Decarboxylative C–C and C–N Bond Formation via Ligand-Accelerated Iron Photocatalysis
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Through iron photocatalysis, a mild and effective protocol for the decarboxylative C–C and C–N bond formation has been achieved. The carboxylic acids readily underwent radical decarboxylation in the presence of Fe<sub>2</sub>(SO<sub>4</sub>)<sub>3 </sub>and di-(2-picolyl)amine with visible light irradiation. The resultant alkyl radicals then reacted with Michael acceptors or azodicarboxylates to furnish the adducts.<br>
Visible-light-mediated allylation of alkyl radicals with allylic sulfones via a deaminative strategy
2018 ◽
Vol 5
(23)
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pp. 3443-3446
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2018 ◽
Vol 8
(16)
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pp. 4044-4051
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