Biocompatible Nano Composite Coating on 316L Stainless Steel Surface for Bone Implant Application

2021 ◽  
Vol 57 (3) ◽  
pp. 351-359
Author(s):  
R. Manonmani ◽  
S. Sureshkumar
2020 ◽  
pp. 2467-2478
Author(s):  
Amaal S. Sadiq ◽  
Entesar O. Al-Tamimi

A series of polymers containing1,2,4-triazole  and tetrazole groups in their main chains were synthesized through several steps. Poly(acryloyl hydrazide) was first prepared and then subjected to a hydrazide reaction with phenyl isothiocyanate to give a 1,2,4-triazole ring (2). This polymer was introduced into a reaction with chloro acetylchloride to yield polymer (3), which was refluxed with sodium azide to give polymer (4). Polymer (5) was synthesized by the reaction of polymer (4) with  acrylonitrile in the presence of NH4Cl as a catalyst. Finally, polymer (6) was synthesized by the electrochemical polymerization of polymer (5) using  316L stainless steel as an anti-corrosion coating. Polymer-coated and uncoated stainless steel was tested for corrosion safety in a solution of 0.1 M HCl, followed by Tafel and Potentiostatic procedures at a temperature of 293 K. Nano materials such as ZnO were applied to the monomer solution at different concentrations to enhance the corrosion resistance of the 316L stainless steel surface. The results showed that the performance values of corrosion protection for the polymer coating were increased with the introduction of the nano materials. Furthermore, 13C-NMR, 1H-NMR, and FTIR were recorded to confirm the structures of the poylmers, while their physical properties were tested using atomic force microscope (AFM) and scanning electron microscope (SEM).


2017 ◽  
Vol 1142 ◽  
pp. 8-13
Author(s):  
Ahmed Al Mehrzi ◽  
Yong Sun Yi ◽  
Pyung Yeon Cho ◽  
Sara Al Saadi ◽  
Ji Sung Lee ◽  
...  

Water droplets formed by the deliquescence of pre-deposited NaCl on 316L stainless steel were investigated. Different total weights of NaCl particles between 0.0005 g and 0.01 g were deposited on 316L stainless steel surface, which were exposed to an atmospheric condition at 80oC and relative humidity of 80% until NaCl droplets were stabilized. The volume of NaCl droplet was linearly proportional to the total weights of pre-deposited NaCl and consequently the chloride concentration in droplets, ranging from 3 to 6 M, did not depend on the NaCl weights. After exposed to the NaCl droplets at 80oC and relative humidity of 80% over 5, 10, and 15 days, all 316L stainless steel samples suffered from pitting. The Cl- ions in the surface films of samples were measured by ToF SIMS. The pit densities on samples were well correlated with the Cl- intensities in the surface films. These results suggest that the pit initiation under NaCl droplets by deliquescence is caused by the Cl- ions either incorporated into surface films or penetrated through them.


2021 ◽  
Vol 19 (1) ◽  
pp. 18
Author(s):  
M I Mukhsen ◽  
R Nur ◽  
C. R. Rakka ◽  
M. A. Fattah

Type 316 stainless steel is a material that is often used in the medical world, especially as a material for making bone implant plates. However, the use of stainless steel as an implant material, stainless steel must be treated to increase the hardness and adjust the level of roughness on the surface. In this study, shot peening was carried out on the 316 stainless steel surface. The shooting parameters used were 2, 4, 6 minutes for the shooting duration, and 0o, 15o, 30o, 45o for the shooting angle, as well as the diameter of the steel shot used, i.e. 0.6 mm and 1 mm. The results of this study indicated that there was a change in the characteristic properties of 316 stainless steel, namely the hardness and surface roughness.


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