scholarly journals Antimicrobial Study of Synthesized and Characterized Rhodium, Platinum and Gold Metal Complexes Derived from Bidentate Schiff Base Ligand. (Research Article)

2021 ◽  
Vol 11 (1) ◽  
pp. 77-86
Author(s):  
Manik Rathod ◽  
Vijaykumar L. Chavan
2001 ◽  
Vol 56 (4-5) ◽  
pp. 403-410 ◽  
Author(s):  
Daniela Koch ◽  
Winfried Hoffmüller ◽  
Kurt Polborn ◽  
Wolfgang Beck

Abstract β-Phenylalanine forms with chloro bridged complexes the chiral N, O-chelates Cp*Ir(Cl)(NH2CH(Ph)CH2CO2) and (p-cymene)Ru(Cl)(NH2CHPhCH2CO2) as mixture of two diastereoisomers. Similarly the palladium(III) and platinum(II) complexes (Et3P)(Cl)M(NH2CH(Ph)CH2CO2) (M = Pd, Pt) were obtained. Schiff base complexes (arene)(Cl)M(O2CC(R)=N-CH(R)CH(R)CH2CO2CH3) (arene = Cp*, p-cymene; M = Ir, Ru) were synthesized from the chloro-bridged compounds, 2-oxocarboxylates and β-alanine or β-phenylalanine methylester. The Cp*Ir complex with a tridendate dianionic Schiff base generated from pyruvate and β-phenylalaninate is obtained as a single isomer. Cp*Ir(Cl) forms a complex with an N, O-bidentate Schiff base ligand from glycinate and acetylacetic ethyl ester.


2021 ◽  
Vol 23 (09) ◽  
pp. 160-167
Author(s):  
Syeda Haseen Buvabi ◽  
◽  
Vani Srinivasan ◽  
Dr. Manjunatha M ◽  
◽  
...  

A novel ligand was synthesized from terephthalaldehyde and o-phenylene diamine and treated with coumarin derivative to form a New Schiff base. Co(II), Ni(II) and Cu(II) complexes of the ligand were synthesized. 1HNMR and LC-MS mass spectrometry studies were done. Antimicrobial studies were performed for the ligand and its metal complex with E.Coli and was found to be active. The ligand can be further modified and studied for its antimicrobial action in the future.


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