Visible-Light-Driven Reductive Carboarylation of Styrenes with CO2 and Aryl Halides

2019 ◽  
Author(s):  
Hao Wang ◽  
yuzhen gao ◽  
Chunlin Zhou ◽  
Gang Li
Keyword(s):  
Visible Light ◽  
Alkyl Halides ◽  
Aryl Halides ◽  
Addition Reactions ◽  
Aryl Chlorides ◽  
Aryl Iodides ◽  
Visible Light Driven ◽  
User Friendly

The first example of visible-light-driven reductive carboarylation of styrenes with CO<sub>2</sub> and aryl halides in a regioselective manner has been achieved. A broad range of aryl iodides and bromides were compatible with this reaction. <a>Moreover, pyridyl halides, alkyl halides and even aryl chlorides were also viable with this method.</a> These findings may stimulate the exploration of novel visible-light-driven Meerwein arylation-addition reactions with user-friendly aryl halides as the radical sources and the photocatalytic utilization of CO<sub>2.</sub>

Visible-Light-Driven Reductive Carboarylation of Styrenes with CO2 and Aryl Halides

2019 ◽  
Author(s):  
Hao Wang ◽  
yuzhen gao ◽  
Chunlin Zhou ◽  
Gang Li
Keyword(s):  
Visible Light ◽  
Alkyl Halides ◽  
Aryl Halides ◽  
Addition Reactions ◽  
Aryl Chlorides ◽  
Aryl Iodides ◽  
Visible Light Driven ◽  
User Friendly

The first example of visible-light-driven reductive carboarylation of styrenes with CO<sub>2</sub> and aryl halides in a regioselective manner has been achieved. A broad range of aryl iodides and bromides were compatible with this reaction. <a>Moreover, pyridyl halides, alkyl halides and even aryl chlorides were also viable with this method.</a> These findings may stimulate the exploration of novel visible-light-driven Meerwein arylation-addition reactions with user-friendly aryl halides as the radical sources and the photocatalytic utilization of CO<sub>2.</sub>

Solvent-free coupling of aryl halides with pyrroles applying visible-light photocatalysis

2017 ◽  
Vol 2 (4) ◽  
pp. 472-478 ◽  
Author(s):  
M. Obst ◽  
R. S. Shaikh ◽  
B. König
Keyword(s):  
Visible Light ◽  
Solvent Free ◽  
Aryl Halides ◽  
Visible Light Photocatalysis ◽  
Visible Light Driven

A novel reactor for solvent-free, visible-light-driven photocatalytic transformations was developed.

scholarly journals Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt(iv) hydrides

2020 ◽  
Vol 11 (44) ◽  
pp. 12095-12102
Author(s):  
Dionisio Poveda ◽  
Ángela Vivancos ◽  
Delia Bautista ◽  
Pablo González-Herrero
Keyword(s):  
Visible Light ◽  
Addition Reactions ◽  
Insertion Reactions ◽  
Photochemical Generation ◽  
Visible Light Driven ◽  
Alkyne Insertion

The photochemical generation of isolable bis-cyclometalated Pt(iv) hydrides via photooxidative C–H addition reactions is demonstrated from easily accessible Pt(ii) precursors using visible light.

Visible light-driven photocatalytic Heck reaction over carbon nanocoil supported Pd nanoparticles

2016 ◽  
Vol 6 (21) ◽  
pp. 7738-7743 ◽  
Author(s):  
Xiao-Wei Guo ◽  
Cai-Hong Hao ◽  
Cheng-Yu Wang ◽  
Sarina Sarina ◽  
Xiao-Ning Guo ◽  
...  
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Coupling Reaction ◽  
Pd Nanoparticles ◽  
Aryl Halides ◽  
Pd Nanoparticle ◽  
Visible Light Driven ◽  
Nanoparticle System ◽  
Supported Pd

This paper presents a carbon nanocoil supported Pd nanoparticle system (Pd/CNCs) as a photocatalyst for coupling reaction of aryl halides and alkenes (Heck reaction) at 40 °C.

Visible light-driven cross-coupling reactions of alkyl halides with phenylacetylene derivatives for C(sp3)–C(sp) bond formation catalyzed by a B12 complex

2019 ◽  
Vol 55 (87) ◽  
pp. 13070-13073 ◽  
Author(s):  
Li Chen ◽  
Yohei Kametani ◽  
Kenji Imamura ◽  
Tsukasa Abe ◽  
Yoshihito Shiota ◽  
...  
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Bond Formation ◽  
Cross Coupling ◽  
Alkyl Halides ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Visible Light Driven

Visible light-driven cross-coupling reactions of alkyl halides with phenylacetylene and its derivatives catalyzed by the cobalamin derivative (B12) with the [Ir(dtbbpy)(ppy)2]PF6 photocatalyst at room temperature are reported.

Visible-Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts

2017 ◽  
Vol 139 (28) ◽  
pp. 9467-9470 ◽  
Author(s):  
Katsuya Shimomaki ◽  
Kei Murata ◽  
Ruben Martin ◽  
Nobuharu Iwasawa
Keyword(s):  
Visible Light ◽  
Aryl Halides ◽  
Combined Use ◽  
Visible Light Driven

scholarly journals Nickel-catalyzed electrochemical carboxylation of unactivated aryl and alkyl halides with CO2

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Guo-Quan Sun ◽  
Wei Zhang ◽  
Li-Li Liao ◽  
Li Li ◽  
Zi-Hao Nie ◽  
...  
Keyword(s):  
Catalytic System ◽  
Functional Group ◽  
Alkyl Halides ◽  
Aryl Halides ◽  
Aryl Chlorides ◽  
Mild Conditions ◽  
Aryl Bromides ◽  
Alkyl Bromides ◽  
Pseudo Halides ◽  
Electrochemical Carboxylation

AbstractElectrochemical catalytic reductive cross couplings are powerful and sustainable methods to construct C−C bonds by using electron as the clean reductant. However, activated substrates are used in most cases. Herein, we report a general and practical electro-reductive Ni-catalytic system, realizing the electrocatalytic carboxylation of unactivated aryl chlorides and alkyl bromides with CO2. A variety of unactivated aryl bromides, iodides and sulfonates can also undergo such a reaction smoothly. Notably, we also realize the catalytic electrochemical carboxylation of aryl (pseudo)halides with CO2 avoiding the use of sacrificial electrodes. Moreover, this sustainable and economic strategy with electron as the clean reductant features mild conditions, inexpensive catalyst, safe and cheap electrodes, good functional group tolerance and broad substrate scope. Mechanistic investigations indicate that the reaction might proceed via oxidative addition of aryl halides to Ni(0) complex, the reduction of aryl-Ni(II) adduct to the Ni(I) species and following carboxylation with CO2.

Visible-Light-Driven Reductive Carboarylation of Styrenes with CO2 and Aryl Halides

2020 ◽  
Vol 142 (18) ◽  
pp. 8122-8129 ◽  
Author(s):  
Hao Wang ◽  
Yuzhen Gao ◽  
Chunlin Zhou ◽  
Gang Li
Keyword(s):  
Visible Light ◽  
Aryl Halides ◽  
Visible Light Driven
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