Inference of molecular divertor density from filtered camera analysis of molecularly induced Balmer line emission during detachment in JET L-mode plasmas

A previously presented Monte Carlo method for estimating local plasma conditions in 2D based on intensity ratios of deuterium Balmer D α , D γ and D ɛ lines was amended to consider also the D α and D γ emission contributions arising from molecular processes. The obtained estimates were used to infer the molecular divertor density with the help of the molecular databases of EIRENE. The method was benchmarked against EDGE2D-EIRENE simulations and observed to reproduce the molecularly induced emission fractions and the molecular divertor densities primarily within 25% of the references. Experimental analysis of a JET L-mode density scan suggested molecularly induced D α and D γ contributions of up to 60–70% and 20%, respectively, during the process of detachment. The independent estimates of the molecular divertor density inferred from the obtained molecularly induced D α and D γ intensities agree within uncertainties with each other. Both estimates show the molecular density increasing up to approximately 1.0–2.0 × 1020 m−3 at the outer strike point in deep detachment with its ratio to the local electron density agreeing with EDGE2D-EIRENE predictions within the scatter of the experimental data.

Nd L-shell x-ray emission induced by light ions

The L-shell x ray of Nd has been obtained for 300 - 600 keV He2 + ions impacting, and compared with that produced by H+ and H2 + ions. The threshold of projectile kinetic energy for L-shell ionization of Nd is crudely verified in the energy region of about 300 - 400 keV. It is found that the energy of the distinct L-subshell x rays has a blue shift. The relative intensity ratios of Lβ1, 3, 4 and Lβ2, 15 to Lα1, 2 x-ray are enlarged compared to the atomic data, and they decrease with the increase of incident energy, and increase with increasing effective nuclear charge of the incident ions. That is interpreted by the multiple ionization of outer-shells induced by light ions.

KAPPA: A Package for the Synthesis of Optically Thin Spectra for the Non-Maxwellian κ-distributions. II. Major Update to Compatibility with CHIANTI Version 10

KAPPA is a database and software for the calculation of the optically thin spectra for the non-Maxwellian κ-distributions that were recently diagnosed in the plasma of solar coronal loops, flares, as well as in the transition region. KAPPA is based on the widely used CHIANTI database and reproduces many of its capabilities for κ-distributions. Here we perform a major update of the KAPPA database, including a near-complete recalculation of the ionization, recombination, excitation, and deexcitation rates for all ions in the database, as well as an implementation of the two-ion model for calculations of relative-level populations (and intensities) if these are modified by ionization and recombination from or to excited levels. As an example of KAPPA usage, we explore novel diagnostics of κ, and show that O iii lines near 500 and 700 Å provide a strong sensitivity to κ, with some line intensity ratios changing by a factor of up to 2–4 compared to Maxwellian. This is much larger than previously employed diagnostics of κ.

Florescence Intensity Ratio Thermometer in the First Biological Window Based on Non-Thermally Coupled Energy Levels of Tm3+ and Ho3+ Ions

In this study, the up-conversion luminescence and optical temperature sensing properties of Ho3+/Tm3+/Yb3+-co-doped NaLuF4 phosphors were investigated. The visible (475, 540, and 650 nm) and near-infrared light (692 and 800 nm) radiated from 1Ho3+/4Tm3+/Yb3+-co-doped NaLuF4 phosphors were obvious enough for subsequent detection. The slopes in the lnI–lnP plot of the emissions located in the first biological window (650, 692, and 800 nm) were both ∼1.5, which mean that the power had little effect on the three fluorescence peak ratios. Based on the florescence intensity ratios (FIRs) of 650 and 692 nm, the relative sensing sensitivity reaches 0.029 K−1 (476 K). The relative sensing sensitivity based on the FIRs of 800 and 692 nm reaches 0.0076 K−1 (476 K). The results reveal that 1Ho3+/4Tm3+/Yb3+-co-doped NaLuF4 phosphors have potential applications in FIR-based temperature sensing in biological tissue for their high sensing sensitivity. In addition, the emission colors of the sample stabilize in the white light region as the temperature increased from 303 to 467 K, implying that it can also be used in white display.

CPExtract, a Software for the Automated Tracer-Based Pathway Specific Screening of Secondary Metabolites in LC-HRMS Data

The use of stable isotopically labeled tracers is a long-proven way of specifically detecting and tracking derived metabolites through a metabolic network of interest. While recently developed stable isotope assisted methods and associated, supporting data analysis tools have greatly improved untargeted metabolomics approaches, no software tool is currently available that allows to automatically search LC-HRMS chromatograms for completely free user-definable isotopolog patterns expected for the metabolism of labeled tracer substances. Here we present Custom Pattern Extract (CPExtract), a versatile software tool that allows for the first time the high-throughput search for user-defined isotopolog patterns in LC-HRMS data. The patterns can be specified via a set of rules including the presence or absence of certain isotopologs, their relative intensity ratios as well as chromatographic co-elution. Each isotopolog pattern satisfying the respective rules is verified on a MS-scan level and also in the chromatographic domain. The CPExtract algorithm allows the use of both labeled tracer compounds in non-labeled biological samples as well as a reversed tracer approach, employing non-labeled tracer compounds along with globally labeled biological samples. In a proof of concept study we searched for metabolites specifically arising from the malonate pathway of the filamentous fungi Fusarium graminearum and Trichoderma reesei. 1,2,3- 13 C 3 -malonic acid diethyl ester and native malonic acid monomethyl ester were used as tracers. We were able to reliably detect expected fatty acids and known polyketides. In addition, up to 189 and 270 further, unknown metabolites presumably including novel polyketides were detected in the F. graminearum and T. reesei culture samples respectively, all of which exhibited the user-predicted isotopolog patterns originating from the malonate tracer incorporation. The software can be used for every conceivable tracer approach. Furthermore, the rule sets can be easily adapted or extended if necessary. CPExtract is available free of charge for non-commercial use at https://metabolomics-ifa.boku.ac.at/CPExtract.

FLUKA Simulations of Kβ/Kα Intensity Ratios of Copper in Ag–Cu Alloys

The numerical simulations of Cu Kα and Cu Kβ fluorescence lines induced by Rh X-ray tube and by monoenergetic radiation have been presented. The copper Kβ/Kα intensity ratios for pure elements as well as for Ag–Cu alloys have been modeled. The results obtained by use of the FLUKA code, based on the Monte-Carlo approach, have been compared to available experimental and theoretical values. A visible relationship was found between the simulated Kβ/Kα intensity ratios and the copper content of the Ag–Cu alloy: as the Cu content increases, the Kβ/Kα coefficient decreases. The results can play role in elemental material analysis, especially in archaeometry.

Measurement of the Thermal Effect of Standing Surface Acoustic Waves in Microchannel by Fluoresence Intensity

Temperature is an important parameter for many medical and biological applications. It is key to measuring the temperature of acoustofluidics devices for controlling the device’s temperature. In this paper, Rhodamine B was used to measure the temperature change of the microchannel induced by the SSAWs’ thermal effect in microfluidics. A thermocouple was integrated into the microfluidics device to calibrate the relationship between the fluorescent intensity ratios of Rhodamine B and the temperature. Then, the fluid temperature in the microchannel heated by the SSAWs was measured by the fluorescent signal intensity ratio in the acoustofluidics device. The fluid temperature with different input voltages and different flow rates was measured. The results show that SSAWs can heat the still fluid rapidly to 80 °c, and the flow rates will influence the temperature of the fluid. The results will be useful for precisely controlling the temperature of acoustofluidics devices.