scholarly journals Influence of Amino Acids and Alcohols on Catalytic Oxidation of Cyclohexane

2021 ◽  
Vol 15 (3) ◽  
pp. 352-358
Author(s):  
Anatolij Ludyn ◽  
◽  
Volodymyr Reutskyy ◽  
Viktor Reutskyy ◽  
Yurij Hrynchuk ◽  
...  
Keyword(s):  
Amino Acids ◽  
Liquid Phase ◽  
Catalytic Oxidation ◽  
Spectral Studies ◽  
Catalytic Systems ◽  
Industrial Catalyst ◽  
Homogeneous Oxidation ◽  
Structural Formulas

Conducted experiments and collected data show that use of catalytic systems that contain individual amino acids and industrial catalyst – solution of cobalt naphtenate with cyclohexanone – have certain influence on the process of liquid-phase homogeneous oxidation of cyclohexane. The results of spectral studies of binary catalytic systems based on NC using additives of different nature (alcohols and nitrogen-containing modifiers) allow us to propose structural formulas of catalytic complexes.

ChemInform Abstract: Catalytic Oxidation of 4-Vinylcyclohexene with Atmospheric Oxygen in the Liquid Phase in the Presence of Bimetallic Catalytic Systems.

ChemInform ◽  
1987 ◽  
Vol 18 (48) ◽  
Author(s):  
S. I. SADYCH-SADE ◽  
F. I. GARIBOV ◽  
R. A. KULIEV ◽  
N. I. GARIBOV
Keyword(s):  
Liquid Phase ◽  
Catalytic Oxidation ◽  
Atmospheric Oxygen ◽  
Catalytic Systems

Nickel (II) and oxovanadium (IV) complexes supported on MCM-41 mesoporous and their application in catalytic selective sulfide and thiol oxidation

2020 ◽  
Vol 23 ◽  
Author(s):  
Mohsen Nikoorazm ◽  
Maryam Khanmoradi ◽  
Masoumeh Sayadian
Keyword(s):  
Catalytic Activity ◽  
Room Temperature ◽  
Sol Gel ◽  
Reaction Times ◽  
Significant Loss ◽  
Spectral Studies ◽  
High Catalytic Activity ◽  
Catalytic Systems ◽  
Solvent Free Conditions ◽  
Mcm 41

Introduction:: MCM-41 was synthesized using the sol-gel method. Then two new transition metal complexes of Nickel (II) and Vanadium (IV), were synthesized by immobilization of adenine (6-aminopurine) into MCM-41 mesoporous. The compounds have been characterized by XRD, TGA, SEM, AAS and FT-IR spectral studies. Using these catalysts provided an efficient and enantioselective procedure for oxidation of sulfides to sulfoxides and oxidative coupling of thiols to their corresponding disulfides using hydrogen peroxide at room temperature. Materials and Methods:: To a solution of sulfide or thiol (1 mmol) and H2O2 (5 mmol), a determined amount of the catalyst was added. The reaction mixture was stirred at room temperature for the specific time under solvent free conditions. The progress of the reaction was monitored by TLC using n-hexane: acetone (8:2). Afterwards, the catalyst was removed from the reaction mixture by centrifugation and, then, washed with dichloromethane in order to give the pure products. Results:: All the products were obtained in excellent yields and short reaction times indicating the high activity of the synthesized catalysts. Besides, the catalysts can be recovered and reused for several runs without significant loss in their catalytic activity. Conclusion:: These catalytic systems furnish the products very quickly with excellent yields and VO-6AP-MCM-41 shows high catalytic activity compared to Ni-6AP-MCM-41.

ChemInform Abstract: LIQUID-PHASE CATALYTIC OXIDATION OF ALLYL CHLORIDE TO EPICHLOROHYDRIN

1976 ◽  
Vol 7 (36) ◽  
pp. no-no
Author(s):  
I. YA. MOKROUSOVA ◽  
L. A. OSHIN ◽  
YU. A. TREGER
Keyword(s):  
Liquid Phase ◽  
Catalytic Oxidation ◽  
Allyl Chloride

scholarly journals Solvent inhibition in the liquid-phase catalytic oxidation of 1,4-butanediol: understanding the catalyst behaviour from NMR relaxation time measurements

2016 ◽  
Vol 6 (21) ◽  
pp. 7896-7901 ◽  
Author(s):  
Carmine D'Agostino ◽  
Mark R. Feaviour ◽  
Gemma L. Brett ◽  
Jonathan Mitchell ◽  
Andrew P. E. York ◽  
...  
Keyword(s):  
Relaxation Time ◽  
Liquid Phase ◽  
Catalytic Oxidation ◽  
Heterogeneous Catalysts ◽  
Nmr Relaxation ◽  
Nmr Relaxation Time

Solvent inhibition over surfaces affects behaviour and performances of heterogeneous catalysts.

Solvent-free liquid-phase selective catalytic oxidation of toluene to benzyl alcohol and benzaldehyde over CeO2-MnOx composite oxides

2022 ◽  
Author(s):  
Gui Chen ◽  
Kuiyi You ◽  
Xiangbo Gong ◽  
Fangfang Zhao ◽  
Zhenpan Chen ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Benzyl Alcohol ◽  
Catalytic Oxidation ◽  
Molecular Oxygen ◽  
Efficient Method ◽  
Value Added ◽  
Solvent Free ◽  
Composite Oxides ◽  
Selective Catalytic Oxidation

An efficient method for highly selective preparation of the high value-added benzyl alcohol (BOL) and benzaldehyde (BAL) from liquid-phase catalytic oxidation of toluene with molecular oxygen over CeO2-MnOx composite oxides...

Enhanced catalytic oxidation of monoterpenes by zeolite-Y entrapped iron complex: spectral studies and mechanistic vision

2018 ◽  
Vol 25 (6) ◽  
pp. 1649-1658 ◽  
Author(s):  
Jignasu P. Mehta ◽  
Digvijaysinh K. Parmar ◽  
Haresh D. Nakum ◽  
Dinesh R. Godhani ◽  
Nisheeth C. Desai
Keyword(s):  
Catalytic Oxidation ◽  
Zeolite Y ◽  
Iron Complex ◽  
Spectral Studies

Liquid phase catalytic oxidation of aliphatic alcohols mixtures

1995 ◽  
Vol 24 (1-2) ◽  
pp. 59-64
Author(s):  
I. Mazzarino ◽  
A. Santos ◽  
C. Renzi
Keyword(s):  
Liquid Phase ◽  
Catalytic Oxidation ◽  
Aliphatic Alcohols
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