel, zinc, copper and cadmium, when CaSx was added excessively, complexes would be formed, causing the result of re-dissolve and this would also reduce the removal efficiency. Since it is difficult to accurately control the dosage of agents for in-situ groundwater remediation, the concentration of re-dissolved nickel, zinc, cop-per, and cadmium may not be able to meet the groundwater control standards. CaSx had high lead removal efficiency, and it would not cause re-dissolution due to excessive CaSx dosing. CaSx can be used as an in-situ stabilization technique for lead contaminated groundwater.

Recent Advances of Nanoremediation Technologies for Soil and Groundwater Remediation: A Review

Nanotechnology has been widely used in many fields including in soil and groundwater remediation. Nanoremediation has emerged as an effective, rapid, and efficient technology for soil and groundwater contaminated with petroleum pollutants and heavy metals. This review provides an overview of the application of nanomaterials for environmental cleanup, such as soil and groundwater remediation. Four types of nanomaterials, namely nanoscale zero-valent iron (nZVI), carbon nanotubes (CNTs), and metallic and magnetic nanoparticles (MNPs), are presented and discussed. In addition, the potential environmental risks of the nanomaterial application in soil remediation are highlighted. Moreover, this review provides insight into the combination of nanoremediation with other remediation technologies. The study demonstrates that nZVI had been widely studied for high-efficiency environmental remediation due to its high reactivity and excellent contaminant immobilization capability. CNTs have received more attention for remediation of organic and inorganic contaminants because of their unique adsorption characteristics. Environmental remediations using metal and MNPs are also favorable due to their facile magnetic separation and unique metal-ion adsorption. The modified nZVI showed less toxicity towards soil bacteria than bare nZVI; thus, modifying or coating nZVI could reduce its ecotoxicity. The combination of nanoremediation with other remediation technology is shown to be a valuable soil remediation technique as the synergetic effects may increase the sustainability of the applied process towards green technology for soil remediation.