Benzyl Alcohol-Water and -Ammonia Clusters: Ion Fragmentation and Chemistry.

1992 ◽  
Author(s):  
S. Li ◽  
E. R. Bernstein
Keyword(s):  
Benzyl Alcohol ◽  
Ion Fragmentation ◽  
Alcohol Water ◽  
Ammonia Clusters

Study of the Phase Diagram of the CTAB/Benzyl Alcohol/Water System

1995 ◽  
Vol 172 (2) ◽  
pp. 494-501 ◽  
Author(s):  
Gemma Montalvo ◽  
Mercedes Valiente ◽  
Elvira Rodenas
Keyword(s):  
Phase Diagram ◽  
Benzyl Alcohol ◽  
Water System ◽  
Alcohol Water

scholarly journals Selective Liquid Phase Hydrogenation of Benzaldehyde to Benzyl Alcohol Over Alumina Supported Gold

2019 ◽  
Vol 150 (3) ◽  
pp. 881-887
Author(s):  
Yufen Hao ◽  
Chiara Pischetola ◽  
Fernando Cárdenas-Lizana ◽  
Mark A. Keane
Keyword(s):  
Liquid Phase ◽  
Benzyl Alcohol ◽  
Reaction Conditions ◽  
Liquid Phase Hydrogenation ◽  
Alcohol Water ◽  
Reaction Constant ◽  
Supported Gold ◽  
First Time ◽  
Nucleophilic Mechanism ◽  
By Products

Abstract We report for the first time 100% benzyl alcohol yield from the liquid phase (T = 353 K, P = 9 bar) hydrogenation of benzaldehyde over Au/Al2O3. Under the same reaction conditions, a benchmark Pt/Al2O3 catalyst promoted the formation of toluene and benzene as hydrogenolysis by-products. Reaction kinetics was subjected to a Hammett treatment and the reaction constant (ρ = 0.9) was found to be consistent with a nucleophilic mechanism. A solvent (alcohol, water and alcohol + water) effect is demonstrated and ascribed to competitive adsorption where solvation by polar (water) facilitates benzaldehyde activation. Graphic Abstract

Toward the Rationalization of Facilitated Hydrotropy: Investigation with the Ternary Dimethyl Isosorbide / Benzyl Alcohol / Water System

2012 ◽  
Vol 41 (3) ◽  
pp. 555-565 ◽  
Author(s):  
Morgan Durand ◽  
Alexander Stoppa ◽  
Valérie Molinier ◽  
Didier Touraud ◽  
Jean-Marie Aubry
Keyword(s):  
Benzyl Alcohol ◽  
Water System ◽  
Alcohol Water
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