Aerobic and Anaerobic Biotransformations and Treatment of Chlorinated Pulp Bleach Waste Constituents

1994 ◽  
Vol 29 (5-6) ◽  
pp. 73-80 ◽  
Author(s):  
Jaakko A. Puhakka ◽  
Päivi M. Mäkinen ◽  
Margareta Lundin ◽  
John F. Ferguson

Biotransformations and treatment of several chlorinated, hydroxylated and methoxylated monoaromatic compounds were studied in batch bottle bioassays and continuous-flow fluidized-bed reactors. With the aerobic enrichment, polychlorinated phenols were biodegraded with simultaneous release of inorganic chloride in amounts equal to mineralization stoichiometrics. Aerobic removal of 4,5-dichlorocatechol and 4,5- dichlorovanillin were associated with the release of inorganic chlorine. The aerobic enrichment showed no activity against mono- or di-O-methylated phenols. With the anaerobic enrichment, reductive transformations of these compounds were observed. These transformations included reductive dechlorinations, de-O-methylations and dehydroxylations. High-rate operation of an aerobic fluidized-bed reactor resulted in over 99.7% biodégradation of polychlorophenols. In the anaerobic fluidized-bed reactor, over 95% removal of chlorophenols with no apparent accumulation of lower chlorinated phenols indicated complete dechlorination.

2020 ◽  
Vol 749 ◽  
pp. 142359
Author(s):  
Su Yan ◽  
Ka Yu Cheng ◽  
Maneesha P. Ginige ◽  
Guanyu Zheng ◽  
Lixiang Zhou ◽  
...  

2004 ◽  
Vol 4 (5-6) ◽  
pp. 21-28
Author(s):  
S.-C. Kim ◽  
D.-K. Lee

TiO2-coated granular activated carbon was employed for the removal of toxic microcystin-LR from water. High surface area of the activated carbon provided sites for the adsorption of microcystin-LR, and the adsorbed microcystin-LR migrated continuously onto the surface of TiO2 particles which located mainly at the exterior surface in the vicinity of the entrances of the macropores of the activated carbon. The migrated microcystin-LR was finally degraded into nontoxic products and CO2 very quickly. These combined roles of the activated carbon and TiO2 showed a synergistic effect on the efficient degradation of toxic microcystin-LR. A continuous flow fluidized bed reactor with the TiO2-coated activated carbon could successfully be employed for the efficient photocatalytic of microcystin-LR.


1989 ◽  
Vol 21 (4-5) ◽  
pp. 157-165 ◽  
Author(s):  
F. Ehlinger ◽  
J. M. Audic ◽  
G. M. Faup

The characterization of the biofilm of an anaerobic fluidized-bed reactor was completed under standard conditions. The distribution of the fixed protein concentration depended on the level in the reactor. The protein concentration reached 1520 µg.g−1 of support at the top of the reactor and only 1200 µg.g−1 at the bottom after 504 hours of operation but the specific activity of the biofilm was 33×10−4 µM acetate.h−1.mg−1 proteins at the bottom and only 26×10−4 µM.h−1.mg−1 at the top. The efficiency of a fluidized bed reactor and the composition of the biofilm changed with an increase of the pH from 7 to 8.5 during the seeding of the support material. Future development of the biofilm and the specific activity of the support were affected.


1990 ◽  
Vol 85 (9) ◽  
pp. 651-656 ◽  
Author(s):  
Kenji KIDA ◽  
Shigeru MORIMURA ◽  
Yorikazu SONODA ◽  
Masaaki OBE ◽  
Kohei TANEMUR

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