Fe(II) oxidation during acid mine drainage neutralization in a pilot-scale sequencing batch reactor

2013 ◽  
Vol 68 (6) ◽  
pp. 1406-1411 ◽  
Author(s):  
J. N. Zvimba ◽  
M. Mathye ◽  
V. R. K. Vadapalli ◽  
H. Swanepoel ◽  
L. Bologo

This study investigated Fe(II) oxidation during acid mine drainage (AMD) neutralization using CaCO3 in a pilot-scale Sequencing Batch Reactor (SBR) of hydraulic retention time (HRT) of 90 min and sludge retention time (SRT) of 360 min in the presence of air. The removal kinetics of Fe(II), of initial concentration 1,033 ± 0 mg/L, from AMD through oxidation to Fe(III) was observed to depend on both pH and suspended solids, resulting in Fe(II) levels of 679 ± 32, 242 ± 64, 46 ± 16 and 28 ± 0 mg/L recorded after cycles 1, 2, 3 and 4 respectively, with complete Fe(II) oxidation only achieved after complete neutralization of AMD. Generally, it takes 30 min to completely oxidize Fe(II) during cycle 4, suggesting that further optimization of SBR operation based on both pH and suspended solids manipulation can result in significant reduction of the number of cycles required to achieve acceptable Fe(II) oxidation for removal as ferric hydroxide. Overall, complete removal of Fe(II) during AMD neutralization is attractive as it promotes recovery of better quality waste gypsum, key to downstream gypsum beneficiation for recovery of valuables, thereby enabling some treatment-cost recovery and prevention of environmental pollution from dumping of sludge into landfills.

2020 ◽  
Vol 36 ◽  
pp. 101349 ◽  
Author(s):  
Josiel Martins Costa ◽  
Lívia Martins Verola ◽  
Juliana Kawanishi Braga ◽  
Renata Piacentini Rodriguez ◽  
Giselle Patrícia Sancinetti

2018 ◽  
Vol 30 (1) ◽  
pp. 47-58 ◽  
Author(s):  
Mirabelle Perossi Cunha ◽  
Rafael Marçal Ferraz ◽  
Giselle Patrícia Sancinetti ◽  
Renata Piacentini Rodriguez

2018 ◽  
Vol 247 ◽  
pp. 624-632 ◽  
Author(s):  
Yaneth Vasquez ◽  
Maria C. Escobar ◽  
Johan S. Saenz ◽  
Maria F. Quiceno-Vallejo ◽  
Carmen M. Neculita ◽  
...  

2017 ◽  
Vol 321 ◽  
pp. 764-772 ◽  
Author(s):  
Pierre Le Pape ◽  
Fabienne Battaglia-Brunet ◽  
Marc Parmentier ◽  
Catherine Joulian ◽  
Cindy Gassaud ◽  
...  

2020 ◽  
Vol 39 (4) ◽  
pp. 851-858
Author(s):  
Marina Isabel Vianna de Oliveira Ribeiro ◽  
Juliana Kawanishi Braga ◽  
Renata Piacentini Rodriguez ◽  
Giselle Patricia Sancinetti

1998 ◽  
Vol 38 (6) ◽  
pp. 79-88 ◽  
Author(s):  
Hang-Sik Shin ◽  
Sang-Min Lee ◽  
In-Seok Seo ◽  
Goo-Oung Kim ◽  
Kyeong-Ho Lim ◽  
...  

A pilot plant of SBR (Sequencing Batch Reactor) and MF (microfiltration) process was operated in order to treat and reuse the greywater produced from an office building. The performance of SBR for greywater was satisfactory as the effluent had 20 mg/l, 5 mg/l, and 0.5 mg/l of SCOD, BOD, and ammonia, respectively. The cyclic operation of SBR used in this study proved more effective in nitrification and denitrification than the conventional SBR operation. However, the most effective mode was step-feed SBR for denitrification. The decanting system of this SBR discharged the effluent fairly well without sludge washout. However, it was difficult to maintain constant concentration of suspended solid from the SBR process. Thus, additional filtration was needed to get adequate water quality for water reuse. MF could remove residual suspended solids and pathogens as well from the SBR effluent. The suspended solids of final effluent were around 1 mg/l and allowed using the treated water for some purposes.


2018 ◽  
Vol 73 ◽  
pp. 05009
Author(s):  
Hardyanti Nurandani ◽  
Utomo Sudarno ◽  
Oktaviana Angelica ◽  
Serafina Katrin ◽  
Junaidi Junaidi

Sulphur dioxide gas is one of most contaminating gas in the air. Sulphur gas can be produced by mining activities. Sulphur gas will be harmful if bond with CO2 to form as Sulphur Dioxide. To reduce the Sulphur Dioxide gas concentration we must inhibite the sulphur gas formation from mining activities. The inhibition of sulphur gas could be done by reduce the sulphate concentration in acid mine drainage. One of important factor that influencing the reduce of sulphate is COD/SO42- ratio. The effect of COD/SO42- ratio on bacterial growth and sulfate removal process can be investigated with anaerobic batch reactor. The laundry septic tank sediments were inoculated on an anaerobic batch reactor which were contacted with artificial coal acid mine water wastes with 1000 sulfate concentrations and 2000 mg SO42- /L. In an anaerobic batch reactor there are five reactors with variations of COD / SO42-1.0, 1.5, 2.0, 4.0, and 8.0 ratios. Efficiency ratio and the best sulfate removal rate is in reactor ratio 2.0 with value efficiency of 46.58% and a reduction rate of 29.128 mg / L.day in an anaerobic batch reactor. The efficiency of the removal rate decreased when the COD / SO42->2.0 ratio decreased. The fastest pH decline was in the COD/SO42-8.0 ratio variation in the anaerobic batch reactor and. The COD / SO42-ratio can help the sulfate reduction process in the optimum value by affecting the sulfate-reducing bacterial metabolism in the balance of the acceptor and the electron donor.


2016 ◽  
Vol 130 ◽  
pp. 116-125 ◽  
Author(s):  
Erin J. Clyde ◽  
Pascale Champagne ◽  
Heather E. Jamieson ◽  
Caitlin Gorman ◽  
John Sourial

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