Sonochemical Synthesis of Silica and Silica Sulfuric Acid Nanoparticles from Rice Husk Ash: A New and Recyclable Catalyst for the Acetylation of Alcohols and Phenols Under Heterogeneous Conditions

2012 ◽  
Vol 15 (9) ◽  
pp. 705-712 ◽  
Author(s):  
Masoud Salavati-Niasari ◽  
Jaber Javidi
2007 ◽  
Vol 48 (30) ◽  
pp. 5219-5222 ◽  
Author(s):  
Ali Khalafi-Nezhad ◽  
Abolfath Parhami ◽  
Mohammad Navid Soltani Rad ◽  
Mohammad Ali Zolfigol ◽  
Abdolkarim Zare

2006 ◽  
Vol 7 (7) ◽  
pp. 494-498 ◽  
Author(s):  
Khodabakhsh Niknam ◽  
Mohammad Ali Zolfigol ◽  
Ahmad Khorramabadi-Zad ◽  
Reza Zare ◽  
Mohsen Shayegh

2021 ◽  
Vol 47 (2) ◽  
pp. 324-331
Author(s):  
Prinya Chindaprasirt ◽  
Kiatsuda Somna

Geopolymer is an aluminosilicate material, synthesized from source materials rich in silica and alumina and alkali solution. This product provides similar strength to Portland cement concrete. Geopolymer exhibits a wide variety of properties and characteristics, including high compressive strength, low shrinkage, acid resistance, fire resistance and low thermal conductivity. In term of acid resistance, acid rain is an important consideration due to global warming. Structures deteriorate as a result of persistence contact with acid rain with of pH less than 5. Thus, this research aims to improve acid resistance of fly ash-NaOH geopolymer mortars by incorporating rice husk ash (RHA). Artificial acid rain solution was prepared by mixing nitric acid and sulfuric acid at the ratio of 70:30 v/v. The geopolymer mortars were immersed in 5% nitric acid, 5% sulfuric acid, and 5% synthetic acid rain solutions for 36 weeks. The evaluations of its resistance to acid solution was investigated with surface corrosion, compressive strength, and microstructure. The results showed that the incorporation of RHA improved the acid rain resistance of geopolymer mortar through pore refinement and increase in strength. The mortar with fly ash to RHA ratio of 90:10 provided the highest compressive strength and good resistance to acid rain.


ChemInform ◽  
2005 ◽  
Vol 36 (41) ◽  
Author(s):  
T. Yakaiah ◽  
G. Venkat Reddy ◽  
B. P. V. Lingaiah ◽  
B. Narsaiah ◽  
P. Shanthan Rao

2010 ◽  
Vol 7 (4) ◽  
pp. 1546-1554 ◽  
Author(s):  
Alireza Hasaninejad ◽  
Abdolkarim Zare ◽  
Mohammad Rez Mohammadizadeh ◽  
Mohsen Shekouhy ◽  
Ahmad Reza Moosavi-Zare

Silica sulfuric acid is utilized as a green, highly efficient, heterogeneous and recyclable catalyst for the preparation ofβ-enaminones andβ-enamino esters from amines andβ-dicarbonyl compounds under solvent-free conditions at 80 °C. Using this method, the title compounds are produced in high to excellent yields and in short reaction times.


ChemInform ◽  
2007 ◽  
Vol 38 (45) ◽  
Author(s):  
Ali Khalafi-Nezhad ◽  
Abolfath Parhami ◽  
Mohammad Navid Soltani Rad ◽  
Mohammad Ali Zolfigol ◽  
Abdolkarim Zare

In many rice producing countries of the world, including in Vietnam, various research aimed at using rice husk ash (RHA) as a finely dispersed active mineral additive in cements, concrete and mortars are being conducted. The effect of the duration of the mechanoactivation of the RHA, produced under laboratory conditions in Vietnam, on its pozzolanic activity were investigated in this study. The composition of ash was investigated by laser granulometry and the values of indicators characterizing the dispersion of its particles before and after mechanical activation were established. The content of soluble amorphous silicon oxide in rice husk ash samples was determined by photocolorimetric analysis. The pizzolanic activity of the RHA, fly ash and the silica fume was also compared according to the method of absorption of the solution of the active mineral additive. It is established that the duration of the mechanical activation of rice husk ash by grinding in a vibratory mill is optimal for increasing its pozzolanic activity, since it simultaneously results in the production of the most dispersed ash particles with the highest specific surface area and maximum solubility of the amorphous silica contained in it. Longer grinding does not lead to further reduction in the size of ash particles, which can be explained by their aggregation, and also reduces the solubility of amorphous silica in an aqueous alkaline medium.


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