Three-Phase Compositional Modeling With Capillarity in Heterogeneous and Fractured Media

SPE Journal ◽  
2013 ◽  
Vol 18 (06) ◽  
pp. 1150-1168 ◽  
Author(s):  
Joachim Moortgat ◽  
Abbas Firoozabadi

Summary We model for the first time capillarity in fully compositional three-phase flow, with higher-order finite-element (FE) methods. Capillary pressure gradients may be an important driving force, particularly in layered or fractured porous media, which exhibit sharp discontinuities in permeability. We introduce a simple local computation of the capillary pressure gradients, propose a fractional-flow formulation in terms of the total flux, and resolve complications arising from gravity and capillarity in the upwinding of phase fluxes. Fractures are modeled with the crossflow equilibrium concept, which allows large timesteps and includes all physical interactions between fractures and matrix blocks. The pressure and flux fields are discretized by the mixed hybrid finite-element method, and mass transport is approximated by a higher-order local discontinuous Galerkin (DG) method. Numerical-dispersion and grid-orientation effects are significantly reduced, which allows computations on coarser grids and with larger timesteps. The main advantages in the context of this work are the accurate pressure gradients and fluxes at the interface between regions of different permeabilities. The phase compositions are computed with state-of-the-art phase-splitting algorithms and stability analyses to guarantee the global minimum of Gibbs free energy. Accurate compositional simulation motivates the use of an implicit-pressure/explicit-composition (IMPEC) scheme, and we discuss the associated Courant-Friedrichs-Lewy (CFL) condition on the time-steps. We present various numerical examples on both core- and large-scale, illustrating the capillary end effect, capillary-driven crossflow in layered media, and the importance of capillarity in fractured media for three-phase flow.

SPE Journal ◽  
2014 ◽  
Vol 19 (06) ◽  
pp. 1005-1023 ◽  
Author(s):  
R.. Okuno ◽  
Z.. Xu

Summary Mixtures of reservoir oil and carbon dioxide (CO2) can exhibit complex multiphase behavior at temperatures typically less than 120°F, in which a third CO2-rich liquid (L2) phase can coexist with the oleic (L1) and gaseous (V) phases. The three-phase behavior is bounded by two types of critical endpoints (CEPs) in composition space. The lower CEP (LCEP) is a tie line in which the two liquid phases merge in the presence of the V phase, and the upper CEP (UCEP) is a tie line in which the L2 and V phases merge in the presence of the L1 phase. Slimtube tests reported in the literature show that low-temperature oil displacement by CO2 can result in the high displacement efficiency of more than 90% when three phases are present during the displacement. The nearly piston-like displacements can be quantitatively reproduced in numerical simulations when the CEP behavior is properly considered. However, it is uncertain how multicontact miscibility (MCM) is developed through the interaction of flow and three-hydrocarbon-phase behavior. This research presents a detailed analysis of mass conservation on multiphase transitions between two and three phases for the limiting three-phase flow, where the L1 phase is completely displaced by the L2 phase on the LCEP. The analysis indicates that interphase mass transfer on multiphase transitions occurs in the most-efficient way for MCM development. Simple analytical conditions derived for MCM through three phases are applied to 1D fine-scale simulations of CO2 floods by use of four and more components. Results show that the MCM conditions are nearly satisfied when the effect of numerical dispersion is small. MCM is likely developed through three hydrocarbon phases on the LCEP in the cases studied. This is consistent with analytical solutions of water and gas injection presented in the literature, in which MCM is developed on a CEP for the aqueous, V, and L1 phases. For MCM cases in this research, the L2-V two phases are present upstream of the miscible front if the composition path does not go through the UCEP tie line. However, they also can be miscible on the non-L1 edge of the UCEP tie line if the MCM composition path goes through it. Three-phase flow gradually changes to two-phase flow with varying pressure in the presence of numerical dispersion. It is shown that interphase mass transfer on multiphase transitions becomes less efficient during the change until the three-phase region completely disappears.


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