Hydrogen Isotope Effect on Self-Organized Radial Electric Field Criticality During Electron Internal Transport Barrier Formation in Toroidal Plasmas

Author(s):  
Tatsuya Kobayashi ◽  
Akihiro Shimizu ◽  
Masaki Nishiura ◽  
Takeshi Ido ◽  
Shinsuke Satake ◽  
...  

Abstract Self-organized structure formation in magnetically confined plasmas is one of the most attractive subjects in modern experimental physics. Nonequilibrium media are known to often exhibit phenomena that cannot be predicted by superposition of linear theories. One representative example of such phenomena is the hydrogen isotope effect in fusion plasmas, where the larger the mass of the hydrogen isotope fuel is the better the plasma confinement becomes, contrary to what simple scaling models anticipate. In this article, threshold condition of a plasma structure formation is shown to have a strong hydrogen isotope effect. To investigate the underlying mechanism of this isotope effect, the electrostatic potential is directly measured by a heavy ion beam probe. It is elucidated that the positive radial electric field structure can be driven by less input power normalized by plasma density in plasmas with larger isotope mass across the structure formation.

2007 ◽  
Vol 62 (12) ◽  
pp. 721-728 ◽  
Author(s):  
Masahisa Kakiuchi

The D/H ratio of hydrogen gas in equilibrium with aqueous alkaline earth (Mg, Ca, Sr or Ba) chloride solutions measured at 25◦C using a hydrophobic platinum catalyst, was found to be higher than the D/H ratio equilibrated with the applied pure water. The hydrogen isotope effect between such solutions and pure water changes with the molality of the solutions. The order of the D/H ratios in alkaline earth chlorides is found to be BaCl2 > SrCl2 ≥ CaCl2 ≥ MgCl2. The hydrogen isotope effect in the aqueous chloride solutions of Mg, Ca, Sr or Ba ions is significantly larger than that in the aqueous chloride solutions of Li, Na, K or Cs ions. For MgCl2 and CaCl2 solutions, the hydrogen isotope effect is opposite to the oxygen isotope effect. The results are compared with the free energy change of transfer from H2O to D2O, and are discussed for the vapour pressure ratio of H2O and D2O of CaCl2 solutions.


1997 ◽  
Vol 52 (11) ◽  
pp. 811-820 ◽  
Author(s):  
Masahisa Kakiuchi

Abstract The D/H ratios of hydrogen gas in equilibrium with aqueous alkali halide solutions were deter-mined at 25 °C, using a hydrophobic platinum catalyst. The hydrogen isotope effect between the solution and pure water changes linearly with the molality of the solution at low concentrations, but deviates from this linearity at higher concentration for all alkali halide solutions. The magnitude of the hydrogen isotope effect is in the order; Kl > Nal > KBr > CsCl ≧ NaBr > KCl > NaCl > LiCl, at concentrations up to a molality of 4 m. The sign and trend of the hydrogen isotope effect is different from that of oxygen. In aqueous alkali halide solutions, the hydrogen isotope effect is influenced by both the cation and the anion species, while the oxygen isotope effect is mainly caused by the cation species. This suggests that the mechanism of hydrogen isotope fractionation between the water molecules in the hydration spheres and the free water molecules differs from the mechanism of the oxygen isotope fractionation. The hydrogen and oxygen isotope effects for alkali halides, except LiCl and NaCl, may be influenced by changes in energy of the hydrogen bonding in free water molecules.


2010 ◽  
Vol 39 (2) ◽  
pp. 204-208
Author(s):  
Lei Qianghua ◽  
Chen Chang'an ◽  
Huang Li ◽  
Zhang Yongbin

1961 ◽  
Vol 39 (1) ◽  
pp. 180-191 ◽  
Author(s):  
G. E. Dunn ◽  
Peter J. Krueger ◽  
Walter Rodewald

Mixtures of chlorobenzene and chlorobenzene-2-2H have been subjected to partial amination by sodamide in liquid ammonia and both the unreacted starting material and the product aniline have been analyzed for deuterium. Deuterium in the aniline is distributed approximately equally between the ortho and meta positions. The results give strong support to the mechanism proposed by Roberts and co-workers in which the slow step is the formation of an intermediate, such as benzyne, which is symmetrical with respect to carbon atoms 1 and 2.


1980 ◽  
Vol 22 (5) ◽  
pp. 2281-2283
Author(s):  
J. J. Reidy ◽  
H. Daniel ◽  
R. Bergmann ◽  
F. J. Hartmann ◽  
W. Wilhelm

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