Regulatory Requirements for Pulp and Paper Mill Effluent Control: Scientific Basis and Consequences

1991 ◽  
Vol 24 (3-4) ◽  
pp. 19-31 ◽  
Author(s):  
J. Folke

The Ministers' Declaration from the 2nd North Sea Conference recommended a goal to be set to diminish the discharge of hazardous substances via rivers by 50% over the next 10 years, e.g. to diminish the discharge of persistent halogenated compounds from pulp and paper mill effluents. The Paris Convention adopted this recommendation later. Based on a study conducted for the EEC Commission, we have arrived at the following conclusions to fulfil this goal. For historic reasons the regulation of the pulp and paper industry includes some parameters which may not be the most appropriate ones, e.g. BOD5 and AOX. To regulate the bleached pulp mills by AOX/TOC1 is not recommendable. PCDD/PDDFs are very difficult to regulate at present. Regulation of polychlorinated phenolics (PoCPs) in the effluent may prove to be a valid indirect measure of TCDD-equivalents, but this has yet to be proven. To ensure sufficient removal of hazardous compounds, we recommend that standards for TSS be stringent, as the major fraction of hazardous compounds is associated with suspended solids (including PoCPs and PCDD/PCDFs). Effluent control should be based on pH, COD (Chemical Oxygen Demand using dichromic acid), TSS (total suspended solids) and PoCPs. At present there are not sufficient data available to establish a regulation based on these parameters. So, further data should be obtained.

1994 ◽  
Vol 29 (5-6) ◽  
pp. 313-328 ◽  
Author(s):  
Sakari Halttunen

High suspended solids concentrations are typical for pulp and paper industry treated effluents. A new clarifier model was developed to find the reasons for this problem. The model clarifier is divided into four different zones: inlet, settling, thickening and separation. In the inlet zone sludge is transported by water flow and neither thickening nor settling will happen. When water velocity decreases the main part of the sludge will settle until it reaches the thickening zone. Thickening will continue until the sludge is pumped away from the clarifier. Concentration increase depends on sludge concentration, time and specific thickening coefficient. The minor part, which is specific to the sludge, enters the separation zone and will either settle in the thickening zone or stay in the effluent. In intensive field studies on 12 different activated sludge processes sludge volume in the clarifier, effluent suspended solids concentrations and sludge settling qualities were examined. Modelled sludge blanket volumes were verified with blanket measurements. Modelled effluent suspended solids were also verified by concentration measurements. Sludge thickening characteristics can be estimated by DSVI. From the data collected two empirical relationships were noticed between sludge settling properties and process operation. Solids concentration in clarified water depends on settling number, which is the mean number of sludge settling during its residence time in the process (sludge age). Sludge settling properties seem to depend on collision load, which is defined as COD-load divided by return sludge biomass flow.


1980 ◽  
Vol 13 (12) ◽  
pp. 9-22
Author(s):  
G. Fladda ◽  
T. Pettersson ◽  
L. Eriksson ◽  
G. Tidstam

1980 ◽  
Vol 13 (4) ◽  
pp. 9-22 ◽  
Author(s):  
G. Fladda ◽  
T. Pettersson ◽  
L. Eriksson ◽  
G. Tidstam

2011 ◽  
Vol 63 (3) ◽  
pp. 491-501 ◽  
Author(s):  
R. Dewi ◽  
J. A. Van Leeuwen ◽  
A. Everson ◽  
S. C. Nothrop ◽  
C. W. K. Chow

The use of coagulation and flocculation for tertiary treatment of pulp and paper mill effluent was investigated, where the evaluation was based on the removal of nitrogen (N), phosphorus (P) and BOD from post-coagulated wastewater. The study was undertaken on laboratory scale aerobic stabilisation basins (ASB). Two post coagulated (alum) wastewaters were studied, where the BOD:N:P ratios were 100:1.3:0.06 and 100:1.3:0.3. These wastewaters were treated in two identical concurrent simulations (A & B). The influent ratio for ‘A’ was selected representing the composition of actual coagulated Pinus radiata sulfite pulp effluent mixed with paper mill effluent. The input composition for ‘B’ represented a typical P concentration found in existing pulp and paper mill effluents. Unmodified sludge collected from a mill-pond was added at 4% v/v to each simulation replicating the treatment conditions at full-scale. Similar high percentage removals of BOD and COD occurred after 28 days (two HRTs) which were 94 and 67% respectively for ‘A’, and 98 and 70% respectively for ‘B’, where both remained at steady state during the third HRT. A statistical analysis of the data revealed that there was no significant difference in the sample variance of the BOD and COD results.


2018 ◽  
Vol 10 (1) ◽  
pp. 367-374 ◽  
Author(s):  
Sangeeta Madan ◽  
Preeti Sachan ◽  
Utkarsh Singh

At present, a large amount of water required for paper production and various chemicals has been identified in effluents, which is produced at different steps of paper making in paper mills. The pulp and paper industry is typically related to pollution difficulties related to high biological oxygen demand (BOD), chemical oxygen demand (COD), colour, suspended solids, lignin and chlorinated compounds. Several studies have been made on eliminate these difficulties of pulp and paper effluents, the problem still continues. Although the physical and chemical methods are on the track of treatment, they are not on par with biological treatment because of cost ineffectiveness and residual effects. The biological treatment is known to be effective in reducing the organic load and toxic effects of paper mill effluents. Some microorganisms including bacteria and fungi have been involved in degrading the chemicals present in pulp and paper mill effluent. This article is an overview of the attempts made by several researchers worldwide to use biotechnological methods for degradation of the toxic compounds present in pulp and paper mill effluents by using fungi, bacteria, algae and enzymes. The current study clearly shows that application of native dominant bacterial and fungal isolates may be used forthe treatment of large pulp and paper mills effluents.


2007 ◽  
Vol 55 (6) ◽  
pp. 223-230 ◽  
Author(s):  
Leo Habets ◽  
Willie Driessen

Since the early 1980s, anaerobic treatment of industrial effluents has found widespread application in the pulp and paper industry. Over 200 installations are treating a large variety of different pulp and paper mill effluents. Amongst various anaerobic systems the UASB and IC are the most applied anaerobic reactor systems. Anaerobic treatment is well feasible for effluents originated from recycle paper mills, mechanical pulping (peroxide bleached), semi-chemical pulping and sulphite and kraft evaporator condensates. The advantages of anaerobic pre-treatment are (1) net production of renewable energy (biogas), (2) minimized bio-solids production, (3) minimal footprint and (4) reduced emission of greenhouse gases. Via in-line application of anaerobic treatment in closed circuits (paper kidney technology) further savings on cost of fresh water intake and effluent discharge levies are generated.


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