scholarly journals The electrochemical impedance spectroscopy of silver doped hydroxyapatite coating in simulated body fluid used as corrosive agent

2012 ◽  
Vol 77 (11) ◽  
pp. 1609-1623 ◽  
Author(s):  
Ana Jankovic ◽  
Sanja Erakovic ◽  
Antonija Dindune ◽  
Djordje Veljovic ◽  
Tatjana Stevanovic ◽  
...  

Titanium is a key biomedical material due its good biocompatibility, mechanical properties and corrosion stability, but infections of the implantation site still pose serious threat. One approach to prevent infection is to improve antimicrobial ability of the coating material. Silver doped hydroxyapatite (Ag/HAP) nanoparticles were synthesized by new modified precipitation method. The synthesized powder was used for preparation of Ag/HAP coating on titanium by electrophoretic deposition. The coating was characterized in terms of phase composition and structure by Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray diffraction (XRD); surface morphology and chemical composition was assessed using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Research focused on evaluation of the corrosion behaviour of Ag/HAP coating in simulated body fluid (SBF) at 37 ?C during prolonged immersion time by electrochemical impedance spectroscopy (EIS). Silver doped HAP coating provided good corrosion protection in SBF solution.

2008 ◽  
Vol 396-398 ◽  
pp. 393-396 ◽  
Author(s):  
D. Ionita ◽  
Doina Raducanu ◽  
Mariana Prodana ◽  
Ioana Demetrescu

The paper is an electrochemical study regarding the influence of different acid etching conditions on the corrosion behaviour of a new Ti based bioalloy with Nb, Ta and Zr. Open circuit, potentiodynamic and electrochemical impedance spectroscopy were the methods performed in a simulated body fluid (SBF) and a stability mechanism was discussed in terms of equivalent circuits.


RSC Advances ◽  
2016 ◽  
Vol 6 (83) ◽  
pp. 80275-80285 ◽  
Author(s):  
Bhavana Rikhari ◽  
S. Pugal Mani ◽  
N. Rajendran

In the present work, dynamic electrochemical impedance spectroscopy (DEIS) was used to investigate the corrosion behavior of polypyrrole (PPy)-coated titanium (Ti) in simulated body fluid (SBF) solution.


RSC Advances ◽  
2014 ◽  
Vol 4 (53) ◽  
pp. 27791-27795 ◽  
Author(s):  
A. Srinivasan ◽  
Kwang Seon Shin ◽  
N. Rajendran

The change in impedance values as a function of potential indicated the transformation of Mg from its passive to active state.


2012 ◽  
Vol 66 (2) ◽  
pp. 187-192
Author(s):  
Rade Surudzic ◽  
Sanja Erakovic ◽  
Vesna Miskovic-Stankovic

In order to improve corrosion stability and biocompatibility of titanium surfaces, hydroxyapatite (Ca10(PO4)6(OH)2, HAP) has been used as coating material due to the fact that it possess similar chemical composition as bone tissue. Lignin?s (Lig) usage in medical applications could be interesting because it could lead to thermal stability, hydrophilicity, biocompatibility and biodegradability of different materials. Bioceramic hydroxyapatite/lignin (HAP/Lig) coatings on titanium were obtained from ethanol suspension by electrophoretic deposition method. The uniform and compact HAP/Lig coatings were deposited at constant voltage of 60 V for 45 s and sintered at 900?C in argon atmosphere. The corrosion stability of sintered HAP/Lig coatings in simulated body fluid (SBF) at 37?C was investigated by open circuit potential-time measurements and electrochemical impedance spectroscopy (EIS). The greater values of open circuit potential, as well as EIS results, indicated improved corrosion resistance and good corrosion stability of HAP/Lig coatings in simulated body fluid at 37?C .


2013 ◽  
Vol 765 ◽  
pp. 803-807
Author(s):  
Gaur Swati ◽  
Anand Sawroop Khanna ◽  
Raghuvir Kumar Singh Raman

In the present study, combinations of a phosphonato silane with a precursor, Methyltriethoxy silane (MTEOS) in various ratios were applied onto the alloy Mg-6Zn-Ca. The corrosion resistance of the coated and uncoated specimens in a modified simulated body fluid (m-SBF) was characterized by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Results suggest that the silane coating significantly decreases the degradation rate of the magnesium alloy, indicating its potential to be used as a corrosion barrier for magnesium alloy temporary implants.


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