scholarly journals Schiff Base Functionalized 1,2,4-Triazole and Pyrene Derivatives for Selective and Sensitive Detection of Cu2+ in the Mixed Organic- Aqueous Media

2021 ◽  
Author(s):  
Nam Gyu Choi ◽  
Balasaheb D. Vanjare ◽  
Prasad G. Mahajan ◽  
Rajendran Nagarajan ◽  
Hyang Im Ryoo ◽  
...  
Keyword(s):  
Schiff Base ◽  
Colorimetric Detection ◽  
Aqueous Media ◽  
Stoichiometric Ratio ◽  
Naked Eye ◽  
Lower Detection Limit ◽  
Lower Detection ◽  
Pyrene Derivatives ◽  
Sensitivity And Selectivity

Abstract We have prepared Schiff base functionalized 1,2,4-Triazole and Pyrene derivatives for selective, sensitive, and naked eye colorimetric detection of Cu2+ in the mixed organic- aqueous media. Amongst the 18 different metal ions studied for absorption and fluorescence titration, only Cu2+ ion encourages the modification in spectral properties of Schiff base functionalized 1,2,4-Triazole and Pyrene Probe. The stoichiometric ratio of the Probe-Cu2+ complex was determined to be 2:1 according to Job’s plot. The lower detection limit estimated for Cu2+ is 0.234 nM which shows excellent sensitivity and selectivity of the present analytical method towards detection of Cu2+ ion in the mixed organic-aqueous media. The present approach has been successfully utilized for the quantitative determination of Cu2+ ion from environmental aqueous solution.

Improved Spectrophotometric Determination of Cyclopiazonic Acid in Poultry Feed and Corn

1990 ◽  
Vol 73 (2) ◽  
pp. 257-259 ◽  
Author(s):  
Ivan Chang-Yen ◽  
Keshore Bidasee
Keyword(s):  
Detection Limit ◽  
Spectrophotometric Determination ◽  
Spectrophotometric Method ◽  
Cyclopiazonic Acid ◽  
Poultry Feed ◽  
Reaction Conditions ◽  
Lower Detection Limit ◽  
Lower Detection ◽  
Feed Samples

Abstract An improved visible spectrophotometric method has been developed for cyclopiazonic acid in poultry feed and corn. The method Is based on the reaction of cyclopiazonic acid with Ehrlich reagent and detection at 580 nm. Reaction conditions were optimized with respect to reaction and measurement times and acid and Ehrlich reagent concentrations. Calibration curves were linear from 1 to 20 μg cyclopiazonic acid in 3 mL Ehrlich reagent, with a lower detection limit of 0.08 mg/kg for 50 g samples of poultry feed and corn. Recoveries from 50 g samples of poultry feed spiked with cyclopiazonic ranging from 0.16 to 1.20 mg/kg averaged 93.8%. Moldy corn and poultry feed samples analyzed by this method contained between 1 and 4 mg/kg cyclopiazonic acid.

scholarly journals Colorimetric detection and determination of Fe(III), Co(II), Cu(II) and Sn(II) in aqueous media by acrylic polymers with pendant terpyridine motifs

2016 ◽  
Vol 226 ◽  
pp. 118-126 ◽  
Author(s):  
Miriam Trigo-López ◽  
Asunción Muñoz ◽  
Saturnino Ibeas ◽  
Felipe Serna ◽  
Félix Clemente García ◽  
...  
Keyword(s):  
Colorimetric Detection ◽  
Aqueous Media ◽  
Acrylic Polymers

A reversible fluorescent-colorimetric chemosensor based on a novel Schiff base for visual detection of CO32− in aqueous solution

RSC Advances ◽  
2016 ◽  
Vol 6 (76) ◽  
pp. 72185-72192 ◽  
Author(s):  
Anupam Ghorai ◽  
Jahangir Mondal ◽  
Rukmani Chandra ◽  
Goutam K. Patra
Keyword(s):  
Aqueous Solution ◽  
Schiff Base ◽  
Visual Detection ◽  
Colorimetric Detection ◽  
Aqueous Media ◽  
Rapid Response ◽  
Colorimetric Chemosensor ◽  
Excellent Selectivity

A novel Schiff base receptor L has been fabricated for fluorescent-colorimetric detection of CO32− in aqueous media. L shows an excellent selectivity, rapid response and reversibility and its sensitivity for CO32− is the lowest ever found (96 nM).

scholarly journals Determination of epinephrine by the Briggs-Rauscher oscillating system using non-equilibrium stationary state

2012 ◽  
Vol 77 (1) ◽  
pp. 95-104 ◽  
Author(s):  
Jinzhang Gao ◽  
Yanjun Liu ◽  
Jie Ren ◽  
Xiaoli Zhang ◽  
Li Ming ◽  
...  
Keyword(s):  
Detection Limit ◽  
Stationary State ◽  
Lower Detection Limit ◽  
Highly Sensitive ◽  
Lower Detection ◽  
Oscillating Reaction ◽  
The Difference ◽  
Foreign Species ◽  
Non Equilibrium

A highly sensitive method for the determination of epinephrine was proposed, which was based on the perturbation of epinephrine to Briggs-Rauscher oscillating system involving malonic acid, Mn2+, H+, IO3 - and H2O2 at non-equilibrium stationary state. The concentration of KIO3 was chosen as a control parameter to find the bifurcation point in this paper. Results showed that a well linear relationship between the difference of potential and the negative logarithm concentrations of epinephrine existed in the range of 1.1?10-7?5.2?10-9 mol L-1 with a lower detection limit of 6.8?10-10mol L-1 and a correlation coefficient of 0.9974. Compared to the classical oscillating reaction, this method has a lower detection limit and wider linear range. The effects of some foreign species, which may possibly be existed with epinephrine, on determination were also investigated. The proposed method has been successfully used to determine the epinephrine both in the serum and adrenaline hydrochloride injection.

Analysis of Tri-aryl Phosphate Esters and the Determination of Imol S-140 in Fish Tissue and Water Samples by Gas Chromatography

1975 ◽  
Vol 32 (4) ◽  
pp. 457-460 ◽  
Author(s):  
Derek A. J. Murray
Keyword(s):  
Gas Chromatography ◽  
Detection Limit ◽  
Water Samples ◽  
Fish Tissue ◽  
Phosphate Esters ◽  
Lower Detection Limit ◽  
Lower Detection ◽  
Trimethylsilyl Derivatives ◽  
The Individual

This report describes a method for the analysis of tri-aryl phosphate esters used commercially as lubricants. In a fish toxicity study, Imol S-140 (tri-tolyl phosphate) was extracted from fish tissue and water samples, hydrolyzed, and the individual phenols measured by gas chromatography as the trimethylsilyl derivatives. The lower detection limit was about 3 ppm of Imol in wet fish tissue.

Silica cross-linked nanoparticles encapsulating a phenothiazine-derived Schiff base for selective detection of Fe(iii) in aqueous media

2014 ◽  
Vol 2 (37) ◽  
pp. 6306-6312 ◽  
Author(s):  
Fangyuan Gai ◽  
Xiang Li ◽  
Tianlei Zhou ◽  
Xiaogang Zhao ◽  
Dongdong Lu ◽  
...  
Keyword(s):  
Schiff Base ◽  
Fluorescence Quenching ◽  
Aqueous Media ◽  
Selective Detection ◽  
Selective Determination ◽  
Design And Synthesis ◽  
Micellar Nanoparticles

This work demonstrates the design and synthesis of an ET-based fluorescence quenching chemosensor using silica cross-linked micellar nanoparticles as scaffolds to encapsulate EDDP for highly selective determination of Fe3+ in aqueous media.

Differential assay of zidovudine and its glucuronide metabolite in serum and urine with a radioimmunoassay kit

1990 ◽  
Vol 36 (6) ◽  
pp. 897-900 ◽  
Author(s):  
S M Tadepalli ◽  
L Puckett ◽  
S Jeal ◽  
L Kanics ◽  
R P Quinn
Keyword(s):  
Inhibitory Concentration ◽  
Serum Samples ◽  
Lower Detection Limit ◽  
Coefficients Of Variation ◽  
Lower Detection ◽  
Before And After ◽  
The Difference ◽  
Glucuronide Metabolite ◽  
Serum And Urine

Abstract We developed an ancillary procedure for the ZDV-Trac RIA (Incstar) to allow simultaneous determination of both zidovudine (3'-azido-3'-deoxythymidine, ZDV, AZT, Retrovir) and its metabolite, the glucuronide of ZDV (3'-azido-3'-deoxy-5'-O-beta-D-glucopyranuronosylthymidine, ZDVG, GAZT), in human serum and urine. Using the ZDV-Trac RIA, we measured ZDV concentrations before and after ZDVG in samples was hydrolyzed to ZDV by beta-glucuronidase (EC 3.2.1.31); ZDVG concentration was calculated as the difference between the two results. This method enables rapid evaluation of a large number of samples with a total turn-around time of 6 h. The lower detection limit of the RIA was 0.27 micrograms/L; the measurements varied linearly with ZDV concentrations from 0.27 to 217 micrograms/L, with the 50% inhibitory concentration being approximately 10 micrograms/L. Analytical recoveries of inhouse serum and urine controls for both ZDV and ZDVG exceeded 90%. Coefficients of variation (CVs) of serum controls were less than 6% for ZDV and less than 11% for ZDVG; for urine controls, CVs for both ZDV and ZDVG were less than 6%. Results for ZDVG concentrations obtained by HPLC and by the ZDV-Trac RIA system compared well: r = 0.978, slope 1.0, for serum samples, and r = 0.993, slope 1.09, for urine samples.

Analysis of Ochratoxins A and B and Their Esters in Barley, Using Partition and Thin Layer Chromatography. I. Development of the Method

1973 ◽  
Vol 56 (4) ◽  
pp. 817-821 ◽  
Author(s):  
Stanley Nesheim ◽  
Nicole F Hardin ◽  
Octave J Francis ◽  
William S Langham
Keyword(s):  
Sodium Bicarbonate ◽  
Diatomaceous Earth ◽  
Average Recovery ◽  
Aqueous Sodium ◽  
Lower Detection Limit ◽  
Aqueous Sodium Bicarbonate ◽  
Lower Detection ◽  
Tlc Plates ◽  
Layer Chromatography

Abstract A convenient, specific, rapid method, developed for the determination of ochratoxin in barley, involves initial extraction of the sample with water-chloroform (1+9), followed by chromatography of the extract on an aqueous sodium bicarbonate-diatomaceous earth column. The ochratoxin esters are removed from the column with hexane-chloroform. Elution of the column with formic acid-chloroform (1+99) yields ochratoxins A and B. The ochratoxin esters are purified further on an aqueous sodium bicarbonate-methanol-diatomaceous earth column. The extracts are then quantitated on TLC plates by measuring fluorescence intensity. The presence of ochratoxins A and B is confirmed through formation of the corresponding ethyl ester derivatives. In an intralaboratory study, in which samples spiked at 25, 50, and 100 μg/kg levels were analyzed by 4 analysts, the average recovery for ochratoxin A was 81.2% with a lower detection limit of 12 μg/kg.

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