Synthesis and Molecular Properties of Partially Fluorinated DNTTs

1,2,3,4-Tetrafluoro-dinaphthothienothiophene (F4DNTT) and 1,2,3,4,8,9,10,11-octafluoro-dinaphthothienothiophene (F8DNTT) were synthesized via bisthiomethyl alkene intermediates which were accessible by McMurry coupling or Wittig olefination of partially fluorinated naphthalene precursors. DFT-based electronic structure calculations, X-ray absorption spectroscopy (NEXAFS) and UV/Vis measurements were used for HOMO/LUMO gap determination and to analyse the electronic structures of the partially fluorinated DNTTs. Reduced exciton binding was observed in thin films

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Synthesis and Molecular Properties of Partially Fluorinated DNTTs

10.26434/chemrxiv.13385351 ◽

2020 ◽

Author(s):

Matthias W Tripp ◽

Daniel Bischof ◽

Maximilian Dreher ◽

Gregor Witte ◽

Ulrich Koert

Keyword(s):

Thin Films ◽

Electronic Structure ◽

Absorption Spectroscopy ◽

Electronic Structures ◽

Electronic Structure Calculations ◽

X Ray ◽

Wittig Olefination ◽

X Ray Absorption ◽

Homo Lumo ◽

Structure Calculations

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An investigation of the electronic structure of Cu2FeSn3−xTixS8 (0≤x≤3) thiospinel spin-crossover materials by X-ray absorption spectroscopy and electronic structure calculations

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2012.08.057 ◽

2013 ◽

Vol 197 ◽

pp. 532-542 ◽

Cited By ~ 1

Author(s):

John R. Hayes ◽

Andrew P. Grosvenor

Keyword(s):

Electronic Structure ◽

Absorption Spectroscopy ◽

Spin Crossover ◽

Electronic Structure Calculations ◽

X Ray ◽

X Ray Absorption ◽

Structure Calculations

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Lithium insertion mechanism in CoSb3analysed by121Sb Mössbauer spectrometry, X-ray absorption spectroscopy and electronic structure calculations

Journal of Materials Chemistry ◽

10.1039/b312618h ◽

2004 ◽

Vol 14 (11) ◽

pp. 1759-1767 ◽

Cited By ~ 20

Author(s):

Isabelle Devos ◽

Manfred Womes ◽

Mike Heilemann ◽

Josette Olivier-Fourcade ◽

Jean-Claude Jumas ◽

...

Keyword(s):

Electronic Structure ◽

Absorption Spectroscopy ◽

Electronic Structure Calculations ◽

Mössbauer Spectrometry ◽

Lithium Insertion ◽

X Ray ◽

Lithium Insertion Mechanism ◽

Insertion Mechanism ◽

X Ray Absorption ◽

Structure Calculations

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A contrast in the electronic structures of B ion implanted ZnO thin films grown on glass and silicon substrates by using x-ray absorption spectroscopy

Journal of Applied Physics ◽

10.1063/5.0007733 ◽

2020 ◽

Vol 128 (6) ◽

pp. 065303

Author(s):

Krishna Kumar ◽

Shi-Chen Wu ◽

Yueh-Chung Yu ◽

Da-Hua Wei ◽

Jau-Wern Chiou

Keyword(s):

Thin Films ◽

Absorption Spectroscopy ◽

Electronic Structures ◽

Zno Thin Films ◽

Silicon Substrates ◽

X Ray ◽

X Ray Absorption ◽

Ion Implanted

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An electronic structure study ofc-axis oriented NdBCO (123) thin films using polarized soft x-ray absorption spectroscopy on Cu L3and O K edges

Journal of Physics Condensed Matter ◽

10.1088/0953-8984/13/31/320 ◽

2001 ◽

Vol 13 (31) ◽

pp. 6865-6874 ◽

Cited By ~ 4

Author(s):

R K Singhal ◽

S Dalela ◽

D Chaturvedi ◽

B Dalela ◽

N L Saini ◽

...

Keyword(s):

Thin Films ◽

Electronic Structure ◽

Absorption Spectroscopy ◽

Structure Study ◽

X Ray ◽

X Ray Absorption

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Electronic Structure Studies of 200 MeV Ag[sup +15] Swift Heavy Ion Irradiated SnO[sub 2] Thin Films Using X-Ray Absorption Spectroscopy

10.1063/1.3606007 ◽

2011 ◽

Cited By ~ 4

Author(s):

Hardeep Thakur ◽

Ravi Kumar ◽

Kuldeep Kumar Sharma ◽

Pardeep Thakur ◽

Alka B. Garg ◽

...

Keyword(s):

Thin Films ◽

Electronic Structure ◽

Absorption Spectroscopy ◽

Heavy Ion ◽

X Ray ◽

Swift Heavy Ion ◽

X Ray Absorption

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Optical anisotropy and electronic structures ofCdMoO4andCdWO4crystals: Polarized reflection measurements, x-ray photoelectron spectroscopy, and electronic structure calculations

Physical Review B ◽

10.1103/physrevb.77.155118 ◽

2008 ◽

Vol 77 (15) ◽

Cited By ~ 59

Author(s):

Masami Fujita ◽

Minoru Itoh ◽

Tsuyoshi Katagiri ◽

Daisuke Iri ◽

Mamoru Kitaura ◽

...

Keyword(s):

Electronic Structure ◽

Photoelectron Spectroscopy ◽

Electronic Structures ◽

Optical Anisotropy ◽

Electronic Structure Calculations ◽

X Ray ◽

Structure Calculations

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ELECTRONIC STRUCTURES OF FeS AND FeS 2 : X-RAY ABSORPTION SPECTROSCOPY AND BAND STRUCTURE CALCULATIONS

Journal of Physics and Chemistry of Solids ◽

10.1016/s0022-3697(96)00068-6 ◽

1997 ◽

Vol 58 (2) ◽

pp. 345-352 ◽

Cited By ~ 27

Author(s):

M. WOMES ◽

R.C. KARNATAK ◽

J.M. ESTEVA ◽

I. LEFEBVRE ◽

G. ALLAN ◽

...

Keyword(s):

Band Structure ◽

Absorption Spectroscopy ◽

Electronic Structures ◽

X Ray ◽

Band Structure Calculations ◽

X Ray Absorption ◽

Structure Calculations

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Electronic Structure of Ce-Doped and -Undoped Nd2CuO4 Superconducting Thin Films Studied by Hard X-Ray Photoemission and Soft X-Ray Absorption Spectroscopy

Physical Review Letters ◽

10.1103/physrevlett.120.257001 ◽

2018 ◽

Vol 120 (25) ◽

Cited By ~ 9

Author(s):

M. Horio ◽

Y. Krockenberger ◽

K. Yamamoto ◽

Y. Yokoyama ◽

K. Takubo ◽

...

Keyword(s):

Thin Films ◽

Electronic Structure ◽

Absorption Spectroscopy ◽

Superconducting Thin Films ◽

X Ray ◽

X Ray Absorption

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X-Ray absorption spectroscopy of LiBF4 in propylene carbonate: a model lithium ion battery electrolyte

Physical Chemistry Chemical Physics ◽

10.1039/c4cp03240c ◽

2014 ◽

Vol 16 (43) ◽

pp. 23568-23575 ◽

Cited By ~ 35

Author(s):

Jacob W. Smith ◽

Royce K. Lam ◽

Alex T. Sheardy ◽

Orion Shih ◽

Anthony M. Rizzuto ◽

...

Keyword(s):

Electronic Structure ◽

Propylene Carbonate ◽

First Principles ◽

Lithium Ion ◽

Electronic Structure Calculations ◽

X Ray ◽

Battery Electrolyte ◽

X Ray Absorption ◽

Structure Calculations ◽

Insight Into

X-ray absorption spectra, interpreted using first-principles electronic structure calculations, provide insight into the solvation of the lithium ion in propylene carbonate.

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