scholarly journals Thiophene based monoazo disperse dyes for polyester fabric

2002 ◽  
Vol 67 (1) ◽  
pp. 17-26 ◽  
Author(s):  
Hari Maradiya ◽  
Vithal Patel

A series of monoazo disperse dyes have been prepared by coupling 2-amino 3-carbethoxy-4,5-dimethylthiophene with various N-arylmaleimides. The monoazo disperse dyes were characterised by IR spectral studies and elemental analysis. These dyes were applied at 2%depth on polyester fabrics and gave light yellow to brown colour hues with fair fastness to light and very good to excellent fastness to washing, rubbing, perspiration and sublimation. The percentage exhaustion of the dyebath and fixation on the fabric were found to be very good.

2011 ◽  
Vol 8 (3) ◽  
pp. 1218-1225 ◽  
Author(s):  
B. C. Dixit ◽  
D. M. Patel

Novel bisazo-bisazomethine disperse dyes were prepared by the coupling of diazotized solutions of various aromatic amines with 2,2'-{sulfonylbis [4,1-phenylene nitrilomethylylidene]} diphenol (SB). Above Schiff base was prepared by the condensation of 2-hydroxybenzaldehyde with 4,4’-sulphonyl- dianiline (Dapson). The resultant dyes were characterized by elemental analysis, IR and1H NMR spectral studies. The UV Visible absorption spectral data were investigated in dimethylformamide (DMF) and are discussed in terms of structural property relationship. Their dyeing performance as disperse dyes has been assessed on polyester fabrics. The results show that a better hue was obtained on polyester fabrics and have mild to moderate fastness properties.


2020 ◽  
Vol 85 (10) ◽  
pp. 1253-1264
Author(s):  
Umar Ameuru ◽  
Mohammed Yakubu ◽  
Kasali Bello ◽  
Peter Nkeonye ◽  
Azim Halimehjani

A series of monoazo disperse dyes were synthesized by coupling diazotized 4-amino-N-dodecyl-1,8-naphthalimide with N,N-dialkyl anilines and naphthol derivatives. The synthesized intermediates and the dyes were characterized using FTIR, 1H-NMR, 13C-NMR, mass spectroscopy and elemental analysis (CHN). Visible absorption spectra of the dyes were examined in solvents of different polarities. The electronic absorption spectra cover a wavelength (?max) range of 515-535 nm in DMF at uniformly absorption intensity between 1.59-3.00?104 L mol-1 cm-1. The dyes gave deep and bright intense hues of light violet, maroon, pink and neon red on polyester fabrics. The dyes generally showed good washing and perspiration rating but poor to moderate light fastness properties on woven polyester fabric and could be recommended for commercial outlets.


2013 ◽  
Vol 834-836 ◽  
pp. 472-475
Author(s):  
Narumol Ittarat ◽  
Potjanart Suwanruji ◽  
Thitinun Karpkird ◽  
Jantip Setthayanond

Twelve monoazo disperse dyes were synthesized and then characterized by melting point (m.p.) measurement, elemental analysis and1H-NMR. The photostability of monoazo disperse dyes in solvents with different polarities was evaluated thereafter the dyes in each solvent were irradiated with visible light for 8 hours. The percentage of photostability of the dye decreased from the initial value in the range of 5-10%. The photostability was affected by the substituted group of the dyes regardless of the solvent used. Different R1group on the diazo component increased the photostability in order of H˃CN˃Cl. The photostability of the dye was also higher when R2group on the coupling component was a methyl group.


2001 ◽  
Vol 66 (6) ◽  
pp. 367-376 ◽  
Author(s):  
Hari Maradiya ◽  
Vithal Patel

A series of disperse dyes has been synthesized by diazotisation of 2,6-dibromo-4-nitroaniline and coupled with various N-arylmaleimides. The dyes were characterized by IR spectral studies, visible absorption spectroscopy and elemental analysis. All the dyes were applied as disperse dyes on nylon, cellulose triacetate and polyester fabrics. These dyeswere found to give yellowish orange to deep brown shades with very good depth, levelness and brightness on different fabrics. The percentage dye bath exhaustion and fixation on fabrics were found to be very good. The light, washing, rubbing, perspiration and sublimation fastness properties of the dyed fabrics were found to be good to excellent.


Author(s):  
Alya M. Al-Etaibi ◽  
Morsy Ahmed El-Apasery

Polyester fabrics were dyed with prepared disperse dyes using the high temperature dyeing method. The dye exhaustion of the dye baths were compared to the low-temperature dyeing method in an attempt to study the proportion of the dye effluent solution that affects the environment. The dye uptake of the high temperature dyeing method (HT) of polyester fabric was compared with low temperature dyeing, hence (HT) increased the color strength of the investigated dyes by 309 and 265%. This means that the amount of dye present in the dye effluents by using the high-temperature dyeing method is almost non-existent, and this is reflected positively on the environment as these wastes pollute the environment. Post-treated polyester fabric was prepared through a two-step hot process after being immersed in a solution of Titanium (IV) oxide nanoparticle sizeTiO2 NPs (21 nm primary particle size) at 80 °C followed by curing at 140 °C. The treated fabric realized an optimum UV protection factor of 34.9 and 283.6 degrees. These fabrics also demonstrated a strong ability to improve the light fastness properties. Finally, the potential applications of such value-added fabrics as self-cleaning and antifungal activities were investigated. The results indicated that the treated dyed fabrics with TiO2 NPs endowed fabrics with the excellent self-cleaning of methylene blue dye. From the above, the treated fabrics with nano-titanium dioxide can be used in some promising fields, for example, medical ones.


2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Yusuf Y. Lams ◽  
P. O. Nkeonye ◽  
K. A. Bello ◽  
M. K. Yakubu ◽  
A. O. Lawal

The aim of this study was to synthesize disperse dyes in the derivative of 2-amino-4-chloro-5-formylthiazole by conventional diazotization and couplings with pyridone and resorcinol. The dyes were characterized by visible absorption spectroscopy, IR spectral studies, and 1H and 13C NMR. The pyridone and resorcinol substituted dyes exhausted well with good depth on 100% polyester fabrics with a shade of brown and purple colours, respectively. The heteroatom and the intrinsic conjugation in the thiazole structure results in high bathochromic shifts and lead to brightness of shades. The dyed fabrics showed very good to excellent wash fastness and moderate to good light and perspiration fastness properties.


2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
S. K. Zadafiya ◽  
J. H. Tailor ◽  
G. M. Malik

Various diazotized aryl amines were coupled with N-(4-nitrophenyl)-2-[(4-phenyl-1,3-thiazol-2-yl)amino]acetamide to give the corresponding various azo disperse dyes (D1-D13). These dyes were applied to polyester fiber by HTHP method and their fastness properties were evaluated. Dyes were characterized by IR, elemental analysis, and NMR spectral studies. These dyes showed very good antibacterial and antifungal activities.


2017 ◽  
Vol 46 (6) ◽  
pp. 449-457 ◽  
Author(s):  
Abdel-Zaher A. Elassar ◽  
Saleh M. Al-Mousawi ◽  
Maher Helmi Helal ◽  
Mohamed E. Elgazzar

Purpose The purpose of this paper is to prepare new disperse dyes and apply for dying polyester fabrics. Design/methodology/approach The synthetic reaction was carried out through two steps: preparation of arylhydrazones and alkylation using enaminone and dimethylaminovinyl-pyridazine. The high temperature method was used to apply these dyes to polyester fibres. Findings The study revealed that there is a significant effect of the new prepared disperse dyes on polyester fabrics. The structures of the prepared dyes were established based on elemental analysis and spectral data (infra red (IR), mass spectrometry (MS) and proton nuclear magnetic resonance (1H-NMR), carbon 13th nuclear magnetic resonance (13C-NMR)). Research limitations/implications Disperse dyes containing heterocyclic moiety have attracted great academic and industrial attention owing to their significant. The potential of using disperse dyes easily prepared from arylhydrazones are promise broad applications for these dyes. Practical implications The presence of N-thienyl and N-pyridazinyl in the structure of the synthesised disperse dyes would be expected to add the bioactivity advantage. Also, it can be used in formulating the antimicrobial fabrics. Social implications The N-thienyl and N-pyrdiazinyl derivatives of azo dyes are expected to be superior to in the application for fabrics. It may be useful for other applications like painting. Originality/value This paper helps to synthesise novel thiophene or pyridazine-based dyestuff for application in dying properties on polyester fabric and study their fastness properties.


Chemistry ◽  
2021 ◽  
Vol 3 (3) ◽  
pp. 889-895
Author(s):  
Alya M. Al-Etaibi ◽  
Morsy Ahmed El-Apasery

The textile sector is closely linked to environmental pollution as a result of the use of toxic chemicals and their disposal in liquid waste, which negatively affects for the environment. Moreover, textile industries, especially wet processing, consume a large amount of energy, water, and chemical auxiliaries. Therefore, there is an urgent need to find a solution that takes the problem of environmental pollution into account. Considering ultrasound as an environmentally safe alternative for dyeing polyester fabrics with the disperse dyes that we have prepared before, the comparison between the ultrasonic dyeing method and conventional dyeing at low temperatures was investigated. Dye exhaustion on polyester fabrics and fastness properties such as the washing, rubbing, light, and perspiration of all of the dyed fabrics were performed by two dyeing methods. Additionally, the ultraviolet protection factors (UPF) for dyed polyester fabrics were evaluated.


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