New Simple Ion-Selective Membrane Electrode for Serious Environmental Pollutant, Mercury (II), Analysis in Aqueous Solution, Fluorescent Mercury Lamp White Dust, Mercurochrome and Dental Alloy

Author(s):  
Abeer M. E. Hassan ◽  
Hytham M. Ahmed ◽  
Hassan Y. Aboul-Enein
2009 ◽  
Vol 2009 ◽  
pp. 1-10 ◽  
Author(s):  
Asif Ali Khan ◽  
Umme Habiba ◽  
Anish Khan

Poly-o-anisidine Sn(IV) arsenophosphate is a newly synthesized nanocomposite material and has been characterized on the basis of its chemical composition, ion exchange capacity, TGA-DTA, FTIR, X-RAY, SEM, and TEM studies. On the basis of distribution studies, the exchanger was found to be highly selective for lead that is an environmental pollutant. For the detection of lead in water a heterogeneous precipitate based ion-selective membrane electrode was developed by means of this composite cation exchanger as electroactive material. The membrane electrode is mechanically stable, with a quick response time, and can be operated over a wide pH range. The selectivity coefficients were determined by mixed solution method and revealed that the electrode is sensitive for Pb(II) in presence of interfering cations. The practical utility of this membrane electrode has been established by employing it as an indicator electrode in the potentiometric titration of Pb(II).


2010 ◽  
Vol 75 (5) ◽  
pp. 563-575 ◽  
Author(s):  
Moslem Mohammadi ◽  
Mehdi Khodadadian ◽  
Mohammad K. Rofouei

A plasticized poly(vinyl chloride) membrane electrode based on 4-[(5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl]benzene-1,3-diol (L) for highly selective determination of palladium(II) (in PdCl42– form) is developed. The electrode showed a good Nernstian response (29.6 ± 0.4 mV per decade) over a wide concentration range (3.1 × 10–7 to 1.0 × 10–2 mol l–1). The limit of detection was 1.5 × 10–7 mol l–1. The electrode has a response time of about 20 s, and it can be used for at least 2 months without observing any considerable deviation from Nernstian response. The proposed electrode could be used in the pH range of 2.5–5.5. The practical utility of the electrode has been demonstrated by its use for the estimation of palladium content in aqueous samples.


2007 ◽  
Vol 54 (6) ◽  
pp. 1535-1542 ◽  
Author(s):  
Mohammad Reza Yaftian ◽  
Massoumeh Parinejad ◽  
Dominique Matt

2005 ◽  
Vol 23 (7) ◽  
pp. 865-869 ◽  
Author(s):  
Wang Fu-Chang ◽  
Chai Ya-Qin ◽  
Yuan Ruo ◽  
Chen Chun-Hua ◽  
Dai Jian-Yuan ◽  
...  

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