scholarly journals Novel Functional Derivatives of Methyl-cis-9,10-Epoxy-Octadecanoate

2010 ◽  
Vol 4 (3) ◽  
pp. 167-170
Author(s):  
Stanislav Skachko ◽  
◽  
Orest Hevus ◽  
Larysa Dolynska ◽  
◽  
...  
Keyword(s):  
Methyl Ester ◽  
Ring Opening ◽  
Acid Methyl Ester ◽  
Ester Group ◽  
Oxirane Ring ◽  
Acid Methyl ◽  
Functional Derivatives ◽  
Surface Active ◽  
Derivatives Of ◽  
Epoxystearic Acid

The synthesis of functional derivatives of epoxystearic acid methyl ester by oxirane ring opening and transesterification of ester group has been described. Some novel surface-active and peroxide-containing compounds have been obtained. Major features of the process have been investigated and main characteristics have been determined.

Derivate des Benzo[1.3]dioxols, 431 Über Benzo [1.3] dioxolcarbonsäuren / Derivatives of 1,3-Benzodioxoles, 43 1,3-Benzodioxolecarboxylic Acids

1978 ◽  
Vol 33 (7-8) ◽  
pp. 465-471
Author(s):  
Franz Daliacker ◽  
Volker Mues ◽  
In-O Kim
Keyword(s):  
Carboxylic Acid ◽  
Methyl Ester ◽  
Benzoic Acid ◽  
Myristic Acid ◽  
Good Yield ◽  
Acid Ester ◽  
Acid Methyl Ester ◽  
Acid Methyl ◽  
Derivatives Of

Abstract We describe the possibilities of formation and preparation of the “natural” 1,3-benzodioxolecarboxylic acids 1, 2, 4, 6 b, and 7, already mentioned in literature. Myristic acid (3e) was prepared in good yield from 3-methoxy-4,5-dihydroxy-benzoic acid ester (3c) , which could be easily made from 3-methoxy-2,3-carbonyldioxy-benzoic acid methylester (3b). Myristicic acid methylester (3d) could be subjected to methylation and hydrolysis leading to 3e without any difficulties. 4.6-dimethoxy-1,3-benzodioxole-5-carboxylic acid (5b) was prepared in good yields by oxidation of 4,6-dimethoxy-1,3-benzodioxole-5-aldehyde (5a). 5.7-dimethoxy-1,3-benzodioxole-carboxylic acid (13f), one of the “unnatural” 1,3-benzodioxolecarboxylic acids, derivatives of o-ipiperonylic acid (8), was prepared from 5-amino-7-methoxy-1,3- benzodioxole-4carboxylic acid methyl ester (13b) by diazotisation, elimination of nitrogen, methylation, and hydrolysis. A comparison of our measured pkA-values showed the strongest acidity belonging to 5,6-dimethoxy-1,3-benzodioxole-4-carbocylic acid (11).

Synthesis of 2-Cyanoethoxy and 2-(1H-Tetrazol-5-yl)ethoxy Derivatives of Glycyrrhetic Acid Methyl Ester

2018 ◽  
Vol 54 (12) ◽  
pp. 1868-1870
Author(s):  
A. D. Zorina ◽  
V. L. Polozova ◽  
S. A. Marchenko ◽  
S. I. Selivanov ◽  
R. E. Trifonov
Keyword(s):  
Methyl Ester ◽  
Acid Methyl Ester ◽  
Glycyrrhetic Acid ◽  
Acid Methyl ◽  
Derivatives Of

scholarly journals Koenigs-Knorr Glycosylation with Neuraminic Acid Derivatives

2010 ◽  
Vol 2010 ◽  
pp. 1-8 ◽  
Author(s):  
Galina Pazynina ◽  
Vitaly Nasonov ◽  
Ivan Belyanchikov ◽  
Reinchard Brossmer ◽  
Maxim Maisel ◽  
...  
Keyword(s):  
Methyl Ester ◽  
Acid Methyl Ester ◽  
Neuraminic Acid ◽  
Carbohydrate Binding ◽  
Acetylneuraminic Acid ◽  
Acid Methyl ◽  
Glycosyl Donor ◽  
Carbohydrate Binding Proteins ◽  
Derivatives Of

Earlier we reported a convenient and efficient method of preparing α2-6 sialooligosaccharides in conditions of Koenigs-Knorr reaction. The use of Ag2CO3 allowed carrying out α2-6 sialylation of galacto-4,6-diol of mono- and disaccharides with chloride of acetylated N-acetylneuraminic acid methyl ester as glycosyl donor. In this study we applied this approach to other derivatives of neuraminic acid, namely, Neu5Gc, 9-deoxy-9-NAc-Neu5Ac, Neu5Acα2-8Neu5Ac, and Neu5Acα2-8Neu5Acα2-8Neu5Ac as glycosyl donors; eight compounds were synthesized: Neu5Gcα-O(CH2)3NH2 (8), Neu5Gcα2-6Galβ1-4GlcNAcβ-O(CH2)3NH2 (10), 9-deoxy-9-NAc-Neu5Ac-O(CH2)3NH2 (15), 9-deoxy-9-NAc-Neu5Acα2-6Galβ1-4GlcNAcβ-O(CH2)3NH2 (17), Neu5Acα2-8Neu5Acα-O(CH2)3NH2(23) Neu5Acα2-8Neu5Acα-OCH3 (24), Neu5Acα2-8Neu5Acα-OCH2(p-C6H4)NHCOCH2NH2 (25), and Neu5Acα2-8Neu5Acα2-8Neu5Acα-O(CH2)3NH2 (32). These sialosides were used for characterization of siglecs and other carbohydrate-binding proteins.

scholarly journals Synthesis of Bis-Glyoxylamide Peptidomimetics Derived from Bis-N-acetylisatins Linked at C5 by a Methylene or Oxygen Bridge

Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4343 ◽  
Author(s):  
Suryanti ◽  
Zhang ◽  
Aldilla ◽  
Bhadbhade ◽  
Kumar ◽  
...  
Keyword(s):  
Amino Acid ◽  
Methyl Ester ◽  
Single Crystals ◽  
Ring Opening ◽  
Acid Methyl Ester ◽  
X Ray ◽  
Oxygen Bridge ◽  
Acid Methyl ◽  
Amino Acid Methyl Ester

The bis-glyoxylamide peptidomimetics have been synthesized from bis-N-acetylisatins linked at C5 by ring-opening with alcohols, amines, and amino acid methyl ester hydrochlorides. X-ray images of single crystals of bis-glyoxylamide peptidomimetics have been obtained.

scholarly journals Oligomeric Composition of Polyols From Fatty Acid Methyl Ester: The Effect of Ring-Opening Reactants of Epoxide Groups

2018 ◽  
Vol 95 (4) ◽  
pp. 509-523 ◽  
Author(s):  
Tuan Noor Maznee Tuan Ismail ◽  
Nor Azowa Ibrahim ◽  
Mohd Azmil Mohd Noor ◽  
Seng Soi Hoong ◽  
Kosheela Devi Poo Palam ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Methyl Ester ◽  
Fatty Acid Methyl Ester ◽  
Ring Opening ◽  
Acid Methyl Ester ◽  
Acid Methyl
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