scholarly journals Composition and alteration of Cr-spinels from Milia and Pefki serpentinized mantle peridotites (Pindos Ophiolite Complex, Greece)

2014 ◽  
Vol 65 (1) ◽  
pp. 83-95 ◽  
Author(s):  
Argyrios Kapsiotis

Abstract The Pindos Ophiolite rocks include variably serpentinized peridotites derived from a harzburgitic and subordinately dunitic mantle. In the serpentinized matrix of these rocks pseudomorphic (mesh, bastite) and non-pseudomorphic (interpenetrating, type-2 hourglass) textures were recognized. Chromian spinel (Cr-spinel) is anhedral to subhedral and often replaced by a porous opaque phase. Chemistry data show that Cr-spinel cores retain their original composition, having Cr#[Cr/(Cr + Al)] that ranges between 0.45 and 0.73, and Mg#[Mg/(Mg + Fe2+)] that varies between 0.52 and 0.65, accompanied by low content in TiO2 ( < 0.11wt. %). The relatively wide variation of their Cr# values reflects that the studied peridotites were produced by variable degrees of melting. It is likely that the Pindos peridotites represent mantle residues originally formed in a mid-ocean ridge (MOR) environment, which were subsequently entrapped as part of a mantle wedge above a supra-subduction zone (SSZ) regime. Cr-spinel adjacent to clinochlore systematically displays limited compositional and textural zoning along grain boundaries and fractures. However, the degree of peridotite serpentinization does not correlate with the abundance of zoning effects in accessory Cr-spinel. Thus, Cr-spinel zoning is thought to represent a secondary feature obtained during the metamorphic evolution of the host peridotites. Core to rim compositional trends are expressed by MgO and Al2O3 impoverishment, mainly compensated by Cr2O3 and FeO increases. Such chemical trends are produced as a result of Cr-spinel re-equilibration with the surrounding serpentine, and their subsequent replacement by ferrian (Fe3+-rich) chromite and clinochlore, respectively, during a brief, fluid assisted, greenschist facies metamorphism episode (T > 300 °C). The limited occurrence of ferrian chromite with high Fe3+# values suggests that elevated oxidizing conditions were prevalent only on a local scale during Cr-spinel alteration

Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 464 ◽  
Author(s):  
Satoko Ishimaru ◽  
Yuji Saikawa ◽  
Makoto Miura ◽  
Osman Parlak ◽  
Shoji Arai

The Mersin ophiolite, Turkey, is of typical arc type based on geochemistry of crustal rocks without any signs of mid-ocean ridge (MOR) affinity. We examined its ultramafic rocks to reveal sub-arc mantle processes. Mantle peridotites, poor in clinopyroxene (<1.0 vol.%), show high Fo content of olivine (90–92) and Cr# [=Cr/(Cr + Al) atomic ratio] (=0.62–0.77) of chromian spinel. NiO content of olivine is occasionally high (up to 0.5 wt.%) in the harzburgite. Moho-transition zone (MTZ) dunite is also highly depleted, i.e., spinel is high Cr# (0.78–0.89), clinopyroxene is poor in HREE, and olivine is high Fo (up to 92), but relatively low in NiO (0.1–0.4 wt.%). The harzburgite is residue after high-degree mantle melting, possibly assisted by slab-derived fluid. The high-Ni character of olivine suggests secondary metasomatic formation of olivine-replacing orthopyroxene although replacement textures are unclear. The MTZ dunite is of replacive origin, resulted from interaction between Mg-rich melt released from harzburgite diapir and another harzburgite at the diapir roof. The MTZ dunite is the very place that produced the boninitic and replacive dunite. The MTZ is thicker (>1 km) in Mersin than in MOR-related ophiolite (mostly < 500 m), and this is one of the features of arc-type ophiolite.


2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Hamed Gamal El Dien ◽  
Shoji Arai ◽  
Luc-Serge Doucet ◽  
Zheng-Xiang Li ◽  
Youngwoo Kil ◽  
...  

Abstract Mantle melts provide a window on processes related to global plate tectonics. The composition of chromian spinel (Cr-spinel) from mafic-ultramafic rocks has been widely used for tracing the geotectonic environments, the degree of mantle melting and the rate of mid-ocean ridge spreading. The assumption is that Cr-spinel’s core composition (Cr# = Cr/(Cr + Al)) is homogenous, insensitive to post-formation modification and therefore a robust petrogenetic indicator. However, we demonstrate that the composition of Cr-spinel can be modified by fluid/melt-rock interactions in both sub-arc and sub-mid oceanic mantle. Metasomatism can produce Al-Cr heterogeneity in Cr-spinel that lowers the Cr/Al ratio, and therefore modifies the Cr#, making Cr# ineffective as a geotectonic and mantle melting indicator. Our analysis also demonstrates that Cr-spinel is a potential sink for fluid-mobile elements, especially in subduction zone environments. The heterogeneity of Cr# in Cr-spinel can, therefore, be used as an excellent tracer for metasomatic processes.


2008 ◽  
Vol 179 (5) ◽  
pp. 503-518 ◽  
Author(s):  
Georges Ceuleneer ◽  
Elisabeth Le Sueur

AbstractThis paper addresses the question of the petrological relationships between the mantle section and the crustal section of the Trinity ophiolite. Our conclusions are based on a field survey and on petrographic and electron micro-probe study of about 200 samples. We show that the crustal section of Trinity is more developed and less chaotic than expected on the basis of previous surveys. In the Bear Creek area, we were able to describe a well preserved cumulate sequence about 1,500 m thick. The cumulate pile includes a thick (~800 m) basal part made of ultramafic cumulates (dunites, wehrlites, pyroxenites, etc…) displaying very thin (mm- to cm thick) modal layering. The most salient characterisitc of this basal section is the gradual decrease of the modal abundance of olivine from bottom to top. This paragenetic evolution is correlated with the evolution of mineral chemistry consistent with fractional crystallisation from a common parent melt. Plagioclase appears above this ultramafic sequence, in the upper half of the cumulate section, in a diffuse way at first (plagioclase pyroxenites), becoming increasingly abundant toward the top of the section. Its crystallization always coincides with that of hornblende pseudomorphs on previously crystallized pyroxenes. The layering becomes very irregular at this level and attributable essentially to textural variations. The top of the cumulate sequence is characterized by the abundance of magmatic breccias (pyroxenitic and gabbrodioritic fragments embedded in fine grained diorite). These breccias are cross cut by diabase dykes. The horizontal extent of the Bear Creek “magma chamber” is moderate (2–3 km). The lateral contact with the host peridotites and gabbros is always underlain by a screen of pegmatites reaching several hundred metres in thickness. These pegmatites are made of pyroxenites in the lowermost levels and of diorites in the upper levels. Angular xenoliths of mantle derived lherzolites are frequently observed in the layered ultramafic section, their incorporation being contemporaneous to the crystallization of the cumulates.The field relationships and the lithological succession described above are consistent with the sudden injection of a huge batch of melt (reaching several km3) into the lithosphere (rocks at sub-solidus To) followed by fractional crystallization into the internal part of this magma body. The boniniticandesitic kindred of the parent melt is clearly revealed by the crystallization sequence. This conclusion is corroborated by the extreme depletion of pyroxenes and Cr-spinel in relatively incompatible elements (Ti, Al). The fractional crystallization trend of the Trinity cumulates is identical to the one defined by phenocrysts in present-day high-Ca boninites and is clearly distinct from that of mid-ocean ridge gabbros. The plagioclase composition is buffered around high An% values (90–95%), which is consistent with a low Na content of their parent melt and with H2O saturation at the time of crystallization of this mineral. The various so-called “gabbroic” massifs cropping out in Trinity represent individual intrusions similar to the one we have studied in detail in the Bear Creek area.Two generations of melt migration structures are observed in the mantle section of Trinity: (1) ariegitic-gabbroic segregations in mineralogical and chemical equilibrium with the plagioclase lherzolite and whose injection is contemporaneous with high-To plastic deformation ; (2) pyroxenitic (and, less commonly, dioritic) segregations and dykes post-dating the high-To deformation and characterized by strong mineralogical and chemical disequilibrium with the host plagioclase lherzolite. The parent melts of these second generation segregations and dykes are identical to those of the crustal cumulates. The interaction between the boninitic melts, undersaturated in Al and ultra-depleted in incompatible elements, and the peridotites accounts for extreme mineralogical and geochemical variability of the Trinity mantle. Peridotites, away from reactive dykes, are, as a rule, richer in incompatible elements than the cumulates from the crustal section. The mantle peridotites of Trinity cannot be the source nor the residue of the melt that fed the crustal magma chambers. Accordingly, the mantle-crust complementarity argument that is the basis of the slow spreading mid-ocean ridge model for Trinity (Lherzolite Ophiolite Type), must be reconsidered.A likely tectonic scenario that accounts for our data involves the evolution of a marginal, likely back-arc basin, from its opening to its closure. The ariegitic-gabbroic segregations are the witness of a low degree and shallow (~30 km depth) partial melting event experienced by the cold and relatively fertile Trinity peridotites during the first stage of opening of this basin in a transtensional regime, as suggested by the plastic flow pattern. The injection of the boninitic magma in strong disequilibrium with the lherzolite and feeding the crustal section occurred when one of the margins of the Trinity basin migrated above the zone of melting induced by dehydration of the subducting slab. This event occurred shortly before the definitive closure of the back-arc basin and of the obduction event. Paleomagnetic and geochronological data published so far are consistent with this scenario and with a life time of about 40 Ma for the Trinity basin, which is close to the life time of modern back-arc basins.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Mingdong Zhang ◽  
Yuan Li

AbstractPlatinum group elements are invaluable tracers for planetary accretion and differentiation and the formation of PGE sulfide deposits. Previous laboratory determinations of the sulfide liquid–basaltic melt partition coefficients of PGE ($${D}_{PGE}^{SL/SM}$$ D P G E S L / S M ) yielded values of 102–109, and values of >105 have been accepted by the geochemical and cosmochemical society. Here we perform measurements of $${D}_{Pt,\,Pd}^{SL/SM}$$ D P t , P d S L / S M at 1 GPa and 1,400 °C, and find that $${D}_{Pt,\,Pd}^{SL/SM}$$ D P t , P d S L / S M increase respectively from 3,500 to 3.5 × 105 and 1,800 to 7 × 105, as the Pt and Pd concentration in the sulfide liquid increases from 60 to 21,000 ppm and 26 to 7,000 ppm, respectively, implying non-Henrian behavior of the Pt and Pd partitioning. The use of $${D}_{Pt,\,Pd}^{SL/SM}$$ D P t , P d S L / S M values of 2,000–6,000 well explains the Pt and Pd systematics of Earth’s mantle peridotites and mid-ocean ridge basalts. Our findings suggest that the behavior of PGE needs to be reevaluated when using them to trace planetary magmatic processes.


2019 ◽  
Author(s):  
Yung Ping Lee ◽  
◽  
Jonathan E. Snow ◽  
Yongjun Gao
Keyword(s):  

2021 ◽  
Vol 566 ◽  
pp. 116951
Author(s):  
Suzanne K. Birner ◽  
Elizabeth Cottrell ◽  
Jessica M. Warren ◽  
Katherine A. Kelley ◽  
Fred A. Davis

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