Transition Metal-Mediated Kinetic Resolution

2000 ◽  
Vol 4 (8) ◽  
pp. 869-885 ◽  
Author(s):  
Gregory R. Cook
Keyword(s):  
Transition Metal ◽  
Kinetic Resolution

Highly active, chemo- and enantioselective Pt-SPO catalytic systems for the synthesis of aromatic carboxamides

2015 ◽  
Vol 5 (7) ◽  
pp. 3822-3828 ◽  
Author(s):  
Henrik Gulyás ◽  
Ivan Rivilla ◽  
Simona Curreli ◽  
Zoraida Freixa ◽  
Piet W. N. M. van Leeuwen
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Kinetic Resolution ◽  
Platinum Complexes ◽  
Catalytic Systems ◽  
Highly Active

Platinum complexes of the chiral non-racemizing SPO ligand 1 have been discovered to be the first artificial transition metal complexes providing kinetic resolution in the hydration of a racemic chiral nitrile.

Catalytic asymmetric oxidative carbonylation-induced kinetic resolution of sterically hindered benzylamines to chiral isoindolinones

2021 ◽  
Vol 57 (14) ◽  
pp. 1778-1781
Author(s):  
Qiu-Qi Mu ◽  
Yi-Xue Nie ◽  
Hang Li ◽  
Xing-Feng Bai ◽  
Xue-Wei Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Kinetic Resolution ◽  
Oxidative Carbonylation ◽  
Sterically Hindered ◽  
Transition Metal Catalyzed ◽  
Catalytic Asymmetric ◽  
Metal Catalyzed ◽  
First Time

A highly enantioselective kinetic resolution of sterically hindered benzylamines has been achieved for the first time through transition-metal-catalyzed oxidative carbonylation.

Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolution

2014 ◽  
Vol 5 (10) ◽  
pp. 3803-3807 ◽  
Author(s):  
David Grassi ◽  
Alexandre Alexakis
Keyword(s):  
Transition Metal ◽  
Kinetic Resolution ◽  
Grignard Reagents ◽  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Quaternary Centers ◽  
Metal Free ◽  
Stereogenic Centers

The first transition metal-free catalyzed diastereoselective and enantioselective asymmetric allylic alkylation (AAA) has been disclosed leading to the construction of vicinal tertiary/quaternary centers via a kinetic resolution protocol starting from readily available starting materials.

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