scholarly journals Effect of Iron Modification on the Adsorption Property of Nitrogen Monoxide on Zeolite Y

1998 ◽  
Vol 106 (1229) ◽  
pp. 79-83 ◽  
Author(s):  
Yukichi SASAKI ◽  
Toshiyuki SUZUKI ◽  
Isao TATEYAMA ◽  
Yukari ISIKAWA ◽  
Akira SAJI ◽  
...  
Author(s):  
H. Kinney ◽  
M.L. Occelli ◽  
S.A.C. Gould

For this study we have used a contact mode atomic force microscope (AFM) to study to topography of fluidized cracking catalysts (FCC), before and after contamination with 5% vanadium. We selected the AFM because of its ability to well characterize the surface roughness of materials down to the atomic level. It is believed that the cracking in the FCCs occurs mainly on the catalysts top 10-15 μm suggesting that the surface corrugation could play a key role in the FCCs microactivity properties. To test this hypothesis, we chose vanadium as a contaminate because this metal is capable of irreversibly destroying the FCC crystallinity as well as it microporous structure. In addition, we wanted to examine the extent to which steaming affects the vanadium contaminated FCC. Using the AFM, we measured the surface roughness of FCCs, before and after contamination and after steaming.We obtained our FCC (GRZ-1) from Davison. The FCC is generated so that it contains and estimated 35% rare earth exchaged zeolite Y, 50% kaolin and 15% binder.


2010 ◽  
Vol 38 (3) ◽  
pp. 401-404
Author(s):  
Da-Wei LOU ◽  
Ying-Jie YANG ◽  
Guang HUANG ◽  
Ping-Li PU ◽  
Xin-Qing LEE ◽  
...  

2020 ◽  
Vol 71 (7) ◽  
pp. 175-186
Author(s):  
Doina Lutic ◽  
Danut-Gabriel Cozma

The abundance of some pollutants from the air depend on the geographic area, the human activities intensity, the climate, the season and even on the hour within a day. The nitrogen oxides are the most abundant and most dangerous toxic species from the air, and these emissions are tightly connected to human polluting activities. Therefore, in our work, the first part is assigned for a wide literature search concerning the incidence of the keywords �nitrogen oxide� and searching the connections with other significant related terms and formulas, investigated by the researches worldwide. Then, a statistic approach was applied trying to correlate the values of the concentration in air of nitrogen monoxide, nitrogen dioxide, carbon monoxide, sulfur dioxide, benzene and particulate matter PM10, all of these being generated to a large extent from the exhaust gases from different automotives. The data were collected from the official site of the National Network of Air Quality Monitoring from Romania, and processed by statistical methods, using specific software and methods, in order to find significant differences between the pollutants concentrations values in two neighbor counties (Suceava and Botosani), with relatively similar climate conditions, but different social wealth. The findings of these statistical processing indicate that the PM10 values do not present significant differences between the two locations, neither the time within a day, while the other parameters exhibit distinctions between the values of the other pollutants concentrations in different seasons (summer and winter) and hourly intervals within a day (night, morning, afternoon and evening).


2020 ◽  
Vol 17 (2) ◽  
pp. 117-130 ◽  
Author(s):  
Mehdi Kalhor ◽  
Zohre Zarnegar ◽  
Zahra Seyedzade ◽  
Soodabeh Banibairami

Background: SO3H-functionalized zeolite-Y was prepared and used as a catalyst for the synthesis of 2-aryl-N-benzimidazole-4-thiazolidinones and tri-substituted imidazoles at ambient conditions. Objective: The goals of this catalytic method include excellent yields and high purity, inexpensive procedure and ease of product isolation, the use of nontoxic and heterogeneous acid catalyst, shorter reaction times and milder conditions. Materials and Methods: NMR spectra were recorded on Brucker spectrophotometer using Me4Si as internal standard. Mass spectra were recorded on an Agilent Technology 5975C VL MSD with tripe-axis detector. FTIR spectra were obtained with KBr disc on a galaxy series FT-IR 5000 spectrometer. The surface morphology of nanostructures was analyzed by FE-SEM (EVO LS 10, Zeiss, Carl Zeiss, Germany). BET analysis were measured at 196 °C by a Japan Belsorb II system after the samples were vacuum dried at 150°C overnight. Results: The NSZ was characterized by FT-IR, FESEM, EDX, XRF, and BET. The catalytic activity of NSZ was investigated for synthesis of 1,3-tiazolidin-4-ones in H2O/Acetone at room temperature. Moreover, NSZ was used for synthesis of tri-substituted imidazoles at 60 °C via solvent-free condensation. Different kinds of aromatic aldehydes were converted to the corresponding of products with good to excellent yields. Conclusion: Sulfonated zeolite-Y was as an efficient catalyst for the preparation of N-benzimidazole-2-aryl-1,3- thiazolidin-4-ones and 2,4,5-triaryl-1H-imidazoles. High reaction rates, elimination toxic solvent, simple experimental procedure and reusability of the catalyst are the important features of this protocol.


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