Enhanced Failure Analysis (FA) of Organic Contamination Using Submicron Simultaneous IR and Raman Spectroscopy: Breakthrough Developments of Optical Photothermal IR (O-PTIR)

Author(s):  
D. Jay Anderson ◽  
Mustafa Kansiz ◽  
Michael Lo ◽  
Eoghan Dillon ◽  
Curtis Marcott

Abstract Rapid identification of organic contamination in the semi and semi related industry is a major concern for research and manufacturing. Organic contamination can affect a system or subsystem’s performance and cause premature failure of the product. As an example, in February 2019 the Taiwan Semiconductor Manufacturing Company (TMSC), a major semiconductor manufacturer, reported that a photoresist it used included a specific element which was abnormally treated, creating a foreign polymer in the photoresist resulting in an estimated loss of $550M [1].

Author(s):  
Jay Anderson ◽  
Mustafa Kansiz ◽  
Michael Lo ◽  
Curtis Marcott

Abstract Failure analysis of organics at the microscopic scale is an increasingly important requirement, with traditional analytical tools such as FTIR and Raman microscopy, having significant limitations in either spatial resolution or data quality. We introduce here a new method of obtaining Infrared microspectroscopic information, at the submicron level in reflection (far-field) mode, called Optical-Photothermal Infrared (O-PTIR) spectroscopy, that can also generate simultaneous Raman spectra, from the same spot, at the same time and with the same spatial resolution. This novel combination of these two correlative techniques can be considered to be complimentary and confirmatory, in which the IR confirms the Raman result and vice-versa, to yield more accurate and therefore more confident organic unknowns analysis.


2005 ◽  
Vol 39 (2) ◽  
pp. 249-256 ◽  
Author(s):  
Hartwig Schulz ◽  
Gülcan Özkan ◽  
Malgorzata Baranska ◽  
Hans Krüger ◽  
Musa Özcan

2000 ◽  
Vol 65 (5-6) ◽  
pp. 399-406 ◽  
Author(s):  
Ubavka Mioc ◽  
Marija Todorovic ◽  
Snezana Uskokovic-Markovic ◽  
Zoran Nedic ◽  
Nada Bosnjakovic

In this paper the latest results of our continuing investigation of heteropoly acids and their salts are reported. Specially attention was paid to the influence of cations on the dynamic equilibrium of protonic species, as well as on the structure of the host lattice itself, i.e., the Keggin anions. The investigations were done by IR and Raman spectroscopy within the range of 1200.40 cm-1.


Author(s):  
K. Antonova ◽  
P. Byshewski ◽  
G. Zhizhin ◽  
J. Piechota ◽  
M. Marhevka

2001 ◽  
Vol 596 (1-3) ◽  
pp. 151-156 ◽  
Author(s):  
P. Pasierb ◽  
S. Komornicki ◽  
M. Rokita ◽  
M. Rȩkas

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