scholarly journals Behavior of SnO2 in the tin-bearing iron concentrate during a reduction sintering process

2017 ◽  
Vol 53 (1) ◽  
pp. 67-74 ◽  
Author(s):  
Z. Su ◽  
Y. Zhang ◽  
B. Liu ◽  
J. Chen ◽  
G. Li ◽  
...  
Keyword(s):  
Adverse Effect ◽  
Valence State ◽  
Gas Flow ◽  
Iron Ores ◽  
Gas Composition ◽  
Sintering Process ◽  
Iron Concentrate ◽  
Morphology Analysis ◽  
State Analysis

The reserve of tin-bearing iron ores is very large in China. However, they have not been utilized sufficiently so far due to the complex embedded relationship between iron- and tin-bearing minerals. In the present work, the behavior of tin in the tin-bearing iron concentrates during a reduction sintering process (RSP) were studied using XRD, SEM-EDS, chemical valence state analysis and morphology analysis. The results show that there is about 30 mass% tin deprived from the tinbearing iron concentrates by the RSP. The tin-bearing phases remained in the finished sinters exist as the form of stannic (Sn4+), stannous (Sn2+) compounds and metallic Sn (Sno). The atmosphere in the sinter bed during the RSP is theoretically suitable for the volatilization of SnO(g). However, the gas composition and temperature of the sintering gas flow are changeable, which bring about adverse effect to the deprivation of tin.

Valence state analysis of elements by EPMA and its application

1990 ◽  
Vol 48 (2) ◽  
pp. 230-231
Author(s):  
Chen Liqing ◽  
Liu Zuqin ◽  
Zhang Wei
Keyword(s):  
Valence State ◽  
Line Intensities ◽  
Valence States ◽  
Valence Electrons ◽  
Fe And Mn ◽  
Intensity Ratios ◽  
State Analysis

Valence state analyses of Fe and Mn in oxides by EPMA have been reported in literature. In this paper, the effects of valence state on intensity ratios ILα/IKα and ILα/ILβ of Cu, Ni, Co, Fe, Mn, Cr and their oxides, and on intensity ratios ILβ2/ILα1 and ILγ1/ILα1 of Mo, Nb, Zr and their oxides were studied. It was observed that intensity ratios change with valence states in accordance with some regularities, and these effects could be utilized for analyzing the valence states of catalysts.Valence state analysis of elements by EPMA is based on the fact that changes in the states of valence electrons in the outer shells of an atom cause corresponding changes in line intensities. The M electrons of Cu, Ni, Co, Fe, Mn, Cr and the N electrons of Mo, Nb, Zr are valence electrons. Line Kα1,2 and six lines of L are produced from the transitions of K-L2,3 and L-M or L-N respectively.

Experimental Research on Bonding Intensity of Iron Ores in the Sintering Process

2011 ◽  
Vol 391-392 ◽  
pp. 60-64
Author(s):  
Fang Yi Long ◽  
Sheng Li Wu ◽  
Juan Zhu ◽  
Yuan Du ◽  
Guo Liang Zhang
Keyword(s):  
South Africa ◽  
Liquid Phase ◽  
Experimental Research ◽  
Negative Correlation ◽  
Influence Factors ◽  
Iron Ores ◽  
Sintering Process ◽  
Different Types ◽  
Lower Porosity

The bonding intensity of four kinds of ores from Brazil, Australia and South Africa is researched in this study, and the influence factors are analyzed. The results show that, the ores of different types have apparently differences in bonding intensity, ores from Brazil and South Africa have high bonding intensity, while ores from Australia have low bonding intensity; The foundation of generation of effective liquid is adequate liquid phase fluidity and the lower porosity of core ore; The ratio of porosity of core ore and the index of liquid phase fluidity has negative correlation with the bonding intensity.

scholarly journals Modification of Aerosol Gold Nanoparticles by Nanosecond Pulsed-Periodic Laser Radiation

Nanomaterials ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 2701
Author(s):  
Kirill Khabarov ◽  
Messan Nouraldeen ◽  
Sergei Tichonov ◽  
Anna Lizunova ◽  
Alexey Efimov ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Laser Radiation ◽  
Gas Flow ◽  
Laser Pulses ◽  
Radiation Absorption ◽  
Sintering Process ◽  
Spherical Nanoparticles ◽  
Shrinkage Curve ◽  
Size Modification ◽  
Pulse Energies

This study investigates the processes of interaction of nanosecond pulsed-periodic laser radiation with the flow of aerosol agglomerates of gold nanoparticles synthesized in a spark discharge. Nanoparticles in a gas flow are spatially separated nano-objects whose interaction with each other and with the walls of an experimental cell was insignificant. Therefore, the energy absorbed by nanoparticles was used only for their own heating with further shape and size modification and on heat transfer to the surrounding gas. In the research, we used laser radiation with wavelengths of 527 and 1053 nm at pulse energies up to 900 µJ and pulse repetition rates up to 500 Hz. The dynamics of changes in the nanoparticles size during their sintering process depending on the laser pulses energy is characterized by an S-shaped shrinkage curve. Complete sintering of the initial agglomerates with their transformation into spherical nanoparticles is achieved by a series of impacting laser pulses. The result of nanoparticles’ laser modification is largely determined by the pulse energy and the efficiency of the nanoparticles’ radiation absorption.

scholarly journals Control Technique of the Melting Reaction in Sintering Process by the Fine Part Selective Granulation of Clayish Iron Ores

1997 ◽  
Vol 83 (2) ◽  
pp. 103-108 ◽  
Author(s):  
Tetsuzo HAGA ◽  
Akiyoshi OHSHIO ◽  
Keiichi NAKAMURA ◽  
Takuma KOZONO ◽  
Kiyota UEKAWA
Keyword(s):  
Control Technique ◽  
Iron Ores ◽  
Sintering Process ◽  
Melting Reaction

An Experimental Research on Cationic Reverse Flotation of Anshan-Type Iron Ores

2020 ◽  
Vol 980 ◽  
pp. 359-367
Author(s):  
Zhong Hang Cheng ◽  
Dian Bing Zhu ◽  
Shu Juan Dai ◽  
Ahmed Sobhy
Keyword(s):  
Iron Ore ◽  
Spectroscopic Analysis ◽  
Iron Ores ◽  
Reverse Flotation ◽  
Iron Concentrate ◽  
Mineral Separation ◽  
Pulp Temperature ◽  
Reagent Consumption ◽  
Depressing Agent

The mineral processing technology of Anshan-type iron ores has been developed in a rapid speed in recent years, and the combined flowsheet at the core of anionic reverse flotation has become a mainstream in the beneficiation of Anshan-type iron ores in china. With the successful application of this combined flowsheet, some obvious problems are also emerging. Such as high requirement of pulp temperature, complex reagent system, high cost of reagent consumption and so on. In view of this,we have carried out an experimental study on the separation of Anshan type iron ore by cationic reverse flotation . A new collector (named KBD) which is mixed amines have been developed . On this basis, the actual mineral separation experiment is carried out in the laboratory.With KBD as the collector,and starch and sodium hexametaphoshate as the depressant, has resulted in an iron concentrate of 68.16% and recovery rate of 89.71%. The determination of the electrokinetic potential and the infra-red spectroscopic analysis show that KBD can effectively and priorly adsorbed to the surface of quartz, and has greatly change the elecrtokinetic potential of quartz.The interaction of the depressing agent has increased the differences of the floatabilities in quartz and hermitite and changed the surface electric property so that the effective separation has been realized.

Gaseous Fluorides Formation Mechanism in the Roasting Process of the Fluorite-Bearing Iron Concentrate

2013 ◽  
Vol 690-693 ◽  
pp. 3498-3505 ◽  
Author(s):  
Yi Ci Wang ◽  
Jian Liang Zhang ◽  
Jing Wang ◽  
Fang Zhang ◽  
Guo Ping Luo
Keyword(s):  
Thermal Analysis ◽  
Water Vapor ◽  
Formation Mechanism ◽  
Theoretical Basis ◽  
Emission Rate ◽  
Sintering Process ◽  
Iron Concentrate ◽  
Roasting Process ◽  
Fluorine Emission ◽  
Roasting Temperature

The gaseous fluorides formation mechanism in the roasting process of the fluorite-bearing iron concentrate was studied by thermodynamic calculation, differential thermal analysis (DTA) and chemical analysis. The results show that fluorine in the fluorite-bearing iron concentrate begins to escape since 400~500°C, and the emission rate of fluorine significantly increases when the temperature is above 1100°C; in the roasting process of fluorite-bearing iron concentrate, SiO2, K2O, Na2O, MgO, Al2O3 in the gangue and water vapor in roasting atmospher react with CaF2 in fluorite to generate such gaseous fluorides as SiF4, KF, NaF, MgF2, AlF3 and HF; with the increase of roasting temperature, the emission rate of fluorine increases obviously; and the water vapor in roasting atmosphere can improve escaping of fluorine.The results provide a theoretical basis for the improvement of roasting technology to reduce fluorine emission in the roasting or sintering process of Baiyanobo iron concentrate.

scholarly journals Improvement of the Melting Reaction in Sintering Process by the Fine Part Selective Granulation of Clayish Iron Ores

1997 ◽  
Vol 83 (4) ◽  
pp. 233-238 ◽  
Author(s):  
Tetsuzo HAGA ◽  
Akiyoshi OHSHIO ◽  
Yukihiro HIDA ◽  
Hajime FUKUDA ◽  
Nariaki OGATA
Keyword(s):  
Iron Ores ◽  
Sintering Process ◽  
Melting Reaction
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