scholarly journals Nitrogen-Substitution in the Flapping Wings of Cyclooctatetraene-Fused Molecules

Author(s):  
Kensuke Suga ◽  
Takuya Yamakado ◽  
Shohei Saito

New synthetic protocols to the nitrogen-embedded flapping molecules have been developed. Gram-scale synthesis of a key precursor, tetraamine of dibenzo[<i>a</i>,<i>e</i>]cyclooctatetraene has been established for designing flapping quinoxaline and flapping phenazineimide. The impact of the nitrogen substitution on the photophysical properties and the viscosity-probing function has been investigated in comparison with the reported flapping anthraceneimide.

2021 ◽  
Author(s):  
Kensuke Suga ◽  
Takuya Yamakado ◽  
Shohei Saito

New synthetic protocols to the nitrogen-embedded flapping molecules have been developed. Gram-scale synthesis of a key precursor, tetraamine of dibenzo[<i>a</i>,<i>e</i>]cyclooctatetraene has been established for designing flapping quinoxaline and flapping phenazineimide. The impact of the nitrogen substitution on the photophysical properties and the viscosity-probing function has been investigated in comparison with the reported flapping anthraceneimide.


2011 ◽  
Vol 516 (1-3) ◽  
pp. 45-50 ◽  
Author(s):  
Christian Kuhnt ◽  
Michael Karnahl ◽  
Sven Rau ◽  
Michael Schmitt ◽  
Benjamin Dietzek ◽  
...  

2019 ◽  
Vol 11 ◽  
pp. 175682931984612 ◽  
Author(s):  
Tao Yang ◽  
Mingjun Wei ◽  
Kun Jia ◽  
James Chen

It has been a challenge to simulate flexible flapping wings or other three-dimensional problems involving strong fluid–structure interactions. Solving a unified fluid–solid system in a monolithic manner improves both numerical stability and efficiency. The current algorithm considered a three-dimensional extension of an earlier work which formulated two-dimensional fluid–structure interaction monolithically under a unified framework for both fluids and solids. As the approach is extended from a two-dimensional to a three-dimensional configuration, a cell division technique and the associated projection process become necessary and are illustrated here. Two benchmark cases, a floppy viscoelastic particle in shear flow and a flow passing a rigid sphere, are simulated for validation. Finally, the three-dimensional monolithic algorithm is applied to study a micro-air vehicle with flexible flapping wings in a forward flight at different angles of attack. The simulation shows the impact from the angle of attack on wing deformation, wake vortex structures, and the overall aerodynamic performance.


Author(s):  
Asiyeh Shahraki ◽  
Ali Ebrahimi ◽  
Shiva Rezazadeh ◽  
Roya Behazin

The impact of ion-π interactions on the photophysical properties of quinizarin have been investigated using the density functional theory and time-dependent density functional theory at the M06-2X/6-311++G(d,p) level in the gas phase and solution.


2018 ◽  
Vol 20 (35) ◽  
pp. 22660-22673 ◽  
Author(s):  
Mahalingavelar Paramasivam ◽  
Ramesh Kumar Chitumalla ◽  
Joonkyung Jang ◽  
Ji Ho Youk

The heteroatom substitution on cross conjugation takes a reverse trend to the linear π-conjugated systems by means of energy levels and photophysical properties. The resultant changes directly affecting the photovoltaic performance of DSSCs.


2017 ◽  
Vol 41 (7) ◽  
pp. 2717-2723 ◽  
Author(s):  
Gleb V. Baryshnikov ◽  
Rashid R. Valiev ◽  
Boris F. Minaev ◽  
Hans Ågren

In the present work we have studied a series of unsymmetrical azatrioxa[8]circulenes in order to explain the impact of outer substituents and benzoannelation on photophysical constants and aromaticity of these compounds.


2014 ◽  
Vol 107 ◽  
pp. 51-59 ◽  
Author(s):  
T. Bříza ◽  
S. Rimpelová ◽  
J. Králová ◽  
K. Záruba ◽  
Z. Kejík ◽  
...  

Nanoscale ◽  
2015 ◽  
Vol 7 (20) ◽  
pp. 9140-9146 ◽  
Author(s):  
T.-W. Koh ◽  
A. M. Hiszpanski ◽  
M. Sezen ◽  
A. Naim ◽  
T. Galfsky ◽  
...  

Nanoclusters with different degrees of aggregation are synthesized and their electrochemical energy levels are measured to implement light-emitting devices with luminance >40 cd m−2 and EQE >0.1%, with suppressed parasitic emission.


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