scholarly journals Geochemical Variability & Implications for Magma Transport at 14°N on the Mid-Atlantic Ridge

Author(s):  
Emma Elizabeth McCully

Observations of seafloor bathymetry and gravity surveys indicate that magma focuses in the center of slow spreading Mid-Ocean Ridge (MOR) segments, however; it is not well constrained how magma is generated, stored, and transported to the segment ends. There are two end-member models for magma transport: 1) a focused magma model wherein the magma upwells beneath the entire ridge axis, is focused and pools beneath the center of the segment, and is then transported towards the segment ends via lateral diking in the shallow crust and 2) a distributed magma model wherein magma vertically upwells and is erupted on the seafloor along the entire segment, but there is enhanced focusing in the segment center. (Figure 1). Both models are supported by the bathymetric and geophysical observations but have different implications for the chemistry of lavas erupted along the segment. To test how lava chemistries vary along a slow-spreading MOR, we systematically sampled a segment of the Mid-Atlantic Ridge. The segment (~14°N) (Figure 2) is known to host Popping Rocks, gas-rich basalts which, upon reaching surface pressures, explode. Two expeditions to this region in 2016 and 2018 collected both ship-based bathymetry (75 m gridded resolution) aboard the R/V Atlantis and high-resolution bathymetry (1 m) from the Autonomous Underwater Vehicle (AUV) Sentry. 27 dives from the Human Occupied Vehicle (HOV) Alvin collected 382 lavas all of which have been analyzed for major element contents, and 162 have been analyzed for trace element contents. During these expeditions, samples were collected both along and across axis from the magmatically robust segment center, through a transition region, to a sparsely magmatic region. Analytical results show that there is significant chemical variability along this segment. For example, there is less variability at the segment center (K/Ti ratios from 0.24 to 0.46 and La/Sm from 2.58 to 3.59) compared to the sparsely magmatic region (K/Ti values from 0.06 to 0.42 and La/Sm). This suggests that magmas erupted at the segment center are more homogeneous compared to lavas erupting in the sparsely magmatic region. Major element contents in each region vary, but on average, become more mafic moving southward away from the magmatically robust segment center towards the sparsely magmatic region. Petrologic modeling of fractional crystallization and trace element contents show that fractional crystallization dominates the chemical variability in the sparsely magmatic region, while either extent of melting or differing mantle sources dominates the variability in the transition regions and the sparsely magmatic region. Reconciling these data with both physical and geophysical observations of a slow spreading ridge, we present a model of magma generation, storage, and transport that is a hybrid of the two proposed models.

Variations in trace element contents and inter-element ratios of deep-sea basalts are much more marked than variations in major element contents. This paper explores possible reasons for the variations which have been discovered. Inadequacy of sampling techniques may be responsible for some reported differences, but variations due to this cause are unlikely to approach the magnitude of reported variations. Some variation in samples from restricted areas of the ocean floor can be correlated with variation in the degree of silica saturation of the basalts. Submarine alteration of lavas by reaction with sea water is another possible cause of variation. Studies of metamorphosed deep-sea basalts suggest that very low-grade metamorphism may cause some, though slight, elemental migration. Studies on ultrabasic rocks show variations in trace element contents which, to some degree, appear to complement the variations encountered in basalts, suggesting that the extent of partial melting in the mantle during basaltic genesis influences the trace element contents of the products of melting. However, when such possible explanations have been considered, there remain variations in trace element contents of otherwise comparable basalts from different parts of the ocean floor, which appear to represent real variations in the trace element contents of the erupted basaltic magmas. In view of the difficulty of explaining such differences by contamination of magmas on their way to the surface, it is suggested that variations exist in the trace element contents of mantle material at the levels of basaltic genesis. Geochemical provinces exist in oceanic areas just as they do in continental regions.


2018 ◽  
Vol 1 (1) ◽  
pp. 1-13

Background: Thyroid cancer is an internationally important health problem. The aim of this exploratory study was to evaluate whether significant changes in the thyroid tissue levels of Ag, Co, Cr, Fe, Hg, Rb, Sb, Sc, Se, and Zn exist in the malignantly transformed thyroid. Methods: Thyroid tissue levels of ten trace elements were prospectively evaluated in 41 patients with thyroid malignant tumors and 105 healthy inhabitants. Measurements were performed using non-destructive instrumental neutron activation analysis with high resolution spectrometry of long-lived radionuclides. Tissue samples were divided into two portions. One was used for morphological study while the other was intended for trace element analysis. Results: It was found that contents of Ag, Co, Cr, Hg, and Rb were significantly higher (approximately 12.8, 1.4, 1.6, 19.6, and 1.7 times, respectively) in cancerous tissues than in normal tissues. Conclusions: There are considerable changes in trace element contents in the malignantly transformed tissue of thyroid.


Urolithiasis ◽  
1989 ◽  
pp. 229-231
Author(s):  
J. Hofbauer ◽  
I. Steffan ◽  
H. Schwetz ◽  
G. Vujicic ◽  
O. Zechner

2016 ◽  
Vol 39 (5) ◽  
pp. 1159-1177 ◽  
Author(s):  
R. Jiménez-Ballesta ◽  
F. J. García-Navarro ◽  
S. Bravo ◽  
J. A. Amorós ◽  
C. Pérez-de-los-Reyes ◽  
...  

2011 ◽  
Vol 184 (7) ◽  
pp. 4517-4538 ◽  
Author(s):  
Uwe Buczko ◽  
Rolf O. Kuchenbuch ◽  
Walter Übelhör ◽  
Ludwig Nätscher

1997 ◽  
Vol 61 (405) ◽  
pp. 257-269 ◽  
Author(s):  
Suzanne Y. O'Reilly ◽  
D. Chen ◽  
W. L. Griffin ◽  
C. G. Ryan

AbstractThe proton microprobe has been used to determine contents of Ca, Ti, Ni, Mn and Zn in the olivine of 54 spinel lherzolite xenoliths from Australian and Chinese basalts. These data are compared with proton-probe data for Ni, Mn and Zn in the olivine of 180 garnet peridotite xenoliths from African and Siberian kimberlites. Fe, Mn, Ni and Zn contents are well-correlated; because the spinel lherzolite olivines have higher mean Fe contents than garnet peridotite olivines (average Fo89.6vs. Fo90–92) they also have lower Ni and higher Mn contents. Zn and Fe are well-correlated in garnet peridotite olivine, but in spinel peridotites this relationship is perturbed by partitioning of Zn into spinel. None of these elements shows significant correlation with temperature. Consistent differences in trace-element contents of olivines in the two suites is interpreted as reflecting the greater degree of depletion of Archean garnet peridotites as compared to Phanerozoic spinel lherzolites. Ca and Ti contents of spinel-peridotite olivine are well correlated with one another, and with temperature as determined by several types of geothermometer. However, Ca contents are poorly correlated with pressure as determined by the Ca-in-olivine barometer of Köhler and Brey (1990). This reflects the strong T-dependence of this barometer: the uncertainty in pressure (calculated by this method) which is produced by the ±50°C uncertainty expected of any geothermometer is ca ± 8 kbar, corresponding to the entire width of the spinel-lherzolite field at 900–1200°C.


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