scholarly journals Synergistic Excited State involved Catalytic Reduction of (NH3-trz)[Fe(dipic)2] Complex by SnO2/TiO2 Nanocomposite

2022 ◽  
Author(s):  
Venkatesh D ◽  
Pavalamalar S ◽  
Silambarasan R ◽  
Anbalagan K
Keyword(s):  
Photocatalytic Activity ◽  
Model Compound ◽  
Catalytic Reduction ◽  
Ultra Violet ◽  
Structural Features ◽  
Binary Solvent ◽  
Hydrothermal Route ◽  
Ft Ir ◽  
Binary Solvent Systems ◽  
Solvent Systems

Abstract The photocatalytic activity of well-fabricated, economical SnO2/TiO2 nanocomposite synthesized via hydrothermal route was validated using the (NH3-trz)[Fe(dipic)2] complex under ultra-violet illumination. The structural features of (NH3-trz)[Fe(dipic)2] complex was explored in detail. The catalysts were systematically examined with XRD, SEM, FT-IR UV-vis, PL, micro-Raman, VSM, AFM, HRTEM. The photoreactivity of the model compound (NH3-trz)[Fe(dipic)2] in water/binary solvent systems was investigated. The rate of photoreaction (k) of nanocomposite (0.1432 sec-1) is higher than the SnO2 (0.0373 sec-1) and TiO2 (0.1422 sec-1) in H2O:PriOH (70:30%) than the rest of the solvents system. The pathways, mechanistic feature of accumulated reactive species on nanocomposite to induce adherent [Fe(dipic)2]- anion and photo-reductive products were studied. The generation of hydroxyl radical on the surface of each catalyst can be identified as 7-hydroxycoumarin and discussed.

Measurement and Correlation for Solubility of Myo-inositol in Five Pure and Four Binary Solvent Systems

2021 ◽  
Author(s):  
Ying Guo ◽  
Hui He ◽  
Haishuang Huang ◽  
Jingxuan Qiu ◽  
Jiaming Han ◽  
...  
Keyword(s):  
Binary Solvent ◽  
Binary Solvent Systems ◽  
Solvent Systems

Effect of modification of binary solvent molecules on ε-CL-20 crystal morphology: a molecular dynamics study

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yanpeng Zhao ◽  
Guanwen Su ◽  
Guozhao Liu ◽  
Hongyuan Wei ◽  
Leping Dang
Keyword(s):  
Molecular Dynamics ◽  
Molecular Dynamics Simulation ◽  
Crystal Morphology ◽  
Dynamics Simulation ◽  
Binary Solvent ◽  
Binary Solvent Systems ◽  
Solvent Systems ◽  
Solvent Molecules

The effects of thirteen binary solvent systems on the growth of CL-20 were studied by molecular dynamics simulation, and the effect of antisolvent properties on the solvent inhibition was systematically investigated.

scholarly journals A Facile Urea-Assisted Thermal Decomposition Process of TiO2 Nanoparticles and Their Photocatalytic Activity

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 165
Author(s):  
Sandip Madhukar Deshmukh ◽  
Mohaseen S. Tamboli ◽  
Hamid Shaikh ◽  
Santosh B. Babar ◽  
Dipak P. Hiwarale ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Photocatalytic Activity ◽  
Tio2 Nanoparticles ◽  
Large Scale ◽  
Ultra Violet ◽  
Tio2 Nps ◽  
Transmission Electron ◽  
Structures And Properties ◽  
Ft Ir ◽  
Large Scale Synthesis

In the present work, we have reported a facile and large-scale synthesis of TiO2 nanoparticles (NPs) through urea-assisted thermal decomposition of titanium oxysulphate. We have successfully synthesized TiO2 NPs by using this effective route with different weight ratios of titanium oxysulphate: urea. The structures and properties of TiO2 NPs were confirmed by scanning electron microscope) (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), fourier transform infrared spectroscopy (FT-IR), ultra violet–visible spectroscopy (UV-vis), and photoluminescence (Pl) techniques. XRD demonstrated that TiO2 NPs holds of anatase crystal phase with crystallizing size 14–19 nm even after heating at 600 °C. TGA, SEM, and TEM images reveal urea’s role, which controls the size, morphology, and aggregation of TiO2 NPs during the thermal decomposition. These TiO2 NPs were employed for photodegradation of Methyl Orange (MO) in the presence of ultraviolet (UV) radiation. An interesting find was that the TiO2 NPs exhibited better photocatalytic activity and excellent recycling stability over several photodegradation cycles. Furthermore, the present method has a great perspective to be used as an efficient method for large-scale synthesis of TiO2 NPs.

Phase equilibria of rodlike molecules in binary solvent systems

Biopolymers ◽  
1968 ◽  
Vol 6 (7) ◽  
pp. 973-982 ◽  
Author(s):  
Akio Nakajima ◽  
Toshio Hayashi ◽  
Minako Ohmori
Keyword(s):  
Phase Equilibria ◽  
Binary Solvent ◽  
Binary Solvent Systems ◽  
Solvent Systems
Sign in / Sign up

Export Citation Format

Share Document