ABSTRACT
The chemical composition and physical properties of a crude oil determine the behavior of the oil and the way its properties will change when the oil is spilled at sea. Reliable knowledge of the oil's behavior will enable the most effective countermeasure techniques to be used in a spill situation.
A diverse range of crude oils is coming into production in the North Sea. The weathering behavior and chemical dispersibility of three very different crude oils—Troll (naphthenic), Balder (asphaltenic), and Nome (waxy)—have recently been thoroughly investigated through bench- and meso-scale experiments. The naphthenic crude oil was also exposed to full-scale studies in the North Sea.
This study shows that emulsion formation, the viscosity of emulsion, and the potential for dispersing emulsions by dispersant treatment may vary greatly for the different crude oils. It would be impossible to predict these differences with existing oil-weathering models based on fresh oil properties alone. Especially for abnormal (e.g., highly asphaltenic, waxy) crude oils, the weathering and dispersibility behavior can be revealed only by experimental work. The findings have important implications for effective oil spill response planning, particularly for estimating the most appropriate “window of opportunity” and for optimizing a dispersant application strategy for crude oils.