scholarly journals Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives

2016 ◽  
Vol 81 (12) ◽  
pp. 1383-1392
Author(s):  
Danijela Stojkovic ◽  
Alessia Bacchi ◽  
Davide Capucci ◽  
Milica Milenkovic ◽  
Bozidar Cobeljic ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Elemental Analysis ◽  
Water Solution ◽  
13C Nmr Spectroscopy ◽  
Synthesis And Characterization ◽  
Coumarin Derivatives ◽  
1H And 13C Nmr ◽  
X Ray ◽  
Ir And Nmr Spectroscopy

A Pd(II) complex with methyl 2-((1-(2,4-dioxochroman-3-ylidene)ethyl)amino)acetate was synthesized. The structures of both the ligand and Pd(II) complex were determined by elemental analysis, IR and NMR spectroscopy. Recrystallization of Pd(II) complex from DMF/water solution resulted in its hydrolysis and formation of dimethylamine-(2-((1-(2,4-dioxochroman-3-ylidene)ethyl)amino)acetato)palladium(II) complex, the structure of which was determined by elemental analysis, IR, 1H and 13C NMR spectroscopy, as well as X-ray analysis.

Synthesis and Characterization of the nido-Platinaborane 7,7-(PPh3)2-7-PtB10H11-11-OC(O)Me

2011 ◽  
Vol 66 (4) ◽  
pp. 387-391
Author(s):  
Jinling Miao ◽  
Yong Nie ◽  
Haiyan Chen ◽  
Daqi Wang ◽  
Markus Enders ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Hydrogen Bonds ◽  
Single Crystal ◽  
Elemental Analysis ◽  
Chain Structure ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ir And Nmr Spectroscopy

The reaction of closo-B10H102− with PtCl2(PPh3)2 in the presence of MeCOSH afforded the title platinaborane nido-7,7-(PPh3)2-7-PtB10H11-11-OC(O)Me (1), which has been characterized by IR and NMR spectroscopy, MS, elemental analysis, and single-crystal X-ray diffraction. In contrast to the known products having exo-polyhedral Pt-S-C-O-B ring(s) from the same reaction with Ph- COSH, compound 1 has a B-acetoxy group on the open PtB4 face of the nido-PtB10 cluster. The structure of 1 features both intramolecular/intermolecular C-H· · ·O hydrogen bonds and intramolecular C-H· · ·H-B dihydrogen bonds, which link the molecules into a 1-D chain structure.

scholarly journals Synthesis and characterization of tris[butyl-(1-methyl-3phenyl-propyl)-dithiocarbamato]cobalt(III) seskvitoluen

2002 ◽  
Vol 67 (2) ◽  
pp. 123-126 ◽  
Author(s):  
Goran Kaludjerovic ◽  
Vesna Djinovic ◽  
Srecko Trifunovic ◽  
Ismet Hodzic ◽  
Tibor Sabo
Keyword(s):  
Nmr Spectroscopy ◽  
Electronic Absorption ◽  
Elemental Analysis ◽  
13C Nmr ◽  
Sodium Salt ◽  
13C Nmr Spectroscopy ◽  
Bidentate Ligand ◽  
Synthesis And Characterization ◽  
1H And 13C Nmr

Anew bidentate ligand butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamate (bm?pdtc) was prepared, as the sodium salt. In the reaction of hexaaminecobalt(III) chloride with Nabm?pdtc, the corresponding tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]cobalt(III) [Co(bm?pdtc)3]?complex was prepared. The complex was characterized by elemental analysis, infrared, electronic absorption, 1H and 13C-NMR spectroscopy.

scholarly journals Synthesis and Characterization of Ammonium Acesulfamate

2014 ◽  
Vol 69 (6) ◽  
pp. 737-741 ◽  
Author(s):  
Gustavo A. Echeverría ◽  
Oscar E. Piro ◽  
Beatriz S. Parajón-Costa ◽  
Enrique J. Baran
Keyword(s):  
Molecular Structure ◽  
Ammonium Carbonate ◽  
Crystal And Molecular Structure ◽  
13C Nmr Spectroscopy ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
Orthorhombic Space Group ◽  
1H And 13C Nmr ◽  
X Ray

Ammonium acesulfamate, (NH4)C4H4NO4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. The substance crystallizes in the orthorhombic space group Pnma with Z = 4 molecules per unit cell. The NH4+ ion generates medium to strong hydrogen bonds with the carbonylic oxygen, the iminic nitrogen and the sulfonyl oxygen atoms of the acesulfamate anion. The FTIR spectrum of the compound was also recorded and is briefly discussed.

SYNTHESIS AND CHARACTERIZATION OF PLATINUM(II/IV) COMPLEXES WITH 2-AMINO-5-METHYL-4-PHENYLTHIAZOLE

2021 ◽  
Author(s):  
Danijela Lj. Stojković ◽  
◽  
Verica V. Jevtić ◽  
Đorđe S. Petrović ◽  
Sandra S. Jovičić Milić ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
General Formula ◽  
13C Nmr ◽  
13C Nmr Spectroscopy ◽  
Synthesis And Characterization ◽  
1H And 13C Nmr ◽  
Elemental Microanalysis

This paper examines the synthesis of two new complexes of platinum(II/IV) ion, general formula [PtL2]Cl2 and [PtL2]Cl4, where L is 2-amino-5-methyl-4-phenylthiazole. The structures of the above mentioned compounds were determined by elemental microanalysis, infrared, 1H and 13C NMR spectroscopy.

scholarly journals Synthesis, characterization and crystal structure of butyl N-(3-chloropropyl)-(2S)-alaninate hydrochloride

2013 ◽  
Vol 78 (10) ◽  
pp. 1531-1537
Author(s):  
Dejana Dimitrijevic ◽  
Sladjana Novakovic ◽  
Gordana Radic ◽  
Verica Jevtic ◽  
Laura Menéndez-Taboada ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Nmr Spectroscopy ◽  
Single Crystal ◽  
Elemental Analysis ◽  
13C Nmr ◽  
13C Nmr Spectroscopy ◽  
1H And 13C Nmr ◽  
X Ray

The synthesis of butyl N-(3-chloropropyl)-(2S)-alaninate hydrochloride is reported here. The compound was characterized by elemental analysis, infrared, 1H and 13C NMR spectroscopy. The structure of butyl N-(3-chloropropyl)-(2S)-alaninate hydrochloride was confirmed by single-crystal X-ray analysis.

scholarly journals Synthesis and characterization of zinc(II), palladium(II) and platinum(II) complexes with 2’-[1-(2-pyridinyl)- ethylidene]oxamohydrazide: The crystal structure of biss2'-[1-(2-pyridinyl)ethylidene]oxa

2004 ◽  
Vol 69 (8-9) ◽  
pp. 651-660 ◽  
Author(s):  
Katarina Andjelkovic ◽  
Gordana Jakovljevic ◽  
Mario Zlatovic ◽  
Zivoslav Tesic ◽  
Dusan Sladic ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Nmr Spectroscopy ◽  
13C Nmr ◽  
Neutral Type ◽  
13C Nmr Spectroscopy ◽  
Octahedral Geometry ◽  
Synthesis And Characterization ◽  
X Ray ◽  
Square Planar

Complexes of Zn(II), Pd(II) and Pt(II) with 2?-[1-(2-pyridinyl)ethylidene ]oxamohydrazide (Hapsox) were synthesized and their structures were determined. All the complexes are of a neutral type with two apsox ligands coordinated to Zn(II) and one apsox ligand coordinated to Pd(II) or Pt(II). In each case, the polydentate was coordinated via pyridine and hydrazone nitrogens and ?-oxyazine oxygen, forming an octahedral geometry around Zn(II), and a square planar one around Pd(II) and Pt(II). The structure determination was performed by IR, 1H-NMR and 13C-NMR spectroscopy, and for the Zn(II) complex by X-ray structure analysis.

Synthese und Charakterisierung von Halogen-phosphor(III)- Derivaten des 8-Hydroxychinolins. Röntgenstrukturanalyse von 8-[Phenyl(chloro)-phosphito]-chinolin/ Synthesis and Characterization of Halogen-phosphorus(III) Derivatives of 8-Hydroxyquinoline. X -Ray Structure Analysis of 8-[Phenyl(chloro)phosphito]-quinoline

1993 ◽  
Vol 48 (1) ◽  
pp. 85-89 ◽  
Author(s):  
Lin Yang ◽  
Peter G. Jones ◽  
Reinhard Schmutzler
Keyword(s):  
Nmr Spectroscopy ◽  
Single Crystal ◽  
Diffraction Study ◽  
Elemental Analysis ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
New Compounds ◽  
Derivatives Of

The reaction of 8 -trimethylsiloxyquinoline, 2 with PCl3, PhPCl2, and PhPF2 has furnished the corresponding 8 -quinolyl halophosphite derivatives, 3-5 . The synthesis of two metal complexes, 8 and 9, of 4 with Au(I) and Pt(II) is described. The new compounds were characterized by elemental analysis and by 1H and 31P NMR spectroscopy. A single crystal X-ray diffraction study of 4 has been conducted; a short intramolecular P ··· N contact (230.9 pm) and a long P-Cl bond (218.7 pm) were observed.

Synthesis and Characterization of 3-Chloropropyl-substituted o- Carboranes: Crystal Structures of 1,2-(1,3-Propanediyl)-o-carborane, 1-(3-Chloropropyl)-o-carborane and 1,2-Bis(3-chloropropyl)-ocarborane

2013 ◽  
Vol 68 (7) ◽  
pp. 804-810 ◽  
Author(s):  
Deqian Bian ◽  
Yong Nie ◽  
Jinling Miao ◽  
Zhenwei Zhang ◽  
Ping Lu
Keyword(s):  
Mass Spectrometry ◽  
Nmr Spectroscopy ◽  
Single Crystal ◽  
Main Product ◽  
Total Yield ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ir And Nmr Spectroscopy

The reactions of the lithio-o-carborane Li2C2B10H10 with ClCH2CH2CH2Br were studied under various conditions. While the main product is the known exo-polyhedrally cyclized 1,2- (1,3-propanediyl)-o-carborane (2), the expected 3-chloropropyl-substituted carborane products 1- (ClCH2CH2CH2)C2B10H11 (3) and 1,2-(ClCH2CH2CH2)2C2B10H10 (4) can be obtained in a total yield of 22%. In the presence of CuCl, the same reaction proceeded rather slowly and gave compound 3and bis(o-carborane) (5) in small yields, with the recovery of the starting o-C2B10H12. Compounds 2- 4were characterized by means of IR and NMR spectroscopy and mass spectrometry, as well as by single-crystal X-ray diffraction.

scholarly journals Synthesis and characterization of new Oxazine , Thiazine and Pyrazol derived from chalcones

2014 ◽  
Vol 11 (2) ◽  
pp. 477-485 ◽  
Author(s):  
Baghdad Science Journal
Keyword(s):  
Nmr Spectroscopy ◽  
Hydrazine Hydrate ◽  
Elemental Analysis ◽  
Potassium Hydroxide ◽  
1H Nmr Spectroscopy ◽  
Room Temperature ◽  
Potassium Hydroxide Solution ◽  
Synthesis And Characterization ◽  
Heterocyclic Derivatives

In this study, chalcones were synthesis by condensing 2-acetylpyridine with aromatic aldehyde derivatives in dilute ethanolic potassium hydroxide solution at room temperature according to Claisen-Schmidt condensation. After that, new heterocyclic derivatives such as Oxazine, Thiazine and Pyrazol were synthesis by reaction between chalcones with urea, thiourea and hydrazine hydrate respectively scheme 1. All these compounds wrer characterization by FTIR, 1H-NMR spectroscopy and elemental analysis.

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